• 제목/요약/키워드: Pyridyl-carboxylate terminals

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A Manganese Coordination Polymer and a Palladium Molecular Compound of 3-Pyridinepropionic acid (HL): [MnL2(H2O)2] and trans-[Pd(HL)2Cl2]

  • Im, Seo Young;Lee, Soon W.
    • Bulletin of the Korean Chemical Society
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    • 제34권10호
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    • pp.2947-2952
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    • 2013
  • Three coordination polymers, [$ML_2(H_2O)_2$] (M = Co (1), Ni (2), Mn (3)), were prepared from metal acetates ($M(CH_3COO)_2{\cdot}4H_2O$) and 3-pyridinepropionic acid ($HL=(3-py)-CH_2CH_2COOH$) by solvent-layer methods. By contrast, a discrete molecular compound, trans-[$Pd(HL)_2Cl_2$] (4), was synthesized by replacing benzonitrile (PhCN) ligands in trans-[$Pd(PhCN)_2Cl_2$] with HL under microwave-heating conditions. Compounds 1-3 have a 2D framework, and compound 4 contains a square-planar Pd metal.