• Title/Summary/Keyword: Pure Metals

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Hydrogen Evolution Ability of Selected Pure Metals and Galvanic Corrosion Behavior between the Metals and Magnesium

  • Luo, Zhen;Song, Kaili;Li, Guijuan;Yang, Lei
    • Journal of Electrochemical Science and Technology
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    • v.11 no.4
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    • pp.323-329
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    • 2020
  • The cathodic hydrogen evolution ability of different pure metals and their long term galvanic corrosion behavior with pure Mg were investigated. The hydrogen evolution ability of pure Ti, Al, Sn and Zr is weak, while that of Fe, W, Cr, and Co is very strong. Initial polarization test could not completely reveal the cathodic behavior of the tested metals during long term corrosion. The cathodic hydrogen evolution ability may vary significantly in the long term galvanic tests for different metals, especially for Al whose cathodic current density reduced to 1/50 of the initial value. The anodic polarization shows that Al and Sn as alloying elements are supposed to provide relatively good passive effect for Mg alloy, while Ag can provide a slight passive effect and Zn has little passive effect.

The Effect of Pressure on the Phase Transformation in Fe-Ni-C Alloy and Pure Metals (Fe-Ni-C합금과 저융점 순금속의 상변태에 미치는 압력의 영향)

  • An, Haeng-Geun;Kim, Hak-Sin
    • Korean Journal of Materials Research
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    • v.10 no.6
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    • pp.392-397
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    • 2000
  • The effect of pressure on the phase transformation in Fe-30Ni-0.35C Alloy and pure metals was investigated by using PDSC(pressure differential scanning calorimeter). As the pressure increased from 1 atm to 60 atm, the $A_s$points of the ausformed martensite and the marformed martensite in Fe-30Ni-0.35C Alloy were lowered about $2~4^{\circ}C$ at reverse transformation. This is why the volume change came down at phase transition(from martensite to autenite). As the pressure increased from 1 atm to 60 atm, $A_f$ points were constant or slightly increased. This is due to the promotion of carbide precipitation with increasing pressure. The enthalpy change of the ausformed martensite in Fe-30Ni-0.35C Alloy was increased by 10~14J/g. The melting points of the pure metals, Se, Sn, Pb, Zn and Te were slightly increased with increasing pressure. The enthalpy changes of the pure metals at melting were little changed or slightly increased with increasing pressure.

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Electrochemical Corrosion Characteristics of the Intermetallic Compound NiTi from Pure Metals (금속간 화합물 NiTi와 순금속 니켈 및 티타늄의 전기화학적 부식 특성)

  • Lee, Kyu Hwan;Shin, Myung Chul
    • Analytical Science and Technology
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    • v.5 no.1
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    • pp.97-101
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    • 1992
  • Potentiodynamic corrosion tests were conducted to know the corrosion characteristics of the NiTi intermetallic compound composed of pure Ni and Ti in artificial saline. Tafel extrapolation and linear polarization technique show similar results. Corrosion current Icorr and corrosion rate was increased in the order of NiTi

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Recent Trend of Ultra-Pure Water Producing Equipment

  • Motomura, Yoshito
    • Proceedings of the Membrane Society of Korea Conference
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    • 1996.06a
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    • pp.121-147
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    • 1996
  • Since 1980, the water quality of ultra-pure water has been rapidly improved, and presently ultra-pore water producing equipment for 64Mbit is in operation. Table 1 shows the degree of integration of DRM and required water quality exlmple. The requirements of the ultra-pure water for 64Mbit are resistivity: 18.2 MQ/cm or higher, number of particulates: 1 pc/ml or less (0.05 $\mu$m or larger). bacteria count: 0.1 pc/l or less. TOC (Total Organic Carbon, index of organic snbstance) : 1ppb or less, dissolved oxygen: 5ppb or less, silica: 0.5ppb or less, heavy metal ions: 5ppb or less. The effect of metals on the silicon wafer has been well known, and recently it has been reported that the existence of organic substance in ultra-pure water is closely related to the device defect, drawing attention. It is reported that if organic substance sticks to the natural oxidation film, the oxide film remaims on the organic substance attachment in the hydrofluoric acid treatment (removal of natural oxidation film). The organic substance forms film on the silicon wafer, and harmful elements such as metals and N.P.S., components contained in the organic substance and the bad effect due to the generatinn of silicon carbide cannot be forgotten. In order to remove various impurities in raw water, many technological develoments (membrane, ion exchange, TOC removal, piping material, microanalysis, etc.) have been made with ultra-pure water producing equipment and put to practical use. In this paper, technologies put to practical use in recent ultra-pure vater producing equimeut are introduced.

