• 한국광물학회지
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• 제32권3호
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• pp.223-234
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• 2019

삼덕 Mo 광상 주변지질은 고생대 화전리층, 고운리층, 서창리층, 이원리층, 황강리층, 백악기 우백질 반상화강암 및 화강반암으로 구성된다. 이 광상은 서창리층 내에 발달된 NS 방향의 열극대를 따라 충진한 3개조의 석영맥으로 구성된 광상으로 석영맥의 맥폭은 0.05~0.3 m 정도로 팽축이 심하고 석영맥의 연장성은 약 400 m 정도이다. 석영맥은 괴상, 각력상 및 정동조직들이 관찰되며 모암변질로는 규화작용, 견운모화작용, 점토화작용 및 녹니석화작용 등이 관찰된다. 산출광물은 석영, 형석, 백색운모, 흑운모, 인회석, 모나자이트, 금홍석, 티탄철석, 휘수연석, 황동석, Fe-Mg-Mn 산화물 및 철 산화물 등이다. 이 광상의 백색운모는 석영맥과 모암에서 세립질에서 조립질로 산출되며 4가지 산출유형(I 유형: 석영, 휘수연석, 철 산화물 및 Fe-Mg-Mn 산화물과 함께 산출되는 것, II 유형: 석영, 철 산화물 및 Fe-Mg-Mn 산화물과 함께 산출되는 것, III 유형: 석영 및 흑운모와 함께 산출되는 것 및 IV 유형: 석영과 함께 산출되는 것)을 갖는다. 석영맥에서 산출되는 백색운모의 화학조성은$(K_{0.89-0.60}Na_{0.05-0.00}Ca_{0.01-0.00}Sr_{0.02-0.00})_{0.94-0.62}(Al_{1.54-1.12}Mg_{0.36-0.18}Fe_{0.26-0.09}Mn_{0.04-0.00}Ti_{0.02-0.00}Cr_{0.02-0.00}Zn_{0.01-0.00})_{1.91-1.72}(Si_{3.40-3.11}Al_{0.92-0.60})_{4.00}O_{10}(OH_{1.68-1.42}F_{0.58-0.32})_{2.00}$이나 I 유형의 백색운모는 나머지 유형의 백색운모보다 $SiO_2$ 및 MgO 함량은 낮고 FeO 함량은 높게 나타난다. 또한 이 광상의 백색운모의 화학조성 변화는 팬자이틱 또는 Tschermark 치환($(Al^{3+})^{VI}+(Al^{3+})^{IV}{\leftrightarrow}(Fe^{2+}$ 또는 $Mg^{2+})^{VI}+(Si^{4+})^{IV}$) 및 직접적인 $(Fe^{3+})^{VI}{\leftrightarrow}(Al^{3+})^{VI}$ 치환에 의해 일어났음을 알 수 있다.

• 자원환경지질
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• 제28권1호
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• pp.9-17
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• 1995

The Kamkye Cu-Pb-Zn-Au-Ag deposits occur as quartz veins that filled fault-related fractures of NW system developed in the Cretaceous Gyeongsang basin. Three major stages of mineral deposition are recognized: (1) the stage I associated with wall rock alteration, such as sericite, chlorite, epidote and pyrite, (2) the early stage II of base-metal mineralization such as pyrite, hematite, and small amounts of sphalerite and chalcopyrite. and the middle to late stage II of Cu-As-Sb-Au-Ag-S mineralization, such as sphalerite, chalcopyrite, galena with tetrahedrite, tennantite, pearceite, Pb-Bi-Cu-S system, argentite and electrum. (3) the stage III of supergene mineralization, such as covellite, chalcocite and malachite. K-Ar dating of alteration sericite is a late Cretaceous ($74.0{\pm}1.6Ma$) and it may be associated with granitic activity of nearby biotite granite and quartz porphyry. Fluid inclusion data suggest a complex history of boiling, cooling and dilution of ore fluids. Stage II mineralization occurred at temperatures between 370 to $220^{\circ}C$ from fluids with salinities of 8.4 to 0.9 wt.% NaCl. Early stage II($320^{\circ}C$, 2.0 wt.% NaCl) may be boiled due to repeated fracturing which opened up the hydrothermal system to the land surface, and which resulted in a base-metal sulfide. Whilst the fractures were opened to the surface, mixing of middle-late stage II ore fluids with meteoric waters resulted in deposition of Cu-As-Sb-Au-Ag minerals from low temperature fluids(${\leq}290^{\circ}C$). Boiling of ore fluids may be occured at a pressure of 112 bar and a depth of 412 m. Equilibrium thermodynamic interpretation of sphalerite-tetraherite assemblages in middle stage II indicates that the ore-forming fluid had log fugacities of $S_2$ of -6.6~-9.4 atm.

