• 제목/요약/키워드: Quadrupole Parameter

검색결과 21건 처리시간 0.022초

$^{87}Rb$ NMR Quadrupole Coupling Constants and Asymmetry Parameters in $RbMnCl_3$

  • Woo, Ae-Ja;Park, Young-Sun
    • 한국자기공명학회논문지
    • /
    • 제3권2호
    • /
    • pp.84-89
    • /
    • 1999
  • The 87Rb quadrupole coupling constants (e2qQ/h) and the asymmetry parameters (η) in RbMnCl3 were determined from a nonlinear least-squares fit to the 87Rb NMR powder spectra. The spectra were acquired in the temperature range from 260K to 330K. An important feature in this work is the determination of the quadrupole coupling constants and the asymmetry parameters for two physically nonequivalent Rb sites, Rb(I) and Rb(II), as a function of temperature. In addition, a structural phase transition at room temperature was conformed with the changes in the quadrupole coupling constant and the asymmetry parameter of Rb(II) site.

  • PDF

Calculation of electric field gradient tensor for simple point charge distributions and its application to real systems

  • Choh, Sung-Ho;Shin, Hee-Won;Park, II-Woo;Ju, Heong-Kyu;Kim, Jong-Hyun;Kim, Hae-Jin
    • 한국자기공명학회논문지
    • /
    • 제7권1호
    • /
    • pp.16-24
    • /
    • 2003
  • Nuclei with the spin quantum number not smaller than unity have not only the nuclear magnetic moment but also the electric quadrupole moment. The quadrupole moment couples with the electric field gradient (EFG) to produce the nuclear quadrupole interaction. It is well known that two independent parameters, i.e. the quadrupole coupling constant (QCC) and the asymmetry parameter ($\eta$) together with the principal axis directions can fully describe the interaction and are very sensitive to the local symmetry and structure of the solid. In order to obtain quantitative estimates of the EFG tensor for various simple ionic configurations surrounding the nucleus under consideration, we employ the simple point charge approximation and apply the calculated results to some real crystals. General agreement is rather satisfactory.

  • PDF

ZORA DFT Calculation of $^{11}$B Electric Field Gradient Tensor for Lithium Borates

  • Woo, Ae-Ja;Wasylishen, Roderick E.
    • 한국자기공명학회논문지
    • /
    • 제8권2호
    • /
    • pp.70-76
    • /
    • 2004
  • ZORA-DFT calculations of $^{11}$B EFG (electric field gradient) tensors for lithium borates, LiB$_3O_5$ (LBO) and Li$_2B_4O_7$ (LTB), were performed. The calculated values of 11B quadrupole coupling constant and asymmetry parameter are in good agreement with the experimental values. The sign of the quadrupole coupling constant for the tetrahedral boron site was deduced from the distortion from the ideal tetrahedral symmetry.

  • PDF

유체유동을 포함한 소음기의 음향 특성 해석 (Analysis of Acoustic Characteristics of Muffler including Flow effects)

  • 김형태;정의봉;김희원
    • 한국소음진동공학회:학술대회논문집
    • /
    • 한국소음진동공학회 2006년도 추계학술대회논문집
    • /
    • pp.861-864
    • /
    • 2006
  • In general, 4-pole parameter and three-point method are used for predicting transmission loss which is one of characteristics of Muffler using CAE tools. However, these mehtods show different results from experiment when the flow effects are presented in practical model. In this parer, to overcome these problems, both Fluent and.Sysnoise are used to analyze the performance of extended inlet/outlet muffler including flow effects with varying flow velocity at inlet of duct. Flow fields and quadrupole source is calculated by Fluent. And Sysnoise is used to analyze acoustic performances of muffler with quadrupole source data extracted from Fluent. Finally, the variation of transmission loss is estimated according to various inlet flow velocity.