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Sliding Wear Behavior of Pure Metal, Fe and Cu Having a Cubic Crystal System (입방정계 순 금속 Fe, Cu의 미끄럼 마멸 거동)

  • Yi, S.K.;Kim, Y.S.
    • Transactions of Materials Processing
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    • v.19 no.6
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    • pp.357-362
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    • 2010
  • Dry sliding wear behavior of pure Fe and Cu which have BCC and FCC crystal structure, respectively, was investigated. The wear characteristics of the pure metals with different crystal structure were compared. Dry sliding wear tests were carried out using a pin-on-disk wear tester at various loads under the constant sliding speed condition of 0.15 m/s against a silica ball at room temperature. Sliding distance was fixed as 600 m for all wear tests. Wear rate of a specimen was calculated by dividing the weight loss of the specimen after the test by the specific gravity and sliding distance. Worn surfaces and wear debris were analyzed by SEM. The wear of both pure Fe and Cu proceeded with surface deformation, resulting in similar wear rates despite of their structure difference under the current test conditions. Wear rates of both metals were low if the surface deformation due to wear forms thick surface-deformation layer that is strain hardened beneath the wearing surface. The pure Cu specimens showed a lot of oxides on the worn surface when tested at low loads less than 5 N, which resulted in very low wear rate.

Effect of Under Bump Metallization (UBM) on Interfacial Reaction and Shear Strength of Electroplated Pure Tin Solder Bump (전해 도금된 주석 솔더 범프의 계면 반응과 전단 강도에 미치는 UBM의 효과)

  • Kim, Yu-Na;Koo, Ja-Myeong;Park, Sun-Kyu;Jung, Seung-Boo
    • Korean Journal of Metals and Materials
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    • v.46 no.1
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    • pp.33-38
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    • 2008
  • The interfacial reactions and shear strength of pure Sn solder bump were investigated with different under bump metallizations (UBMs) and reflow numbers. Two different UBMs were employed in this study: Cu and Ni. Cu6Sn5 and Cu3Sn intermetallic compounds (IMCs) were formed at the bump/Cu UBM interface, whereas only a Ni3Sn4 IMC was formed at the bump/Ni UBM interface. These IMCs grew with increasing reflow number. The growth of the Cu-Sn IMCs was faster than that of the Ni-Sn IMC. These interfacial reactions greatly affected the shear properties of the bumps.

A Study on the Fabrication Process and Melt Infiltration of Salt Core in Squeeze Casting Method (스퀴즈캐스팅용 Salt Core의 제조 및 용탕침투성에 관한 연구)

  • Kim, Ki-Bae;Noh, Sang-Woo;Lee, Ho-In;Nam, Tae-Woon
    • Journal of Korea Foundry Society
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    • v.17 no.4
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    • pp.402-410
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    • 1997
  • Developing a salt core for squeeze casting process, two different salt cores(pure salt core and mixed salt core) were fabricated and investigated. Pure salt core was composed of 100% NaCl and mixed salt core was made by mixtures of NaCl with MgO(1%), $Na_2B_4O_7$(2%), and talc(1%) as a binder or a strengthening agent. Salt cores were compacted to various theoretical density, heat treated, and then squeeze-cast with molten Al alloy(AC8A). The compression strength of salt cores were measured and the squeeze-cast products were examined for shape retention, infiltration of molten metal into the cores, and microstructures. The shape of salt core compacted at above 75% of the theoretical density was maintained stably. The higher theoretical density of salt cores gave higher compression strength, and the compression strength of mixed salt core was higher than that of pure salt core. Namely at 90% theoretical density, the compression strength of mixed salt core was $6.3 kg/mm^2$, compared to $4.6 kgmm^2$ for pure salt core. At a squeeze casting pressure of $1000 kg/cm^2$, molten Al alloy was infiltrated into pure salt core of under 85% of the theoretical density. At squeeze casting pressure of $1000 kg/cm^2$, only mixed salt core above 90% of the theoretical density were valid, but the shape of the core was altered in the case of pure salt core at 90% of theoretical density. A key factor for developing a salt core for squeeze casting process was estimated as the ultimate compressive strength of salt core.

