• Title/Summary/Keyword: Proton exchange

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Preparation of Sulfonated PolySEBS/PS Blending Films (술폰화된 PolySEBS/PS Blending 필름의 제조)

  • Jang, Suk-Yong;Han, Sien-Ho
    • Applied Chemistry for Engineering
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    • v.19 no.2
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    • pp.205-208
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    • 2008
  • Sulfonated polySEBS and sulfonated PS were synthesized by sulfonation at the aromatic group of polySEBS and PS. Novel sulfonated polySEBS/sulfonated PS blending films for the ion exchange membrane of polymer electrolyte fuel cell were prepared from these sulfonated polymers. The proton conductivities of these blending films were varied in $10^{-2}{\sim}10^{-3}S/cm$ with the blending ratio of sulfonated polySEBS/sulfonated PS. Especially, the film prepared from the addition of the sulfonated PS (0.5 g) in the sulfonated polySEBS (10.0 g) has the best proton conductivity (0.07 S/cm) with ion exchange capacity (0.75 meq/g) and water uptake (25%).

Fabrication of optical waveguide on LiNbO$_3$substrate by proton exchange (LiNbO$_3$기판 위에서의 양자교환에 의한 공도파로 제작)

  • 정상철;심광보;정용선;신재혁;오근호
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.10 no.4
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    • pp.297-301
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    • 2000
  • Planar optical waveguides which have a higher refractive index than that of substrate were fabricated by proton exchange between $Li^+$ and $H^+$. Benzoic acid was used as proton source and process was carried out under the various reaction time and temperature. The depth of waveguide layer and the generated mode number were investigated by standard prism coupler. The cut-off depth for the fabrication of single mode optical waveguides was obtained by the function which was expressed on refractive index profile. Finally the experimental conditions for cut-of depth of single mode could be confirmed. Channel waveguides were manufactured from these confirmed conditions and the effective confinement of the induced light into waveguides was observed.

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A Two-Dimensional Analysis of Heat Transfer and Flow in Proton Exchange Membrane Fuel Cells (고분자 전해질 연료전지의 2차원 열전달 및 유동 해석)

  • Jeong, Hye-Mi;Yang, Ji-Hye;Koo, Ja-Ye;Park, Jung-Sun
    • Proceedings of the KSME Conference
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    • 2001.06d
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    • pp.995-1000
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    • 2001
  • Distributions of the parameters in proton exchange membrane fuel cell (PEMFC) has been analyzed numerically under steady-state and isothermal conditions. The distributions of the crucial parameters (e.g., temperature and pressure) in a PEMFC have a major impact on its safe and efficient operation. This paper predicts the performance of the model electrode plates by calculating the pressure and temperature distributions of working fluid. The calculated results of pressure and temperature at exit condition shows good agreement to experiments and gives details of flow pattern inside of electrode plates.

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A study on characterization of directional coupler using LiNbO$_3$ (LiNbO$_3$ 기판을 이용한 방향성결합형 광 변조기 특성 연구)

  • 강기성;김창원;소대화
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1995.05a
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    • pp.81-85
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    • 1995
  • A guide-wave electro-optical modulatored direct-ional coupler 1X2 was fabricated on LiNbO$_3$ by proton exchange with self-aligned method After proton exchange process, the waveguide is formed by annealing process, The relationship between refractive index change of waveguide and maximun output was studied a long the annealing time. A self-alinged method was used to simplify the fabrication process of the waveguide and the maximize the efficiency of electric field. The modulatored directional coupler 1${\times}$2 has very good figures of merits; The measured crosstalk was -29.5[dB] and the modulating voltage of 8.0[V].

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Performance Degradation of Mea with Cation Contamination in Polymer Electrolyte Membrane Water Electrolysis (고분자 전해질막 수전해 막전극접합체의 양이온 오염에 따른 성능 저하)

  • JUNG, HYEYOUNG;CHOI, NAKHEON;IM, SUHYUN;YOON, DAEJIN;MOON, SANGBONG
    • Transactions of the Korean hydrogen and new energy society
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    • v.28 no.4
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    • pp.331-337
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    • 2017
  • Proton Exchange Membrane Water Electrolysis (PEMWE) is one of the most popular and widely used methods for hydrogen production. PEMWE contributes to eco-friendly system via its energy storage system application, hence making it environmentally friendly to use. However, its main drawback is contamination of proton exchange membrane during water electrolysis. Existing cation such as magnesium, calcium and the likes are the cause for membrane contamination. As a result, the cation contamination give rise to degradation of performance of electrolysis and the reverse electrolysis is effective method to remove cation.

