• Title/Summary/Keyword: Pyramidal structure

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Fabrication of Si Inverted Pyramid Structures by Cu-Assisted Chemical Etching for Solar Cell Application (결정질 실리콘 태양전지의 효율개선을 위한 실리콘 역 피라미드 구조체 최적화)

  • Park, Jin Hyeong;Nam, Yoon-Ho;Yoo, Bongyoung;Lee, Jung-Ho
    • Journal of the Korean institute of surface engineering
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    • v.50 no.5
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    • pp.315-321
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    • 2017
  • Antireflective pyramid arrays can be readily obtained via anisotropic etching in alkaline solution (KOH, NaOH), which is widely used in crystalline-Si (c-Si) solar cells. The periodic inverted pyramid arrays show even lower light reflectivity because of their superior light-trapping characteristics. Since this inverted pyramidal structures are mostly achieved using very complex techniques such as photolithograpy and laser processes requiring extra costs, here, we demonstrate the Cu-nanoparticle assisted chemical etching processes to make the inverted pyramidal arrays without the need of photolithography. We have mainly controlled the concentration of $Cu(NO_3)_2$, HF, $H_2O_2$ and temperature as well as time factors that affecting the reaction. Optimal inverted pyramid structure was obtained through reaction parameters control. The reflectance of inverted pyramid arrays showed < 10% over 400 to 1100 nm wavelength range while showing 15~20% in random pyramid arrays.

Synthesis and Characterization of Copper(Ⅱ) Complex Containing 2,2'-dipyridylbenzamide

  • 이동환;김병순;오영희;라명수;장원길
    • Bulletin of the Korean Chemical Society
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    • v.17 no.9
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    • pp.836-839
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    • 1996
  • A new copper complex containing 2,2'-dipyridylbenzamide(dpba), Cu(dpba)(NO3)2(CH3CN), has been synthesized and characterized. The crystal structure has been determined. Crystal data: space group P212121, Z=8, a=13.911(3) Å, b=16.813(3) Å, c=18.932(3) Å, V=4427.9(1) Å3 and R=0.0674 for 1716 reflections. The copper environment is square pyramidal containing acetonitrile in axial site. Spectroscopic properties has been characterized in solution state. The redox property of the Cu(dpba)(NO3)2 complex is different from that of corresponding copper-dpa complex.

An Image Synthesis Technique Based on the Pyramidal Structure and MAP Estimation Technique (계층적 Pyramid구조와 MAP 추정 기법을 이용한 Texture 영상 합성 기법)

  • 정석윤;이상욱
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.26 no.8
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    • pp.1238-1246
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    • 1989
  • In this paper, a texture synthesis technique based on the NCAR(non-causal auto-regressive) model and the pyramid structure is proposed. In order to estimate the NCAR model parameters accurately from a noisy texture, the MAP(maximum a posteriori) estimation technique is also employed. In our approach, since the input texture is decomposed into the Laplacian oyramid planes first and then the NCAR model is applied to each plane, we are able to obtain a good synthesized texture even if the texture exhibits some non-random local structure or non-homogenity. The usrfulness of the proposed method is demonstrated with seveal real textures in the Brodatz album. Finally, the 2-dimensional MAP estimation technique can be used to the image restoration for noisy images as well as a texture image synthesis.

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Synthesis, Properties, and X-ray Crystal Structure of Copper(II) Complex with Bis[(2-pyridyl)methyl]-2-(2-pyridyl)ethylamine (Bis[(2-pyridyl)methyl]-2-(2-pyridyl)ethylamine 구리(II) 착물의 합성, 성질 및 X-ray 결정구조)

  • Choi, Ki-Young
    • Journal of the Korean Chemical Society
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    • v.51 no.1
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    • pp.31-35
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    • 2007
  • The tripodal copper(II) complex [Cu(pmea)(H2O)](ClO4)2·H2O (1) (pmea = bis[(2-pyridyl)methyl]-2-(2-pyridyl)ethylamine) has been synthesized and structurally characterized by X-ray diffraction method. It crystallizes in the triclinic system P-1 with a = 9.9362(9), b = 15.7299(17), c = 18.0562(11) A, α = 68.760(8), β = 76.331(6), γ = 77.092(9)°, V = 2526.2(4) A3, Z = 2. Each copper atom reveals a distorted square pyramidal with three nitrogen atoms of the pmea ligand and water molecule occupying the basal plane and one nitrogen atom from the pyridine ring according the axial position. The cyclic voltammogram of 1 undergoes reversible one-electron oxidation to the CuIII and reversible one-electron reduction to the CuI.

Workability and Aging Behavior of Mg-Li-Al alloys (Mg-Li-Al합금의 가공성 및 시효거동)

  • Gang, Min-Cheol;Kim, Sun-Ho;Jeong, Hae-Yong;Lee, Jeong-Mu;Kim, Gyeong-Hyeon;Kim, In-Bae
    • Korean Journal of Materials Research
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    • v.2 no.6
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    • pp.389-397
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    • 1992
  • Workability and aging behavior of Mg-Li-Al alloys hate been investigated with variation of Li and Al contents. It was found that ${\alpha}$(HCP) + ${\beta}$(BCC) two phase structure reveals better workability than ${\alpha}$(HCP) single phase structure. Increase of workability is attributed to the additional slip on pyramidal and prism planes besides the slip on basal plane of HCP Mg. Workability of ${\alpha}$+${\beta}$ two phase structure is improved with increased amount of Al. Among alloys studied in the present study, reduction limit up to 62 % was obtained for Mg-8.08Li-4.26Al. MgL$i_2$Al(${\theta}$) aging precipitation was observed in ${\alpha}$+ ${\beta}$ two phase structure, while it was not in a single phase structure. Result of microhardness reveals peak hardness for ${\alpha}$ +${\beta}$ two phase structure due to $\theta$ precipitate in ${\theta}$ phase. In ${\alpha}$+${\beta}$ two phase Mg-Li-Al alloys, hardness increased with increasing amount of Al. It is believed that addition of Al raised the amount Al partition in u phase and ${\theta}$ precipitation in ${\beta}$ phase.