• 암석학회지
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• 제8권2호
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• pp.81-91
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• 1999

옥천화강암은 옥천읍 일대에서 원형상으로 분포하며, 그 북부와 동부 및 남부에서 옥천층군을 관입한 쥬라기 암체이며 그 서부에서 백악기의 석영반암류에 의해 관입된다. 이 암체는 중립질의 흑운모 화강으로서 유색광물부(mafic enclave)가 종종 발달하며 북부 주변에서는 미약한 엽리구조를 이루기도 한다. 구성광물은 석영, 사장석, 알칼리장석, 흑운모, 스펜과 녹리석 등이다. 복부일부에 발달하는 미립질과 줄무늬 석영, 흑운모와 이차광물인 백운모 등이 이루는 엽리는 옥천화강암질 마그마의 유동중에 주변암에 의해 형성된 구조이다. QAP 모드분석에서 몬조화강암-화강섬록암에 도시되는 과알루미나암질로서 캘크 알칼리례열에 속하는 분화경향을 가진다. SiO2 대 주원소 그리고 미향원소 등의 관계도에서 단일 마그마의 분화경향을 뚜렷이 가진다. 콘드라이트로 표준화한 희토류원소는 경(LREE)에서 중(HREE)으로 갈수록 점진적으로 결핍되며 Eu/Eu*는 0.84의 부 이상값(negative anomaly)을 가져 대체로 국내 쥬라기 화강암류와 유사한 특성을 가진다. 동시충돌대의 지구조적환경에서 I-형의 지각물질이 용융하여 형성된 화강암질 마그마가 다소 빠르게 상승하여 옥천층군내에 정치된 암체이다.

• 자원환경지질
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• 제15권4호
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• pp.205-219
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• 1982

어성천 망간광상은 고생대 오르도비스기의 흥월리 돌로마이트층과 삼태산 석회암층에 관입한 석영반암맥을 따라 산출되는 표성광상이다. 망간광석은 산화망간광물들과 이에 수반되는 맥석광물들로 구성되어 있다. 산화망간광물들 중 란시아이트와 토도로카이트는 다량으로 산출되며, 버어네사이트, 엔소타이트, 연망간석, 캘코파나이트는 소량으로 산출된다. 맥석광물로는 방해석, 석고, 침철석, 레피도크로사이트, 석영, 견운모등이 산출된다. 산화망간광물들과 맥석광물들의 연구에는 현미경 관찰, 화학분석, 엑스선회절분석, 적회선흡수분광분석, 시차열분석 방법등이 이용되었다. 버어네사이트와 란시아이트의 관계가 엑스선회절분석과 적외선흡수분광분석법에 의하여 연구되었다. 이 두 광물들은 구조적으로 상당히 밀접한 관계가 있으나 서로 다른 광물종임이 적외선 흡수 스펙트럼연구에 의하여 확실시된다. 산화망간광물들은 표성환경하에서 교대작용, 용액으로부터의 침전, 재결정작용등에 의하여 생성되었다. 산화망간광물들의 생성순서는 다음과 같은 경향을 보여준다 : (능망간석)-(토도로카이트)-(버어네사이트, 란시아이트)-(엔소타이트, 연망간석, 캘코파나이트).

• 자원환경지질
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• 제25권3호
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• pp.283-296
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• 1992

The Keumryeong deposits is a low grade copper deposits in which copper minerals form disseminated grains and thin veinlets in felsic volcanics seem to be dacite. Alteration of the volcanics consists mainly pervasive propylitization and silicification. Potassic alteration characterized by biotite developed locally adjacent to southwestern contact of granodiorite body. Principal sulfide minerals in altered zone are mainly pyrite and lesser chalcopyrite. Chalcopyrite content in potassic zone is relatively higher than that of surrounding propylitized zone. Pyrite and chalcopyrite accompanies magnetite, molybdenite, sphalerite, pyrrhotite, arsenopyrite, pentlandite, marcasite, hematite, ilmenite, rutile, bismuthinite and native Bi as disseminations, veinlets and knots. Granodiorite body is propylitized and contains veinlets of pyrite, chalcopyrite and molybdenite. Fluid inclusions in sulfide-bearing quartz veinlets and quartz grains of felsic volcanics and granodiorite in altered zone consist of liquid-rich, vapor-rich, $CO_2-bearing$ and halite-bearing inclusions. These four types of inclusion intimately associated on a microscopic scale and indicate condensing or boiling of ore fluid during mineralization. Homogenization temperature of coexisting fluid inclusions are mostly in the range of 350 to $450^{\circ}C$. High salinity fluid contains 28.6 to 48.4 weight percent NaCI equivalent and moderate salinity fluid cotains 0.5 to 12.5 weight percent NaCl equivalent. Pressure estimated from $CO_2$ mole fraction of $CO_2-bearing$ inclusion range 160 to 375 bars. The Kigu copper deposits is a fissure filling copper vein developed 500 m south from the Keumryong deposits. Mineralogy and fluid inclusion data of the Kigu deposits are similar to that of the Keumryeong deposits. Homogenization temperature of fluid inclusions from the Kigu deposits are reasonable agreement with temperature estimated from sulfidation curve of cubanite-chalcopyrite-pyrite-pyrrhotite and pyrite-pyrrhotite mineral assemblages. Not only mineral occurrence and wall rock alteration in the Keumryeong deposits but also fluid inclusion data such as temperature, salinity, pressure and boiling evidences are similar to those of porphyry copper deposits.

