• Resources Recycling
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• v.15 no.1 s.69
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• pp.20-27
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• 2006

PVC is the thermoplastic offering excellent material properties. PVC has been used in wide variety of applications, however, it causes environmental problems when it is discarded because of its high chlorine content. Since dechlorination reaction of PVC is taking place at relatively low temperature compared to the pyrolysis temperature of plastics, study on the dechlorination reaction has been carried out as a pre-treatment process. Twin screw reactor which shows excellent mixing capabilities is employed. Experimental variables are the first and second reactor temperature, PVC content in mixed plastics, viscosity of mixed plastics, feeding rate, rotational speed or the second reactor. Over $90\%$ of dechlorination ratio can be obtained under proper operation conditions. Chlorine gas evolved from reactor is absorbed in water and can be recovered as a hydrochloric acid. Analysis had been done on chlorine flows by taking material balance over realtor.

• Journal of the Korean Applied Science and Technology
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• v.22 no.1
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• pp.43-49
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• 2005

OXI-PAN fibers, Kynol fibers and rayon fibers were used as precursorsfor the preparation of activated carbon fibers (ACFs) by chemical activation with KOH at $800^{\circ}C$. The effects of different precursorfibers and fiber/KOH ratios on the final ACFs are discussed. The precursor fibers used are appropriate for the ACFs in a single stage pyrolysis process. The OXI-PAN fibers which were activated with KOH of 2.0M showed a specific surface area of $2328m^2/g$ however, loosed the fiber shape because of low yields. The Kynol fibers and Rayon fibers showed the high yields but the lower specific surface area of $900m^2/g$ and $774m^2/g$, respectively, at KOH of 1.5M. The OXI-PAN fibers which were activated with KOH of 1.5M have a specific surface area of $1028m^2/g$ and higher micro-pore volumes and lower yields rather than Kynol-1.5 and Rayon-1.5 samples. This phenomenon is because of higher chemical resistance of the Kynol and Rayon fibers rather than OXI-PAN fibers. However, the Kynol fibers were the best precursors on KOH activation at $800^{\circ}C$ considered carbon yields, surface areas and micropore volumes.

• Journal of Korean Society of Environmental Engineers
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• v.32 no.1
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• pp.17-22
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• 2010

The aim of this study is to research applicable possibility of DSI (Dry Sorbent Injection) technique in $SO_2$ removal process using lab-scale facility based on 500MW in capacity coal-fired thermal power plant operated by South Korea N. Power Co., Ltd. To increase the $SO_2$ removal efficiency, it is considered the mixing enhancement as different shapes called lobed-plate and stepplate tested ultimately for optimum shape. Also it tested to analysis $SO_2$ removal efficiency by numbers of injection holes. At experimental it showed the $SO_2$ removal efficiency is higher using mixing enhancement than not installed mixing enhancement and case on the step-plate was shown the most $SO_2$ removal efficiency. Also, $SO_2$ removal efficiency was higher recording which will increase the injection holes case on not installed mixing enhancement. But, the $SO_2$ removal efficiency was higher 4 injection holes case on installed mixing enhancement.

• Proceedings of the Korean Institute of Resources Recycling Conference
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• 2005.10a
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• pp.83-96
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• 2005

PVC is the thermoplastic offering excellent material properties. PVC is used in wide variety of applications, however, it causes environmental problems when it is discarded because of its high chlorine content. Since dechlorination reaction of PVC is taking place relatively low temperature compared to the pyrolysis temperature of plastics, study on the dechlorination reaction has been carried out as a pre-treatment process. Twin screw reactor which shows excellent mixing capabilities is employed. Experimental variables are first and second reactor temperature, PVC content in mixed plastics, viscosity of mixed plastics, feeding rate, rotational speed of the second reactor. Over 90% of dechlorination rate can be obtained under proper operation conditions. Chlorine gas evolved from reactor is absorbed in water and can be recovered as a hydrochloric acid. Analysis had been done on chlorine flows by taking material balance over reactor.

• Journal of the Korean Society for Railway
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• v.12 no.6
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• pp.1059-1066
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• 2009

Recently, the amount of thermosetting plastic wastes has increased with the production of reinforced plastic composites and causes serious environmental problems. The epoxy resins, one of the versatile thermosetting plastics with excellent properties, cannot be melted down and remolded as what is done in the thermoplastic industry. In this research, a series of experiments that decompose epoxy resin and recover carbon fibers from carbon fiber reinforced epoxy composites applied to railway vehicles was performed. We experimentally examined various decomposition processes and compared their decomposition efficiencies and mechanical property of recovered carbon fibers. For the prevention of tangle of recovered carbon fibers, each composites specimen was fixed with a Teflon supporter and no mechanical mixing was applied. Decomposition products were analyzed by scanning electron microscope (SEM), gas chromatography mass spectrometer (GC-MS), and universal testing machine (UTM). Carbon fibers could be completely recovered from decomposition process using nitric acid aqueous solution, liquid-phase thermal cracking and pyrolysis. The tensile strength losses of the recovered carbon fibers were less than 4%.

