• Title/Summary/Keyword: Pure Co

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Poly(n-butyl acrylate-co-methyl methacrylate) and Poly(n-butyl acrylate-co-styrene)/Silicate Nanocomposites Prepared by Emulsion Polymerization

  • Park, Yeong-Suk;Chung, In-Jae
    • Macromolecular Research
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    • v.11 no.6
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    • pp.425-430
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    • 2003
  • Two types of poly(n-butyl acrylate) copolymer/silicate nanocomposites have been produced: poly(n-butyl acrylate-co-methyl methacrylate) [P(BA-co-MMA)]/silicate nanocomposites and poly(n-butyl acrylate-co-styrene) [P(BA-co-ST)]/silicate nanocomposites. The P(BA-co-MMA)/silicate nanocomposites shows the exfoliated structures but a P(BA-co-ST)/silicate nanocomposites have intercalated structures, because the BA/MMA comonomer has a higher polarity (e-value in Q-e scheme) than the BA/ST comonomer. The BA/MMA comonomer expanded the interlayer space of the silicate wider than did the BA/ST comonomer. The thermal degradation onset point of the P(BA-co-MMA)/silicate nanocomposites was 43$^{\circ}C$ higher than that of pure P(BA-co-MMA). P(BA-co-MMA)T5%, P(BA-co-MMA)T10%, and P(BA-co-MMA)T20% exhibit 134,302, and 195% increases, respectively, in their storage moduli at -20$^{\circ}C$ relative to the pure copolymer.

Structure of Edge Flame in a Methane-Oxygen Mixing Layer (메탄/순산소 혼합층에서 edge flame의 구조)

  • Choi, S.K.;Kim, J.;Chung, S.H.;Kim, J.S.
    • 한국연소학회:학술대회논문집
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    • 2006.04a
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    • pp.149-156
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    • 2006
  • Structure of edge flame established in a mixing layer, formed between two uniformly flowing pure $CH_4$ and pure $O_2$ streams, is numerically investigated by employing a detailed methane-oxidation mechanism. The numerical results exhibited the most outstanding distinction of using pure oxygen in the fuel-rich premixed-flame front, through which the carbon-containing compound is found to leak mainly in the form of CO instead of HC compounds, contrary to the rich $CH_4-air$ premixed flames in which $CH_4$ as well as $C_2H_m$ leakage can occur. Moreover, while passing through the rich premixed flame, a major route for CO production, in addition to the direct $CH_4$ decomposition, is found to be $C_2H_m$ compound formation followed by their decomposition into CO. Beyond the rich premixed flame front, CO is further oxidized into $CO_2$ in a broad diffusion-flame-like reaction zone located around moderately fuel-rich side of the stoichiometric mixture by the OH radical from the fuel-lean premixed-flame front. Since the secondary CO production through $C_2H_m$ decomposition has a relatively strong reaction intensity, an additional heat-release branch appears and the resulting heat-release profile can no longer be seen as a tribrachial structure.

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Structure of Edge Flame in a Methane-Oxygen Mixing Layer (메탄/순산소 혼합층에서 Edge Flame의 구조)

  • Choi, S.K.;Kim, J.;Chung, S.H.;Kim, J.S.
    • Journal of the Korean Society of Combustion
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    • v.11 no.1
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    • pp.19-26
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    • 2006
  • Structure of edge flame established in a mixing layer, formed between two uniformly flowing pure $CH_4$ and pure $O_2$ streams, is numerically investigated by employing a detailed methane-oxidation mechanism. The numerical results exhibited the most outstanding distinction of using pure oxygen in the fuel-rich premixed-flame front, through which the carbon-containing compound is found to leak mainly in the form of CO instead of HC compounds, contrary to the rich $CH_4-air$ premixed flames in which $CH_4$ as well as $C_2H_m$ leakage can occur. Moreover, while passing through the rich premixed flame, a major route for CO production, in addition to the direct $CH_4$ decomposition, is found to be $C_2H_m$ compound formation followed by their decomposition into CO. Beyond the rich premixed flame front, CO is further oxidized into $CO_2$ in a broad diffusion-flame-like reaction zone located around moderately fuel-rich side of the stoichiometric mixture by the OH radical from the fuel-lean premixed-flame front. Since the secondary CO production through $C_2H_m$ decomposition has a relatively strong reaction intensity, an additional heat-release branch appears and the resulting heat-release profile can no longer be seen as a tribrachial structure.