• 자원환경지질
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• 제32권5호
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• pp.445-454
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• 1999

산전 금-은 광상은 석영 반암내에 반암내에 발달된 열극을 충진한 석영+방해석의 열수맥광상이다. 광화작용은 단일 시기에 형성되었으며, 시간에 따라 다음과 같이, (2) 초기, 백석 석영+황철석+유비철석+심야연석; (2)중기, 백석-투명 석영+황화광물 (황철석, 섬아연석, 황동석, 방연석)+에렉트럼+휘은석; (3)후기, 방해석+황철석+자연은의 정출이 있었다. 금-은의 주요 광화기인 중기 광화유체의 온도와 NaCl 상당 염농도는 $210^{\circ}$~$250^{\circ}C$와 4~5wt.%이고, 황분압은 -14.0~-12.2atm 으로 금-은 침전은 천수의 혼입작용에 기인한 것으로 보인다. 산소 및 수소동위원소 분석에 의하면, 광화작용이 진행되에 따라 양자 모두 감소하는 경향을 갖는다. 이는 광화작용이 진행됨에 따라 천수의 혼입이 증가하기 때문으로 해석된다.

• 자원환경지질
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• 제9권1호
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• pp.27-43
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• 1976

The flourite in Hwacheon, Hwanggangri and Keumsan district are major fluorite producing areas in Korea. The fluorite deposits of Hwacheon district are wholly fissure filling hydrothermal veins embedded in Precambrian gneiss and schists and Jurassic granites. Also some fluorite deposits are emplaced in felsite whose age is unknown. Emplacement of most fluorite veins of the district are controlled by EW fracture system. Fluorites are generally accompanied to chalcedonic quartz and also kaolinite, montmorillonite, dickite and calcite in parts. Vertical and lateral mineral zonings are not distinct. The fluorite deposits in the Hwanggangri district are wholly embedded in limestone and other calcareous sediments of Paleozoic Yeongweol Group. Most of the fluorite deposits belong to one of two categories which are steeply. dipping veins and gently dipping replacement deposits adjacent to Late Cretaceous(83-90mys) granite bodies. The strikes of fluorite veins of Hwanggangri district mostly occupy the fractures of $N30^{\circ}-40^{\circ}E$ and $N30^{\circ}-40^{\circ}W$ system. Fluorites are accompanied to calcite, milky quartz, chalcedonic quartz, and also montmorillonite, kaolinite in parts. But in some deposits, scheelite, various sulfide minerals and barite are accompanied. Emplacement of fluorite deposits are largely controlled by lithology and structures of this district. In some deposits fluorite veins gradate to scheelite veins and also telescoping of the mineral zones are found in this district. In the Keumsan district, fissure-filled fluorite veins and replacement deposits are mostly emplaced in limestone of Paleozoic Yeongweol Group, late Cretaceous quartz-porphyry, granite and sandstone. Some deposits are emplaced in Precambrian metasediments. Mineralogy and other characteristics of the deposits in this district is similar to those of Hwanggangri district. Fluid inclusion studies reveal the difference of salinities, $CO_2$ contents of ore fluid and temperatures during fluorite mineral deposition in the these districts. In Hwacheon district, ore-fluids were comparatively dilute brine and low $CO_2$ content. Filling temperatures ranges $104^{\circ}C$ to $170^{\circ}C$. In the Chuncheonshinpo mine, most deeply exploited one in this district, salinitles range 0.5-2. 2wt. % NaCl and filling temperatures range from $116^{\circ}C$ to $143^{\circ}C$. In the Hwanggangri district, ore fluids were complex and filling temperature ranges very widly. In the contact metasomatic fluorite deposits, ore fluid were NaCl rich brines with moderate $CO_2$ content and filling temperatures range from $285^{\circ}C$ to above $360^{\circ}C$. Fluids inclusions in tungsten and sulfide minerals bearing fluorite veins show high $CO_2$ content up to 31wt. %. Filling temperature ranges from $101^{\circ}C$ to $310^{\circ}C$. Fluids inclusions In mainly fluorite bearing veins were more dilute brine and low $CO_2$ contents. Filling temperatures range from $95^{\circ}C$ to $312^{\circ}C$. Filling temperature of fluid inclusions of Keumsan district are between $95^{\circ}C$ and $237^{\circ}C$. Data gathered from geologic, mineralogic and fluid inclusion studies reveal that fluorite mineralization in H wacheon district proceeded at low temperature with dilute brine and low $CO_2$ content. In Hwangganri district, fluorite mineralization proceeded by several pulse of chemically distinct ore fluids and formed the mineralogically different type of deposits around cooling granite pluton which emplaced comparatively shallow depth.

