• Title/Summary/Keyword: Pure lead

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Optimum Dosage of Fenton's Reagent for the Dyeing Wastewater by the Different Conditions of Biological Treatment as the Pre-treatment Process (염색폐수의 생물학적 전처리 조건변화에 의한 최적 펜톤시약 투입량 결정에 관한 연구)

  • Bea Joan-Sam;Lee Sang-Ho
    • Journal of Environmental Science International
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    • v.14 no.7
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    • pp.683-689
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    • 2005
  • The consecutive combination process of a biological process as the pre-treatment and a chemical process as the post-treatment is applied for the dyeing wastewater. The poor efficiency of biological treatment using pure oxygen makes the chemical treatment cost high. It is necessary to improve the efficiency of biological treatment in order to reduce the cost of chemical treatment. The purpose of this paper is to find the minimum dose of chemical reagent to fit the Discharged Water Quality Standards for the different biological treatment effluents. Results revealed that the minimum dosage of Fenton's reagent lead to save the cost of chemical treatment based on the guideline dose in the treatment plant. The possible maximum saving reagents was up to $70\%$ for the effluent of the pilot plant packed with the carrier imbedded microorganisms which were selected from the present treatment plant.

Preparation of $Pb(Sc_{1/2}Ta_{1/2})O_3$, by the molten salt synthesis method (용융염 합성법에 의한 $Pb(Sc_{1/2}Ta_{1/2})O_3$의 제조)

  • Park, Kyung-Bong;Kim, Tae-Huei
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.15 no.3
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    • pp.99-103
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    • 2005
  • Lead scandium tantalate powders were prepared by a molten salt synthesis method using NaCl-KCl as a flux. Variations in phase formation and particle morphology were investigated for the temperature range from $700^{\circ}C\;to\;800^{\circ}C$. $Pb(Sc_{1/2}Ta_{1/2})O_3$, with pure perovskite phase was formed at $750^{\circ}C$ fur 2 hrs and the prepared powder had the cubic-like morphology and the average particle size below $0.5{\mu}m$. The results were discussed with respect to DTA, X-ray diffraction, and microstructural characterization data.

An Ecological Study on the Flora of Bijin Island (비진도 식물상에 관한 생태학적 연구)

  • Kim, Chang Ho;Kwang Seung Lee;Kyu Ha Park
    • The Korean Journal of Ecology
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    • v.5 no.4
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    • pp.164-175
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    • 1982
  • This paper contains the results obtained by the ecological investigation in Bijin island. The investigation was conducted during 3 dyas from Aug. 3 to Aug. 5, 1981. The results are followings. The tracheophyta of this island was recoreded as 64 families, 128 genera, 142 species, 21 varieties and 2 forma. Twenty eight species of ever-green broad-leaved trees comprising Gardenia jasminoides for. grandiflora, Castanopsis cuspidata var. thunbergii, Camellia japonica, etc. wad distributed in the southern area of the island. And there was the wind-break forest mainly consisting of aged Machilus thunbergii, Celtis sinensis and Zelkova serrata in the northern area. The northern area dominated by the second forest of Pinus thunbergii, where the whole residents lead their lives, shows the high population density and pure farming rate, so the natural degree is low. The other hand, there was the well-preserved forest of broad-leaved trees containing Zelkoba serrata. Acer palmatum and Quercus serrata, etc. in southern area having a steep peak, Seonyudai, and no resident. So, the potential vegetation of this island is assumed as the forest of ever-green broad-leaved trees which belongs to the forest of subtropics.

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Minimum detectable activity of plastic scintillator for in-situ beta measurement system in ground water

  • Choi, Woo Nyun;Lee, UkJae;Bae, Jun Woo;Kim, Hee Reyoung
    • Nuclear Engineering and Technology
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    • v.51 no.4
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    • pp.1169-1175
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    • 2019
  • The minimum detectable activity (MDA) value was derived according to the flow rate of the sample and degree of amplification of the device by sending the sample directly from the collection site to the detection part through a pump. This method can lead to reduction in time and cost compared to the existing measurement method that uses a pre-treatment process. In this study, experiments were conducted on $^3H$ and $^{90}Sr$, which are the major pure beta-emitting radionuclides, by setting the sample flow rate and the amplification gain as factors. The MDA values were derived according to the flow rates, considering that the flow rate can affect the MDA values. There were no change in the MDA under different flow rates of 0, 600, 800, and 1000 mL/min. Therefore, it was confirmed that the flow rate may not be considered when collecting samples for monitoring in actual field. As the degree of amplification of the amplifier increased, the time required to reach the target MDA decreased. When the amplification was quadrupled, the detection efficiency increased by approximately 23.4 times, and the time to reach the MDA decreased to approximately 1/550 times. This method offers the advantage of real-time on-site monitoring.