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A Study on Extinguishing Concentration of K2CO3-Zeolite Composites (K2CO3가 흡착된 합성제올라이트 구조체의 소화농도에 관한 연구)

  • Kim, Seung-Il;Shin, Chang-Sub
    • Fire Science and Engineering
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    • v.26 no.4
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    • pp.42-47
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    • 2012
  • In the study, fire extinguishing concentration of $K_2CO_3$-Zeolite composite was measured. Zeolite composite is a porous adsorbent which has small particle size, low density and anti-catalytic effect. Scanning Electron Microscopy, X-Ray diffraction and thermal analysis were also conducted to investigate the structural properties of composite. The result showed that despite of weight ratio, the extinguishing concentration of the composite was lower than pure $K_2CO_3$. The extinguishing concentration of $K_2CO_3$-Zeolite composite which has weight ratio of 7 : 3 was 5.72 times lower than that of pure $K_2CO_3$ and 1.1 times lower than that of ABC powder. The SEM and XRD patterns showed that $K_2CO_3$ was adsorbed on the Zeolite properly, and through the thermal analysis, it was founded that the composite is more effective extinguishing agent than pure $K_2CO_3$.

CO gas sensing characteristics of ZnO and ZnO-CuO thick films prepared by acquous precipitation (액상침전법으로 제조된 ZnO와 ZnO-CuO후막의 일산화탄소 감응특성)

  • 전석택;최우성;백승철
    • Electrical & Electronic Materials
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    • v.9 no.9
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    • pp.925-932
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    • 1996
  • Using the d.c. 2-probe method, we have examined the temperature dependence of CO gas sensitivity of pure ZnO and ZnO CuO thick films prepared by the acqueous precipitation. At 200ppm CO gas, pure ZnO thick film shows the maximum sensitivity of -6.5 at 300.deg. C. On the other hand, the maximum sensitivity of 1-5 mol% and 10-15 mol% CuO added ZnO thick films are 2.8-2.5 and 1.6, respectively. Therefore, the sensitivity of pure ZnO thick film is about three times larger than those of ZnO-CuO thick films. We suggest that the promotion of maximum sensitivity is caused by low packing and the increase of chemical adsorptions for $O_{2}$ gas.

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A Computer Simulation Study on the Separation Process for Electronic Grade, Highly Pure Carbon Dioxide through a Cryogenic Distillation (심냉 증류를 통한 전자급 고순도 이산화탄소의 분리 공정에 대한 전산 모사 연구)

  • ILSU PARK;HUNGMAN MOON;JUNGHO CHO
    • Transactions of the Korean hydrogen and new energy society
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    • v.34 no.1
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    • pp.83-89
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    • 2023
  • In this study, a computer simulation work has been performed for the separation of electronic grade highly pure carbon dioxide more than 7 N purity through a cryogenic distillation process. For the cold utility as a cooling medium for a condenser of the cryogenic distillation column, propylene was utilized as a refrigerant in the vapor-recompression refrigeration cycle. Through this work, it was concluded that the cryogenic distillation column with two stage compression and refrigeration cycle were essential to obtain a highly-pure liquefied CO2.