  • PDF

DARK ENERGY REFLECTIONS IN THE REDSHIFT-SPACE QUADRUPOLE

  • NISHIOKA HIROAKI;YAMAMOTO KAZUHIRO;BASSETT BRUCE A.
    • 천문학회지
    • /
    • 제38권2호
    • /
    • pp.175-178
    • /
    • 2005
  • We show that next-generation galaxy surveys such as KAOS (the Kilo-Aperture Optical Spectro-graph)will constrain dark energy even if the baryon oscillations are missing from the monopole power spectrum and the bias is scale- and time-dependent KAOS will accurately measure the quadrupole power spectrum which gives the leading anisotropies in the power spectrum in redshift space due to peculiar velocities, the finger of God effect, as well as the Alcock-Paczynski effect. The combination of monopole and quadrupole power spectra powerfully breaks the degeneracy between the bias parameters and dark energy and, in the complete absence of baryon oscillations ($\Omega$b = 0), leads to a roughly $500\%$ improvement in constraints on dark energy compared with the monopole spectrum alone. As a result, for KAOS the worst case with no oscillations has dark energy errors only mildly degraded relative to the ideal case, providing insurance on the robustness of KAOS constraints on dark energy. We show that nonlinear effects are crucial in correctly evaluating the quadrupole and significantly improving the constraints on dark energy when we allow for multi-parameter scale-dependent bias.

비정질 $Fe_{83}B_9Nb_7Cu_1$의 M$\ (Distributions of Hyperfine Parameters in Amorphous $Fe_{83}B_9Nb_7Cu_1$ Alloys)

  • 윤성현;김성백;김철성
    • 한국자기학회지
    • /
    • 제9권6호
    • /
    • pp.271-277
    • /
    • 1999
  • M ssbauer 분광법을 이용하여 비정질합금 Fe83B9Nb7Cu1의 자기적 성질을 연구하였다. 개선된 Vincze의 방법을 적용하여 각 온도에서 초미세자기장, 이성질체 이동치, 그리고 quadrupole line broadening의 분포함수들을 얻었고 큐리온도는 393K, Hhf(0)는 231kOe로 산출되었다. 환산된 평균 초미세 자기장(reduced average hyperfine field)의 온도 변화는 S=1 자기화 곡선에 비해 급히 감소하는 양상을 보였고 이를 설명하기 위해 Handrich의 분자장 이론에서 교환 상호 작용의 척도인 에 =0.75-0.64(T/Tc)+0.47(T/Tc)2의 온도 의존성을 도입하였다. 평균 초미세 자기장(Hhf(T))은 저온에서 스핀파 여기에 의한 공식 Hhf(T)=Hhf(0)[1-0.44(T/Tc)3/2-0.28(T/Tc)5/2- ]으로 분석하였고, 큐리온도 부근에서는 1.00[1-T/Tc]0.39의 관계를 갖는 것으로 나타났다. 초미세 자기장 분포곡선의 선폭은 13K에서 102kOe (3.29 mm/s)였으며, 오도가 증가함에 따라 감소했다. 큐리온도 이상에서 평균 quadrupole splitting값은 0.43 mm/s였으며 quadrupole 이동치 분포에 의한 선폭 증가는 13K에서 0.1 mm/s, 320K에서는 0.072 mm/s 정도로 초미세 자기장 분포나 quadrupole line broadening에 의한 선폭 증가보다 작았다. 이성질체 이동치의 온도 변화에 Debye 모형을 적용하여 Debye 온도를 D=424K로 산출하였다.

  • PDF

How Shock Wave Interacts with a Vortex ?

  • Chang Keun-Shik;Chang Se-Myong
    • 한국가시화정보학회:학술대회논문집
    • /
    • 한국가시화정보학회 2004년도 춘계학술대회 논문집
    • /
    • pp.1-7
    • /
    • 2004
  • When a vortex diffracts upon encountering a vortex, many strong and weak waves are produced in the course of interaction. They are the cause of shock wave attenuation and noise production. This phenomenon is fundamental to understanding the more complex supersonic turbulent Jet noise. In this paper we have reviewed the research on shock-vortex interaction we have carried on last seven years. We have computationally investigated the parameter effect. When a shock is strong, shock diffraction pattern becomes complex since the slip lines from the triple points on Mach stem curl into the vortex, causing an entropy layer. When the vortex is unstable, vortexlets are brought about each of which make shock diffraction of a reduced intensity. Strong vortex produces quadrupole noise as it impinges into a vortex. Elementary interaction models such as shock splitting, shock reflection, and shock penetration are presented based on shock tube experiment. These models are also verified by computational approach. They easily explain production and propagation of the aforementioned quadrupole noise, Diverging acoustics are explained in terms of shock-vortexlet interactions for which a computational model Is constructed.