Characterization of a carbon black rubber Poisson's ratio based on optimization technique applied in FEA data fit

  • Lalo, Debora Francisco;Greco, Marcelo;Meroniuc, Matias
    • Structural Engineering and Mechanics
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    • v.76 no.5
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    • pp.653-661
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    • 2020
  • The paper presents a study regarding rubber compressibility behavior. The objective is to analyze the effect of compression degree of rubber on its mechanical properties and propose a new methodology based on reverse engineering to predict compressibility degree based on uniaxial stretching test and Finite Element Analysis (FEA). In general, rubbers are considered to be almost incompressible and Poisson's ratio is close to 0.5. Since this property is intimately related to the rubber packing density, little changes in Poisson's ratio can lead to significant changes regarding mechanical behavior. The deviatory hyperelastic constants were obtained through experimental data fitting by least squares method for the most relevant constitutive models implemented in commercial software Abaqus, such as: Neo-Hooke, Mooney-Rivlin, Ogden, Yeoh and Arruda-Boyce, whereas the hydrostatic part was determined through an optimization algorithm implemented in the Abaqus environment by Python scripting. The simulation results presented great influence of the Poisson's ratio in the rubber specimen mechanical behavior mainly for high strain levels. A conventional pure volumetric compression test was also carried out in order to compare the results obtained by the proposed methodology.

Interatomic Potential Models for Ionic Systems - An Overview (이온 결합 물질에 대한 원자간 포텐셜 모델)

  • Lee, Byeong-Joo;Lee, Kwang-Ryeol
    • Korean Journal of Metals and Materials
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    • v.49 no.6
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    • pp.425-439
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    • 2011
  • A review of the development history of interatomic potential models for ionic materials was carried out paying attention to the way of future development of an interatomic potential model that can cover ionic, covalent and metallic bonding materials simultaneously. Earlier pair potential models based on fixed point charges with and without considering the electronic polarization effect were found to satisfactorily describe the fundamental physical properties of crystalline oxides (Ti oxides, $SiO_2$, for example) and their polymorphs, However, pair potential models are limited in dealing with pure elements such as Ti or Si. Another limitation of the fixed point charge model is that it cannot describe the charge variation on individual atoms depending on the local atomic environment. Those limitations lead to the development of many-body potential models(EAM or Tersoff), a charge equilibration (Qeq) model, and a combination of a many-body potential model and the Qeq model. EAM+Qeq can be applied to metal oxides, while Tersoff+Qeq can be applied to Si oxides. As a means to describe reactions between Si oxides and metallic elements, the combination of 2NN MEAM that can describe both covalent and metallic elements and the Qeq model is proposed.

The Overall Performance Improvement of Microbial Fuel Cells Connected in Series with Dairy Wastewater Treatment

  • Choudhury, Payel;Bhunia, Biswanath;Bandyopadhyay, Tarun Kanti;Ray, Rup Narayan
    • Journal of Electrochemical Science and Technology
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    • v.12 no.1
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    • pp.101-111
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    • 2021
  • To improve the potential of single chamber microbial fuel cells (SCMFCs) as an applicable technology, the main challenge is a practical application for larger scales bioenergy production from potent exoelectrogenic microorganism with real dairy wastewater. To increase power generation, three individual MFCs were together operated in series best under the fed batch condition for 15 days. The volume of MFC 1 and MFC 2 is "300 mL" and MFC 3 is "500 mL" respectively. The individual MFCs 1, MFC 2 and MFC 3 gives an open circuit voltage of 0.60 V, 0.66 V and 0.55 V and result in total working voltage when connected in series of 1.745V, which lead an LED to glow. The maximum power densities obtained from MFC 1, MFC 2 and MFC 3 are 62 mW/㎡, 50 mW/㎡ and 45 mW/㎡ (normalized to the surface area of the anodic electrode, which was 50 ㎠ for all three MFCs), and corresponding to current densities of 141 mA/㎡, 155 mA/㎡ and 123 mA/㎡, respectively. Therefore this work suggests the cheapest way to connect microbial fuel cells in series to gain power with the lowest operating cost and chemical oxygen demand (COD) removal.

Effect of Coffee Grounds on Mechanical Behavior of Poly Propylene Composites

  • Vinitsa Chanthavong;M. N. Prabhakar;Dong-Woo Lee;Jung-Il Song
    • Composites Research
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    • v.36 no.4
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    • pp.264-269
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    • 2023
  • Spent coffee grounds (SCG) are a ubiquitous byproduct of coffee consumption, representing a significant waste management challenge, as well as an untapped resource for economic development and sustainability. Improper disposal of SCG can result in environmental problems such as methane emissions and leachate production. This study aims to investigate the physicochemical properties of SCG and their potential as a reinforcement material in polypropylene (PP) to fabricate an eco-friendly composite via extrusion and injection molding, with SCG filler ratios ranging from 5-20%. To evaluate the effect of SCG on the morphological and mechanical properties of the bio- composite, thermogravimetric analysis, SEM, tensile, flexural, and impact tests were conducted. The results demonstrated that the addition of SCG lead to a slight increase in brittleness of the composite but did not significantly affect its mechanical properties. Impressively, the presence of a significant organic component in SCG contributed to the enhanced thermal performance of PP/SCG composites. This improvement was evident in terms of increased thermal stability, delayed onset of degradation, and higher maximum degradation temperature as compared to pure PP. These findings suggest that SCG has potential as a filler material for PP composites, with the ability to enhance the material's properties without compromising overall performance.

