• Bulletin of the Korean Chemical Society
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• 제24권6호
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• pp.864-880
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• 2003

A unified picture for magnetism, superconductivity, quantum optics and other properties of molecule-based materials has been presented on the basis of effective model Hamiltonians, where necessary parameter values have been determined by the first principle calculations of cluster models and/or band models. These properties of the matetials are qualitatively discussed on the basis of the spin and pseudo-spin Hamiltonian models, where several quantum operators are expressed by spin variables under the two level approximation. As an example, ab initio broken-symmetry DFT calculations are performed for cyclic magnetic ring constructed of 34 hydrogen atoms in order to obtain effective exchange integrals in the spin Hamiltonian model. The natural orbital analysis of the DFT solution was performed to obtain symmetry-adapted molecular orbitals and their occupation numbers. Several chemical indices such as information entropy and unpaired electron density were calculated on the basis of the occupation numbers to elucidate the spin and pair correlations, and bonding characteristic (kinetic correlation) of this mesoscopic magnetic ring. Both classical and quantum effects for spin alignments and singlet spin-pair formations are discussed on the basis of the true spin Hamiltonian model in detail. Quantum effects are also discussed in the case of superconductivity, atom optics and quantum optics based on the pseudo spin Hamiltonian models. The coherent and squeezed states of spins, atoms and quantum field are discussed to obtain a unified picture for correlation, coherence and decoherence in future materials. Implications of theoretical results are examined in relation to recent experiments on molecule-based materials and molecular design of future molecular soft materials in the intersection area between molecular and biomolecular materials.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
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• pp.360-360
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• 2012

Graphene shows diverse novel physical properties arising from its peculiar electronic states, so called Dirac electrons. Especially, effect of magnetic field is very unique, exhibiting exotic Landau level (LL) splitting. LLs are substantially modified by spins of Dirac electrons and pseudo-spins. The degeneracy of LLs is lifted to show splitting by electron-electron interaction and by the Zeeman effect. We investigated the magneto-optical absorption of graphene subjected to ultra-high magnetic field. Samples were prepared by the CVD method deposited on GaAs and Quart substrate. We have confirmed existence of graphene on each substrate by the micro-Raman spectroscopy. Next, we conducted magneto-absorption measurements in magnetic field up to 120 T by the single-turn coil (STC) method. We could observe absorption peak at 65 T and 100 T, respectively, probably arising from the LL inter-band transitions.

• 한국정보통신학회논문지
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• 제12권5호
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• pp.863-869
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• 2008

본 연구에서는 센서 네트워크 보안 메커니즘을 홈네트워크 구조에 적용한 시스템을 설계하고 이를 홈네트워크 미들웨어의 가상망에 구현하였다. 홈네트워크 미들웨어의 기본구조는 lookup 서버가 서비스 노드와 일대일 또는 브로드캐스트 통신 방식의 구조이며, 여기에 요구되는 보안요소는 일대일의 통신인 경우에는 기밀성과 인증, 브로드캐스트일 경우에는 브로드캐스트 인증의 보장이다. 센서 네트워크 보안 기술인 SPINS는 기밀성과 인증을 보장하는 SNEP와 브로드캐스트 인증을 제공하는 ${\mu}TESLA$ 부분으로 구성되는데 이를 홈네트워크 미들웨어의 기본구조에 적용한 시스템을 설계하였다. MAC 생성을 위한 CBC-MAC, 메시지 신선성을 제공하는 CTR, 메시지의 랜덤특성을 보장하여 주는 PRF 방식, 그리고 센서노드에 사용될 암호화 알고리즘으로는 낮은 연산량으로 충분한 보안성을 갖는 RC5를 이용하였다. 구현된 결과는 CTR 모드로 인해 공격자가 키를 습득하더라도 새로운 메시지를 복호화 할 수 없었으며 상호 MAC 교환으로 인해 정당한 사용자로부터 전송되었다는 것을 인증할 수 있었다. 이 구현 결과는 향후 효율적이고 안전한 홈 네트워크 시스템 개발에 응용될 수 있을 것으로 기대한다.