  • PDF

기계적 합금화한 Fe계 분말 특성에 관한 뫼스바우어 분광학적 연구 (Mössbauer Study on Crystallographic and Magnetic Properties of Mechanical Alloying Fe-M(M=Cr, Mn, Cu, Zn) Powders)

  • 박재윤;최재주
    • 한국자기학회지
    • /
    • 제17권1호
    • /
    • pp.26-29
    • /
    • 2007
  • 비 평형 시료제조법으로 잘 알려진 기계적 합금법을 이용하여 Fe(Fe-Cr, Fe-Mn, Fe-Cu, Fe-Zn)계 분말을 제조하였다. 일정한 당량비를 갖는 Fe와 전이금속원소 M(Cr, Mn, Cu, Zn)분말을 Ar 분위기에서 볼밀을 사용하여 수주에 걸친 기계적 합금을 시행하였다. 분쇄시간에 대한 Fe계 분말들의 결정 구조적 및 초미세 자기적 특성 변화를 X선 회절기와 $M\"{o}ssbauer$ 분광계를 이용하여 관찰하였다. X-선 회절실험 결과 밀링시간의 진행에 따라 합금이 발생되고 격자 상수값은 전이금속원자 M의 Fe원자 치환에 따라 증가하였다. Fe원자 주위의 국소적 원자분포의 영향을 조사하기 위한 $M\"{o}ssbauer$ 분광실험에서 밀링시간의 경과와 더불어 강자성 상에 대한 공명 흡수선들의 평균선폭은 증가되었고 상자성 상 역시 관측 되었다. 치환에 의한 Fe 원자간 거리증가는 초미세 자기장값은 분산된 값을 가져왔으며, quadrupole shift와 isomer shift의 결과는 M 치환으로 Fe의 결정구조와 국부적 전하분포의 변화가 크게 일어나지 않음을 보여준다.

공동주택 화장실 층간 소음 저감기 개발 (Development of silencer for apartment floor between bathroom noise)

  • 김영수;이재국;김창열
    • 한국소음진동공학회:학술대회논문집
    • /
    • 한국소음진동공학회 2008년도 추계학술대회논문집
    • /
    • pp.715-721
    • /
    • 2008
  • 공동주택에서의 음환경 성능은 실내환경의 질과 연관시켜 설계단계부터 충분한 검토가 필요한 성능항목이다. '국토해양부'는 '공통주택 성능등급 표시제도'에서 Air Duct를 통해 상하층간 전파되는 소음을 제어하기 위한 대책을 요구하고 있다. 이에 화장실에 적합한 구조 및 재질로 소음 저감기를 개발하고, 소음기 성능평가 장치를 구성하여 이론과 비교평가하고, 실제 현장에 설치 시 적용효과를 분석하였다.

  • PDF

충격파-와동 간섭의 파라메터 연구 (Parametric Study on Shock-Vortex Interaction)

  • 장근식;장세명
    • 대한기계학회논문집B
    • /
    • 제29권8호
    • /
    • pp.921-926
    • /
    • 2005
  • In the idealized model problem of the interaction between a planar travelling shock and a symmetric vortex, the physics of shock distortion and quadrupole sound generation are well known to many researchers. However, the authors have distinguished the weak waves reflected and transmitted by the complicated photograph images obtained from a shock tube experiment. In this paper, we introduces a parametric study based on Navier-Stokes simulation and Rankin vortex model to see the difference of shock deformation shapes. Four combination of the strength of shock and vortex are respectively selected from a parameter plane of shock and vortex strength extended to the strong vortex region. The result shows clearly discernable wave morphology for the main parameters, which is not yet explicitly mentioned by other researchers.