• Title/Summary/Keyword: Pulsed field gradient

검색결과 22건 처리시간 0.02초

Pulsed (Field) Gradient Spin Echo (PGSE) NMR에 의한 ADS/OTAC 혼합 수용액에서의 콜로이드 회합체의 자가 확산 계수 (Self-Diffusion Coefficients of Colloidal Association Structures in ADS/OTAC Mixed Aqueous Solutions by Pulsed (Field) Gradient Spin Echo-NMR)

  • 김홍운;임경희;김은희;정재준
    • 한국응용과학기술학회지
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    • 제19권4호
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    • pp.339-348
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    • 2002
  • Self-diffusion coefficients of colloidal ass9Ciation structures in the aqueous solutions of anionic ammonium dodecyl sulfate (ADS) and cationic octadecyltrimethylammonium chloride (OTAC) surfactants were measured by pulsed-gradient spin echo NMR. The results were interpreted on the basis of the ADS/OTAC/water phase diagram. Crossing the phase boundaries, significant changes in self diffusion coefficients were observed and well correlated to the phase diagram. For the micelles their apparent radii were obtained from Stokes-Einstein equation. Their values were 15 for the ADS micelles and 54 ${{\AA}}$ for the OTAC micelles, respectively. For vesicles which were formed spontaneously at different relative amounts of the surfactants and total surfactant concentrations, the radius was measured as 50 to 200 nm. This result is in fair agreement with those by TEM and light scattering.

Cross Correlated Effects of Radiation Damping and the Distant Dipolar Field with a Pulsed Field Gradient in Solution NMR

  • Chung Kee-Choo;Ahn Sang-Doo
    • 한국자기공명학회논문지
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    • 제10권1호
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    • pp.46-58
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    • 2006
  • With a simple pulse sequence ($\pi/2$-{gradient, duration T}-acquisition) in solution NMR, detected signal has slowly grown up to percents of the equilibrium magnetization. The source of this unusual resurrection of dephased magnetization after a crushed gradient is cross-correlated effects of radiation damping and the distant dipolar field, which has been demonstrated by a numerical simulation and theoretical analysis.

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단일층 $d^2B_{z}$/dxdy SQUID 2차 미분기 설계 및 제작 (Fabrication of sing1e layer $d^2B_{z}$/dxdy second-order SQUID gradiometer)

  • 황윤석;박승문;이순걸;김인선;박용기
    • Progress in Superconductivity
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    • 제4권2호
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    • pp.109-113
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    • 2003
  • We have developed a planar-type single layer second-order $high-T_{c}$ SQUID gradiometer, which can detect the $d^2$$B_{z/}$dxdy of the second-order field gradient. This SQUID gradiometer consists of four-way 'clover-leaf' pick-up loops and is coupled directly to a 4-junction dc SQUID in such a way that the coupling polarity of the two diagonal loops is opposite to that of the other two loops. The pickup loops are intrinsically balanced for both uniform field and the 1 st-order field gradient. The $YBa_2$$Cu_3$$O_{7}$ thin film was made by pulsed laser deposition method on $SrTiO_3$ single crystal substrate and patterned by photolithography with Ar ion milling technique. Response of this gradiometer was tested for both uniform field and the 2nd-order field gradient. Details of the design, fabrication, and results will be discussed.

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NOE 실험의 대용으로 응용될 수 있는 PFG Long-range COSY NMR 실험 (Application of Pulsed Field Gradient Long-range COSY-NMR for the Assignment of Geminal Protons on Rigid System: supplemental method of NOE Experiment)

  • 이석근
    • 분석과학
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    • 제18권1호
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    • pp.85-88
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    • 2005
  • Antiphase character of cross peaks in long-range COSY is modulated by changing the fixed delay time and used to assign diastereotopic methylene protons on rigid systems which could produce unpredictable NOE phenomena because of complicate coupling spins.

PCAS공정에 의한 고융점 소결체 열전달 해석 및 특성분석 (Thermal Characteristic Simulation and Property Evaluation of High Melting Point Materials by Pulsed Current Activated Sintering Process)

  • 남효은;장준호;박현국;오익현
    • 센서학회지
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    • 제26권3호
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    • pp.214-222
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    • 2017
  • In this study, the effects of internal heat treatment associated sintering temperatures were simulated by the Finite Element Method (FEM). The sintering mechanism of pulsed current activated sintering process (PCAS) is still unclear because of some unexplainable heat transfer phenomena in coupled multi-physical fields, as well as the difficulty in measuring the interior temperatures of metal powder. We have carried out simulation study to find out thermal distributions between graphite mold and Ruthenium powder prior to PCAS process. For PCAS process, heating rate was maintained at $100^{\circ}C/min$ the simulation indicates that the sintering temperature range was between $1000^{\circ}C$ to $1300^{\circ}C$ under 60 MPa. The heat transfer inside the Ruthenium sintered-body sample was modelled through the whole process in order to predict the minimum interior temperature. Thermal simulation shows that the interior temperature gradient decreased by graphite punch length and calculation results well agreed with the PCAS field test results.

고전압 펄스 전기장 처리에 의한 Saccharomyces cerevisiae의 생리적 변화 (Physiological Changes of Saccharomyces cerevisiae by High Voltage Pulsed Electric Field Treatments)

  • 박희란;윤소정;박한설;신정규
    • 한국식품과학회지
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    • 제45권5호
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    • pp.590-597
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    • 2013
  • 고전압 펄스 전기장 기술은 가열 공정을 대체할 수 있는 비가열 살균기술로서 꾸준한 연구가 이루어지고 있는 기술이다. 본 실험에서는 미생물의 생리적 측면에서 고전압 펄스 전기장 처리에 의한 효모의 생리적 변화를 살펴보았다. 내염성의 변화를 측정한 결과 사멸하지 않은 세포의 90-99% 이상이 세포 손상에 의해 내염성을 소실하였으며, 내염성을 회복하는데 약 4-6시간의 시간이 걸렸다. 고전압 펄스 전기장 처리 초기에는 세포 내외의 pH 구배(${\Delta}pH$)가 차이가 컸으나 처리시간이 증가함에 따라 그 차이가 감소하였다. 이는 세포의 pH 항상성을 유지시키는 $H^+$-traslocation 기능을 담당하고 있는 $H^+$-ATPase 활성이 소실되었거나 세포막 자체가 손상되어 pH 항상성을 잃어버렸기 때문으로, 이는 고전압 펄스 전기장 처리한 세포의 $H^+$-ATPase의 활성이 초기부터 크게 감소하는 것으로 확인할 수 있었다. 또한 세포의 해당활성이 고전압 펄스 전기장 처리에 의해 크게 감소하여 세포의 대사 기능이 손상되는 것을 확인하였다.