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The Effects of Relative Material Properties on the Friction and Wear Behavior of Pure Metals (순수금속의 재료물성치와 마찰.마멸특성에 대한 연구)

  • 황동환;성인하;김대은
    • Tribology and Lubricants
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    • v.14 no.2
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    • pp.10-20
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    • 1998
  • In this paper, the effects of material properties on the friction and wear behavior of pure metals are investigated. The sliding material pairs are selected based on their relative compatibility and relative hardness ratio of the specimen. The initial and steady-state friction coefficients are obtained in the experiments and the wear rates are quantitatively investigated. It is shown that the initial friction coefficient is affected by the hardness ratio of sliding materials. Furthermore, in steady state condition, neither hardness ratio nor compatibility has significant influence on the frictional behavior. As for wear, the ductility of the metal affects the wear particle generation process which in turn affects the frictional behavior. The findings of this research suggest that frictional interaction cannot be simply characterized by either compatibility or hardness ratio of the materials undergoing sliding contact.

SUBLAYER THICKNESS DEPENDENCE OF THE OPTICALPROPERTIES OF NI/TI AND Fe/Zr MULTILAERS

  • Lee, Y.P.;Kim, K.W.;Lee, G.M.;Rhee, J.Y.;Szymansky, B.;Dubowik, J.;Kucherenko, A.Yu.;Kudryavstev, Y.V.
    • Journal of the Korean Vacuum Society
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    • v.6 no.S1
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    • pp.70-74
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    • 1997
  • The study of the thickness dependence of the electron energy structure of Fe, Ni, Ti and Zr sublayers in Ni/Ti and Fe/Zr multilayers by using the experimental and computer simulated optical spectroscopy has been performed. A series of Ni/Ti and Fe/Ze multiayered films (MLF) with a bilayer period of 0.5 - 30 nm and constant (Ni/Ti) / different (Fe/Zr) sublayer thickness ratios were prepared by using computer-controlled double-pair target face-to-face sputtering onto a glass substrate at room temperature (RT) Computer simulation of the resulting optical properties of these MLF was carried out by solving of multireflection problem with a matrix method assuming either "sharp" interfaces resulting in rectangular depth profiles of the components or "mixed" (alloy-like) interfaces of variable thickness between pure-metal sublayers. Optical constants of pure bulk metals as well as equiatomic alloy interfaces were employed in these simulations. It was shown that the difference between experimental and simulated optical properties of the investigated MLF increases with decrease in sublayer thickness. This result allows to conclude that the electronic structures of sublayers below 4-5 nm thickness in mlf differ from the corresponding bulk metals.ponding bulk metals.

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An Experimental Study on the Springback Characteristics of Sheet Metals (금속판재(金屬板材)의 스프링백 특성(特性)에 관한 실험적(實驗的) 연구(硏究))

  • Park, Jung Wan;Kim, Hyung Jong
    • Journal of Industrial Technology
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    • v.18
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    • pp.217-223
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    • 1998
  • The springback characteristics of some sheet metals such as commercially pure aluminium, mild steel and stainless steel in a forming process are investigated experimentally. Three geometrical parameters for evaluating springback in the plane-strain draw-bending, which was a benchmark model of NUMISHEET '93 conference, are defined. The measurement of the springback parameters is carried out accurately and easily by using an image analysis system developed in this study. The effects of the blank holding pressure and tensile strength of the material on the springback are also examined.

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