BCTZ Addition on the Microstructure, Piezoelectric/Dielectric Properties and Phase Transition of NKLN-AS Piezoelectric Ceramics (BCTZ첨가가 NKLN-AS계 압전세라믹스의 미세구조와 압전/유전특성 및 상전이현상에 미치는 효과)

  • Lee, Woong-Jae;Ur, Soon-Chul;Lee, Young-Geun;Yoon, Man-Soon
    • Korean Journal of Materials Research
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    • v.22 no.1
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    • pp.35-41
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    • 2012
  • Presently, the most promising family of lead-free piezoelectric ceramics is based on $K_{0.5}Na_{0.5}NbO_3$(KNN). Lithium, silver and antimony co-doped KNN ceramics show high piezoelectric properties at room temperature, but often suffer from abnormal grain growth. In the present work, the $(Ba_{0.85}Ca_{0.15})(Ti_{0.88}Zr_{0.12})O_3$ component, which has relaxor ferroelectric characteristics, was doped to suppress the abnormal grain growth. To investigate this effect, Lead-Free $0.95(K_{0.5}Na_{0.5})_{0.95}Li_{0.05}NbO_3-(0.05-x)AgSbO_3-x(Ba_{0.85}Ca_{0.15})(Ti_{0.88}Zr_{0.12})O_3$[KNLN-AS-xBCTZ] piezoelectric ceramics were synthesized by ball mill and nanosized-milling processes in lead-Free $0.95(K_{0.5}Na_{0.5})_{0.95}Li_{0.05}NbO_3-(0.05-x)AgSbO_3$ in order to suppress the abnormal grain growth. The nanosized milling process of calcined powders enhanced the sintering density. The phase structure, microstructure, and ferroelectric and piezoelectric properties of the KNLN-AS ceramics were systematically investigated. XRD patterns for the doped and undoped samples showed perovskite phase while tetragonality was increased with increasing BCZT content, which increase was closely related to the decrease of TO-T. Dense and uniform microstructures were observed for all of the doped BCZT ceramics. After the addition of BCTZ, the tetragonal-cubic and orthorhombic-tetragonal phase transitions shifted to lower temperatures compared to those for the pure KNNL-AS. A coexistence of the orthorhombic and tetragonal phases was hence formed in the ceramics with x = 0.02 mol at room temperature, leading to a significant enhancement of the piezoelectric properties. For the composition with x = 0.02 mol, the piezoelectric properties showed optimum values of: $d_{33}$ = 185 pC/N, $k_P$ = 41%, $T_C=325^{\circ}C$, $T_{O-T}=-4^{\circ}C$.

Potency of cashew nut shell liquid in rumen modulation under different dietary conditions and indication of its surfactant action against rumen bacteria

  • Oh, Seongjin;Suzuki, Yasuyuki;Hayashi, Shusuke;Suzuki, Yutaka;Koike, Satoshi;Kobayashi, Yasuo
    • Journal of Animal Science and Technology
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    • v.59 no.11
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    • pp.27.1-27.7
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    • 2017
  • Background: Cashew nut shell liquid (CNSL) is an agricultural byproduct containing alkylphenols that has been shown to favorably change the rumen fermentation pattern only under experimentally fixed feeding conditions. Investigation of CNSL potency in rumen modulation under a variety of feeding regimens, and evidence leading to the understanding of CNSL action are obviously necessary for further CNSL applications. The objective of this study was to evaluate the potency of CNSL for rumen modulation under different dietary conditions, and to visually demonstrate its surfactant action against selected rumen bacteria. Methods: Batch culture studies were carried out using various diets with 5 different forage to concentrate (F:C) ratios (9:1, 7:3, 5:5. 3:7 and 1:9). Strained rumen fluid was diluted with a buffer and incubated with each diet. Gas and short chain fatty acid (SCFA) profiles were characterized after 18 h incubation at $39^{\circ}C$. Monensin was also evaluated as a reference additive under the same conditions. Four species of rumen bacteria were grown in pure culture and exposed to CNSL to determine their morphological sensitivity to the surfactant action of CNSL. Results: CNSL supplementation decreased total gas production in diets with 5:5 and 3:7 F:C ratios, whereas the F:C ratio alone did not affect any gas production. Methane decrease by CNSL addition was more apparent in diets with 5:5, 3:7, and 1:9 F:C ratios. An interactive effect of CNSL and the F:C ratio was also observed for methane production. CNSL supplementation enhanced propionate production, while total SCFA production was not affected. Monensin decreased methane production but only in a diet with a 1:9 F:C ratio with increased propionate. Studies of pure cultures indicated that CNSL damaged the cell surface of hydrogen- and formate-producing bacteria, but did not change that of propionate-producing bacteria. Conclusion: CNSL can selectively inhibit rumen bacteria through its surfactant action to lead fermentation toward less methane and more propionate production. As CNSL is effective over a wider range of dietary conditions for such modulation of rumen fermentation in comparison with monensin, this new additive candidate might be applied to ruminant animals for various production purposes and at various stages.