• 한국토양비료학회지
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• 제39권5호
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• pp.245-252
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• 2006

우리나라 토양의 분류체계를 보완하고 점토광물 조성과 분포를 파악하기 위하여 우리나라 390개 토양통 중 잔적 및 붕적토에서 유래된 26개 토양통을 대상으로 토양 층위별료 시료를 채취하여 집적층을(B층) 토양의 이화학적 특성, 토양 중 점토의 광물조성과 화학성분을 분석하였다. 잔적 및 붕적모재별로는 화강암과 화강편마암, 회장암에서 유래된 토양에서 kaolin과 quartz, 유문암, 3기층, 석영반암, 응회암에서 유래된 토양에서 quartz과 kaolin, 석회암, 혈암, 사암, 역암 등 퇴적암에서 유래된 토양에서 illite와 chlorite가 주요한 점토광물이었다. 토양통별 점토광물조성을 군집분석 (CA, cluster analysis)을 통하여 (1) illite, kaolin, vemiculite를 주광물로 하는 혼합점토광물군 (MIX), (2) kaolin을 주광물로 illite가 많은 kaolin군 (KA), (3) chlorite와 illite가 주광물인 chlorite군 (CH), (4) kaolin과 illite를 주광물로 smectite가 함유된 smectite군 (SM) 등 4개의 점토광물 조성군으로 구분하였다. 우리나라 토양의 대부분은 kaolin을 주광물로 하는 토양과 illite, kaolin, vemiculite가 함유된 토양이었으며, illite와 kaolin을 주광물로 하는 토양에서 CEC가 낮았고 vemiculite와 smectite가 함유된 점토에서 규반비가 높았다.

• 한국실내디자인학회:학술대회논문집
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• 한국실내디자인학회 2006년도 춘계학술발표대회 논문집
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• pp.264-267
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• 2006

The purpose of this study is to examine the advertisements of eco-friendly interior products and finishing materials in 3 interior design magazines which have been published for 4 years since 2002: to identify specific types of the products and materials that consumers can choose and to analyze their special ingredients which have functions and effectiveness related to health. Literature review and content analysis on the advertisements were employed. The results are as follows: The amount of advertisements has been continuously increasing due to the public concerns on well-being and finishing material types absolutely took the greatest proportion (92.8%) among them. Floor coverings, wall papers, and paints are the big 3 materials in the finishing material advertisements. The frequently mentioned health-related ingredients in them were charcoal, natural jade, nanosilver, yellow soil and quartz porphyry, And their main functions were emission of negative ions and ultra infrared. However, it's not easy to find their scientific test results on health. Objective guidelines are needed for the right selection of interior products and materials to maintain healthy interior environment.

• 보존과학회지
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• 제36권1호
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• pp.60-72
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• 2020

The Inscribed stones of Hanyangdoseong has been weathered for a long time because of external environment and living organisms. To establish a long-term conservation-management strategy for the inscription stones, the material characteristics of the inscription stones of Naksan Mountain Area were identified, and its deterioration state was diagnosed. Consequently, it was confirmed that the Inscription stones of Naksan Mountain Area mainly comprised coarse-to medium-grained pinkish granite and biotite granite, and, in part, comprised reddish granite, quartz porphyry, and aplite. Presently, the Inscription stones of Naksan Mountain Area, Hanyangdoseong, is undergoing a considerable decrease in physical properties because of physical, chemical, and biological weathering. Moreover, it has been confirmed that the type of damage, such as blistering, soiling, and dicolouration, on the surface shows a significantly high deterioration rate, and that conservation treatment might be required in future. In addition, because the possibility of damage recurrence is high even after the treatment, the conservation state must be regularly monitored.