Stabilizing Technology of Pure Vitamin A using Triple Matrix Capsulation

  • Kim, In-Young;Lee, Young-Gue;Seong, Bo-Reum;Lee, Min-Hee;Lee, So-Ra;Choi, Seong-Ho
    • Journal of the Korean Applied Science and Technology
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    • v.32 no.4
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    • pp.694-701
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    • 2015
  • In order to get stabilized pure retinol in skin care cosmetics, developing the three layered matrix bead capsules were studied. This study relates to make a cosmetic composition using the three layered matrix capsule that could increase the stability of the active ingredient. A primary encapsulation, vitamin A (pure retinol) of active ingredient was perfectly capsulated into water-in-oil (Water-in-Oil: W/O) emulsion vesicle using PEG-10 dimethicone copolyol emulsifier. A secondary encapsulation of multiple emulsion of the water-in-oil-in-water (W/O/W) emulsion blending W/O emulsion using sucrose distearate of surfactant was developed using homogenizing emulsifying system. Pure retinol of active ingredient was stably capsulized to inside the W/O/W-multiple emulsion in order to load the triple matrix capsulation. By coating it with a polymer matrix base, encapsulated in the triple layered type, which were developed bead encapsulation of 2~10mm uniformly size. To show beautifully appearance capsulated bead type, these finish particles in this triple matrix layer were developed as a gold, green, dark brown, silver and blue color were encapsulated in the bead types. Structural particle certification of triple matrix layer was observed through SEM analysis. Stability of pure retinol was remained stable more than 99.7% for 30 days at $42^{\circ}C$ incubating conditions compared with non-capsule. This technology was applied in different formulations such as various sizes and colors that by applying the skin care cosmetics. In the future, this technology to encapsulate an unstable active ingredient, we expect to be expanded this application in the food and drug as a time delivery system.

Effect of the lubrication oil on heat transfer and pressure drop characteristics of supercritical carbon dioxide in a microfin tube (마이크로핀관내 냉동기유가 초임계 이산화탄소의 열전달과 압력강하에 미치는 영향)

  • Ku, Hak-Keun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.13 no.4
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    • pp.1440-1446
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    • 2012
  • This paper presents an experimental study of heat transfer and pressure drop characteristics of supercritical carbon dioxide with PAG inside a horizontal microfin tube. Heat transfer coefficient and pressure drop gradients were measured at 10 MPa in pressure and 520 kg/$m^2s$ in mass flux with variation of PAG mass concentration from 0.06% to 2.26%. The tendencies of both heat transfer and frictional pressure drop characteristics show the same as those of pure $CO_2$ up to 0.3% in PAG mass concentration. In case of 2.26% in PAG mass concentration, measured heat transfer coefficients showed 50% lower than those of pure $CO_2$ near the pseudocritical temperature and measured frictional pressure drop gradients show 1.6 times higher in comparison with those of pure $CO_2$ at $60^{\circ}C$ in $CO_2$ bulk temperature.

Flow and Heat Transfer Characteristics of $CO_2$/Oil Mixtures in a Circular Tube

  • Kang, Byung-Ha;Lim, Dong-Seop
    • International Journal of Air-Conditioning and Refrigeration
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    • v.16 no.4
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    • pp.117-123
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    • 2008
  • The present study is directed at flow and heat transfer of $CO_2$ and oil mixtures in a circular tube. PAG and POE oils are considered in this study. Flow characteristics of $CO_2$ and oil mixtures have been investigated by flow visualization. Pressure drop has been measured in the range of operating mass flow rate from 0.1 to 0.4 kg/min in a circular tube. Heat transfer characteristics of $CO_2$/oil mixtures have been investigated using a counterflow heat exchanger. In case of pure liquid $CO_2$ as well as $CO_2$ and POE mixtures, flow are seen to be uniform so that $CO_2$ and POE oil are still miscible even at flowing state. However, it is found that $CO_2$ and PAG are not miscible. Pressure drop of $CO_2$/PAG mixtures are much higher than that of $CO_2$/POE mixtures as well as pure $CO_2$ at a fixed mass flow rate. As the concentration of POE oil is increased from 0 to 5 wt%, pressure drop is increased. However, heat transfer rate and heat transfer coefficient of $CO_2$/POE mixtures are much higher than that of $CO_2$/PAG mixtures. The f-factor correlation and Nusselt number correlation for $CO_2$/POE oil mixtures are suggested in this paper.