• Elastomers and Composites
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• v.35 no.4
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• pp.272-280
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• 2000

The experimental kinetics was analyzed for commercial rubbers such as NR, IR, BR, SBR 1500, and SBR 1700. Kinetic analysis for the commercial rubbers was performed using a thermogravimetric method, which the activation energies of NR obtained by Kissinger, Friedman, ana Ozawa's method were 195.0, 198.3, and 186.3 kJ/mol, respectively. whereas that of SBR 1500 were 246.4, 247.5, and 254.8 kJ/mol, respectively. It was shown that the yield of pyrolytic oil was generally increased with increasing the final temperature. Considering the effect of heating rate. it was found that the yield of pyrolytic oil was not consistent for each sample. The number average molecular weight of pyrolitic oil of SBR 1500 was in the range of 740-2486. The calorific value of SBR 1500 was 39-40 kJ/g, and it might be a considerable energy potential although it was lower than the conventional fuel such as kerosene, diesel, light fuel, and heavy fuel.

• Applied Chemistry for Engineering
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• v.29 no.5
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• pp.571-580
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• 2018

In this study, hybrid adsorbents (SS) were prepared by mixing spent coffee grounds (SCG) and sericite, a kind of clay minerals, to adsorb Pb(II) from an aqueous solution. In FT-IR analyses, the main functional groups of SS adsorbents were O-H, C=O and C-N groups. The specific surface area, cation exchange capacity and the pore diameter of SS were larger than those of using SCG and sericite. Formation conditions of the SS adsorbent were the optimum pyrolysis temperature of $300^{\circ}C$, SCG : sericite ratio of 8 : 2, and particle size of 0.3 mm. Langmuir adsorption isotherm was more suitable than Freundlich one, and the maximum adsorption capacity was reached 44.42 mg/g. As a result of the adsorption thermodynamic analysis, the adsorption of Pb(II) onto SS was the physical adsorption and exothermic process in nature. The regeneration of SS adsorbent using distilled water showed 88~92% recovery and the active site of SS adsorbent decreased with increasing the reuse cycle time. As a result, SS adsorbent showed that it can be used to remove Pb(II) easily, inexpensively and efficiently without any pre-treatment from aqueous solutions.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.45 no.2
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• pp.92-98
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• 2017

Porosity in polymer matrix composites generated during pyrolysis process affect the thermomechanical behavior of the composites. In this paper, multislice finite element models for the porous composite materials are developed, and poroelastic and failure analysis for these models are performed. In order to investigate the three-dimensional effects, finite element meshes are modeled considering different porosity(up to 0.5) and the number of slices (up to five). As a result, effective Young's moduli and poroelastic parameters exhibit the maximum differences of 74.0% and 442.1% with respect to porosity respectively, and 98.7% and 37.2% with respect to the number of slices. First and last failure strengths are decreased 88.2% and 90.0% with respect to porosity respectively, and 53.8% and 171.8% with respect to the number of slices.

• Korean Journal of Materials Research
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• v.9 no.7
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• pp.735-739
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• 1999

In this study we investigated stress development and shrinkage of thickness for a single $PbTiO_3$(PT) layer prepared by sol-gel processing. Changes of microhardness for multideposited PT layers with temperatures are also monitored to understand the densification of thin films. Single PT layer shrank rapidly from room temperature to$ 220^{\circ}C$ yielding 83% of total shrinkage observed up to $500^{\circ}C$. A tensile stress of ~75MPa developed in an as-spun layer, and increased steadily beyond $130^{\circ}C$ until it reaches the maximum value of 147MPa at $250^{\circ}C$. The significant decrease of tensile stress in the film beyond $370^{\circ}C$ indicates that thermal expansion mismatch between the film and the substrate dominates the stress behavior in this temperature range. Microhardness of the multideposited coatings also increased rapidly above $300^{\circ}C$ regardless of the pyrolysis temperatures used. Large amount of perovskite phase formed in multideposited coatings after $550^{\circ}C$ may be due partly to enhanced homogeneous nucleation in the thicker coating.

• Korean Journal of Materials Research
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• v.23 no.5
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• pp.293-298
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• 2013

In this study, an HP-mod. type(KHR-45A), which is used as a heater tube material in the pyrolysis process, was evaluated for its carburizing properties. It was confirmed from the microstructural observation of the tubes that the volume fraction of carbide increased and that the coarsening of Cr-carbide generated as a degree of carburization increased. The depth of the hardened layer, which is similar to the thickness of the carburized region of each specimen, due to carburization is confirmed by measurement of the micro-Vickers hardness of the cross section tube, which thickness is similar to that of the carburized region of each specimen. Two types of chromium carbides were identified from the EBSD (electron back-scattered diffraction) image and the EDS (energy-dispersive spectroscopy) analysis: Cr-rich $M_{23}C_6$ in the outer region and Cr-rich $M_7C_3$ in the inner region of tubes. The EDS analysis revealed a correlation between the ferromagnetic behavior of the tubes and the chromium depletion in the matrix. The chromium depletion in the austenite matrix is the main cause of the magnetization of the carburized tube. The method used currently for the measurement of the carburization of the tubes is confirmed; carburizing evaluation is useful for magnetic flux density measurement. The volume fraction of the carbide increased as the measuring point moved into the carburized side; this was determined from the calculation of the volume fraction in the cross-section image of the tubes. These results are similar to the trends of carburization measurement when those trends were evaluated by measurement of the magnetic flux density.