Experiments on PEMFC performance enhancement by pulsating cathode flow

  • Han, Hun-Sik;Kim, Ki-Woong;Kim, Yun-Ho;Kim, Seo-Young
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.05a
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    • pp.542-545
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    • 2008
  • Experiments have been performed to investigate effects of pulsating cathode flow on a 10-cell proton exchange membrane fuel cell (PEMFC) stack. For all the experiments, the flow rate, temperature and relative humidity of hydrogen at the anode inlet are fixed. The effects of the pulsating frequency, amplitude and flow rate at the cathode inlet on performance of 10-cell PEMFC are examined. The polarization and power curves show that the power output and limiting current is substantially increased when the pulsating component is added to cathode flow channel. The maximum power output increases by up to 38% and enhancement of the overall performance is more pronounced at lower flow rate region.

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The Characteristics Evaluation of the Gas Diffusion Layer for a PEM Fuel Cell by Computational Fluid Dynamics (CFD 해석을 이용한 PEMFC 용 기체확산층의 특성평가)

  • Kim B.H.;Choi J.P.;Jeon B.H.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2005.06a
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    • pp.207-210
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    • 2005
  • In this paper, a two-dimensional cross-channel model was applied to investigate influence of the gas diffusion layer(GDL) property and flow field geometry in the anode side for proton exchange membrane fuel cell(PEMFC). The GDL is made of a porous material such as carbon cloth, carbon paper, or metal wire mesh. To the simplicity, the GDL is represented as a block of material containing numerous pathways through which gaseous reactants and liquid water can pass. The purpose of present work was to study the effect of the GDL thickness and the porosity, and flow field geometry by computational fluid dynamics(CFD)

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Character Analysis of 1.2kW Proton Exchange Membrane Fuel cell (1.2KW 고분자 전해질형 연료전지 특성 분석)

  • Kim, Sung-Jun;Choi, Kyung-Tae;Choi, Kwang-Ju;Sugimura, Hisayuki;Lee, Hyun-Woo;Baek, Soo-Hyun
    • Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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    • 2005.05a
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    • pp.288-291
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    • 2005
  • This paper is aimed at presenting a proton exchange membrane (PEM) fuel cell stack. The fuel cell electrical output voltage and current (V-I) characteristic is described for the first time by a simplified closed form suitable. The characteristics obtained from the simulation are compared with the experimental results on a Ballard commercial fuel cell stack as well as to the manufacturer given data.

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A Study on a Design of Bipolar Plate for PEMFC System (PEMFC 시스템용 바이폴라 플레이트의 디자인에 관한 연구)

  • Yoon, Hyung-Sang;Cha, In-Su;Lee, Jeong-Il;Yoon, Jeong-Phil
    • New & Renewable Energy
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    • v.4 no.1
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    • pp.5-10
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    • 2008
  • Hydrogen fuel cell is clean and efficient technology along with high energy densities. While there are many different types of fuel cells, the proton exchange membrane fuel cell stands out as one of the most promising for transportation and small stationary applications. This paper focuses on design of bipolar plate for proton exchange membrane fuel cell. The bipolar plate model is realistically and accurately simulated velocity distribution, current density distribution and its effect on the PEMFC system using CFD tool FLUENT.

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Development of WT-FC Hybrid System for Off-Grid (오프그리드용 풍력-연료전지 하이브리드 시스템 개발)

  • Choi, Jong-Pil;Park, Nae-Chun;Kim, Sang-Hun;Kim, Byeong-Hee;Nam, Yun-Su;Yu, Neung-Su
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.383-386
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    • 2007
  • This paper describes the design and integration of the wind- fuel cell hybrid system. The hybrid system components included a wind turbine, an electrolyzer (for generation of H2), a PEMFC (Proton Exchange Membrane Fuel Cell), storage system and BOP (Balance of Plant) system. The energy input is entirely provided by a wind turbine. A DC-DC converter controls the power input to the electrolyzer, which produces hydrogen and oxygen form water. The hydrogen used the fuel for the PEMFC. The hydrogen is compressed and stored in high pressure tank by hydrogen gas booster system.

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