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Mechanism and Behavior Characteristic of Space Truss Unit for Post-tensioning

  • Kim, Jin-Woo;Kim, Sang-Jin
    • International Journal of Ocean Engineering and Technology Speciallssue:Selected Papers
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    • v.6 no.1
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    • pp.38-43
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    • 2003
  • This paper presents the results of a post-tensioning test and analysis of a pyramidal unit structure that is basic element for space structures. The behavior characteristics was analyzed and compared with the numerical analysis and the mechanism in test model was confirmed with geometrical analysis. The results of this paper show that the behaviors of space structures can be predicted in multi-directional Mero joint system. And the authors suggest the possibility of erection and shaping formation with comparatively small post-tensioning, and space structure with the mechanism should consider the nonlinear behavior due to large deformation.

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초경량 내부구조 접합판재 제작을 위한 금속내부구조의 설계 변수 분석

  • 정창균;윤석준;성대용;양동열;안동규
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2004.05a
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    • pp.64-64
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    • 2004
  • 최근 복합재료, 신소재 등 다양한 방법을 통해 빔(beam), 바(bar), 패널(panel) 등 초경량 구조재료가 개발되고 있다. 이중 금속 내부구조재를 가진 접합판재(Inner Structured and Bonded panel, ISB panel)은 3차원 형상의 내부구조재가 강성 및 강도를 증가시키는 반면, 부피의 대부분이 비어있어 비강도 및 비강성을 크게 개선시킨다 일반적으로 다양한 트러스 형태의 금속 내부구조물은 허니컴 형상의 내부구조와 유사한 정도로 기계적 특성이 우수하다.(중략)

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Synthesis and Characterization of $Ta_2Ni_3Se_8$

  • 동용관;도정환;윤호섭;이영주;신희균;류광경
    • Bulletin of the Korean Chemical Society
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    • v.16 no.9
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    • pp.870-873
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    • 1995
  • A new ternary transition-metal selenide, Ta2Ni3Se8 has been synthesized from a eutectic halide flux. The structure of this phase has been characterized by single crystal X-ray diffraction techniques. The compound crystallizes in the orthorhombic system (D2h9-Pbam, a= 14.788(4) Å, b= 10.467(3) Å, c=3.4563(8) Å) with two formula units in the unit cell. This compound adopts the Nb2Pd3Se8 structure type. Hence, there are two chains of edge-sharing selenium trigonal prisms centered by tantalum atoms and these chains are interconnected through two kinds of nickel atoms. Nickel occupies both square planar and square pyramidal sites as does palladium in Nb2Pd3Se8. Electrical conductivity measurements indicate that this material is semiconducting.

A Study on Spatial Composition and Elements of Ger Architecture in Mongolia (몽골 겔 건축의 공간구성과 구조적 구성요소에 관한 연구)

  • Chong, Geon Chai
    • Journal of the Korean Institute of Rural Architecture
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    • v.16 no.1
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    • pp.111-117
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    • 2014
  • The aim of this study is to find out the pattern of Ger form, inner spatial composition of Mongolian Ger house, and to take a dig at the structural or symbolic elements of nomadic architecture of Ger. To the point of view of corresponding to living and space of housing, remarkable characteristics of Ger Architecture is able to pull down and recombine the structures of nomadic house. Even though urbanization of Mongolia has spreading rapidly in a whole nation, most of people preserves traditional housing pattern within Ger. The ways of survey are to study of traditional home of Mongolia, and then field work at residence or mountain area in Ulan Bator and Gorkhi Terelj National Park area. This survey contains the form, size, structure, spatial composition of living space, structure, and materials. There are three results as follows: First, the form of Ger house is like a pyramidal or crown roof style to approximate to the round shape of it. Usually they had lived in nomadic way of life, so the Ger had a movable and flexible structure. Second, the Ger is easy to build up and deconstruct to move or find a new pasture. Third, the Mongolian Ger structure is composed by mainly five elements that are Khana, Khaalga, Toono, Bagana, and Uni. It has a hierarchy of internal spaces which are classified to gender, orientation, and property.

Formation of lotus surface structure for high efficiency silicon solar cell (고효율 실리콘 태양전지를 위한 lotus surface 구조의 형성)

  • Jung, Hyun-Chul;Paek, Yeong-Kyeun;Kim, Hyo-Han;Eum, Jung-Hyun;Choi, Kyoon;Kim, Hyung-Tae;Chang, Hyo-Sik
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.20 no.1
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    • pp.7-11
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    • 2010
  • The reduction of optical losses in mono-crystalline silicon solar cell by surface texturing is a critical step to improve the overall cell efficiency. In this study, we have changed the sub-micrometer structure on the micrometer pyramidal structure by 2-step texturing. The Ag particles were coated on the micrometer pyramid surface in $AgNO_3$ solution, and then the etching with hydrogen fluoride and hydrogen peroxide created even smaller nano-pyramids in these pyramids. As a result, we observed that the changes of size and thickness of nano structure on pyramidal surface were determined by $AgNO_3$ concentration and etching time. Using 2-step texturing, the surface of wafers is etched to resemble the rough surface of a lotus leaf. Lotus surface can reduce average reflectance from 10% to below 3%. This reflectance is less than conventional textured wafer including anti-reflection coating.