• Title/Summary/Keyword: Proton exchange

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Numerical Study on Comparison of Serpentine and Parallel Flow Channel in High-temperature Proton Exchange Membrane Fuel Cells (고온형 고분자전해질형 연료전지에서의 사형 유로와 평행 유로 성능비교에 대한 수치해석적 연구)

  • AHN, SUNGHA;OH, KYEONGMIN;JU, HYUNCHUL
    • Transactions of the Korean hydrogen and new energy society
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    • v.29 no.1
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    • pp.41-55
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    • 2018
  • General polymer electrolyte fuel cell (PEMFC) operates at less than $80^{\circ}C$. Therefore liquid phase water resulting from electrochemical reaction accumulates and floods the cell which in turn increases the mass transfer loss. To prevent the flooding, it is common to employ serpentine flow channel, which can efficiently export liquid phase water to the outlet. The major drawback of utilizing serpentine flow channel is the large pressure drop that happens between the inlet and outlet. On the other hand, in the high temperature polymer electrolyte fuel cell (HT-PEMFC), since the operating temperature is 130 to $180^{\circ}C$, the generated water is in the state of gas, so the flooding phenomenon is not taken into consideration. In HT-PEMFCs parallel flow channel with lower pressure drop between the inlet and outlet is employed therefore, in order to circulate hydrogen and air in the cell less pumping power is required. In this study we analyzed HT-PEMFC's different flow channels by parallel computation using previously developed 3-D isothermal model. All the flow channels had an active area of $25cm^2$. Also, we numerically compared the performance of HT-PEMFC parallel flow channel with different manifold area and Rib interval against the original serpentine flow channel. Results of the analysis are shown in the form of three-dimensional contour polarization curves, flow characteristics in the channel, current density distribution in the Membrane, overpotential distribution in the catalyst layer, and hydrogen and oxygen concentration distribution. As a result, the performance of a real area fuel cell was predicted.

Comparison between CFD Analysis and Experiments According to Various PEMFC Flow-field Designs

  • Lee, Kang-In;Lee, Se-Won;Park, Min-Soo;Cho, Yong-Hun;Cho, Yoon-Hwan;Chu, Chong-Nam;Sung, Yung-Eun
    • Journal of the Korean Electrochemical Society
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    • v.12 no.1
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    • pp.61-67
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    • 2009
  • Flow-field design has much influence over the performance of proton exchange membrane fuel cell (PEMFC) because it affects the pressure magnitude and distribution of the reactant gases. To obtain the pressure magnitude and distribution of reactant gases in five kinds of flow-field designs, computational fluid dynamics (CFD) analysis was performed. After the CFD analysis, a single cell test was carried out to obtain the performance values. As expected, the pressure differences due to different flow-field configurations were related to the PEMFC performance because the actual performance results showed the same tendency as the results of the CFD analysis. A large pressure drop resulted in high PEMFC performance. The single serpentine configuration gave the highest performance because of the high pressure difference magnitudes of the inlet/outlet. On the other hand, the parallel flow-field configuration gave the lowest performance because the pressure difference between inlet and outlet was the lowest.

Development of Thermoplastic Carbon Composite Bipolar Plates for High-temperature PEM Fuel Cells (고온 양성자 교환막 연료전지용 열가소성 탄소 복합재료 분리판 개발)

  • Lim, Jun Woo;Kim, Minkook;Lee, Dai Gil
    • Composites Research
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    • v.29 no.5
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    • pp.243-248
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    • 2016
  • Although thermoset carbon fiber composite bipolar plates not only have high mechanical properties but also high corrosion resistance in acid environment, high manufacturing cost and low bulk electrical conductivity are the biggest obstacle to overcome. In this research, thermoplastic polymer is employed for the matrix of carbon composite bipolar plate to increase both the manufacturing productivity and bulk electric conductivity of the bipolar plate. In order to increase the electrical conductivity and strength, plain type carbon fabric rather than chopped or unidirectional fibers is used. Also nano particles are embedded in the thermoplastic matrix to increase the bulk resistance of the bipolar plate. The area specific resistance and the mechanical strength of the developed bipolar plate are measured with respect to the environmental temperature and stack compaction pressure.

Optimization of a Fuel Cell Stack for Small Robot Systems (소형 로봇용 연료 전지 스택 설계 사양 최적화)

  • Hwang, S.W.;Choi, G.H.;Park, Sam.;Ench, R. Michael;Bates, Alex M.;Lee, S.C.;Kwon, O.S.;Lee, D.H.
    • 한국태양에너지학회:학술대회논문집
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    • 2012.03a
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    • pp.211-216
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    • 2012
  • Proton Exchange Membrane Fuel Cells (PEMFC) are the most appropriate for energy source of small robot applications. PEMFC has superior in power density and thermodynamic efficiency as compared with the Direct Methaol Fuel Cell (DMFC). Furthermore, PEMFC has lighter weight and smaller size than DMFC which are very important factors as small robot power system. The most significant factor of mobile robots is weight which relates closely with energy consumption and robot operation. This research tried to find optimum specifications in terms of type, number of cell, active area, cooling method, weight, and size. In order to find optimum 500W PEMFC, six options are designed in this paper and studied to reduce total stack weight by applying new materials and design innovations. However, still remaining problems are thermal management, robot space for energy sources, and so on. For a thermal management, design options need to analysis of Computational Fluid Dynamics (CFD) for determining which option has the improved performance and durability.

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Improvement of the characteristics and fabrication of a planar waveguide lens (평면 광도파로 렌즈의 제작 및 특성 개선)

  • 정석문;김재창;윤태훈;김길중
    • Korean Journal of Optics and Photonics
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    • v.7 no.1
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    • pp.51-59
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    • 1996
  • In this paper, we propose a new type of a planar waveguide lens, a meniscus lens instead of a plano-convex lens used widely for the optical integrated circuits such as optical numerical processors. A plano-convex lens has a spherical aberration caused by the linear boundary. In the proposed meniscus lens, this linear boundary is replaced by a circular-boundary, and the spherical aberration is removed. To test the performance of the proposed lens, a meniscus lens is designed using Fermat principle and fabricated on the Y-cut $LiNbO_3$ substrate. First a $Ti:LiNbO_3$ planar waveguide is fabricated on the $LiNbO_3$ substrate by Ti indiffusion. Then a meniscus lens is fabricated on the planar waveguide by TIPE(Ti indiffued proton-exchange) method. A plano-convex lens is also fabricated on the same substrate to compare the spot size at the focal point. The measured spot size of the meniscus lens is reduced to 59% that of the plano-convex lens. This result shows that the proposed meniscus lens is more effective for optical integrated circuits than the plano-convex lens.

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Initial Sizing of General Aviation Aircraft Propelled by Electric Propulsion system (전기로 추진되는 일반 프로펠러 항공기의 초기 사이징)

  • Han, Hye-Sun;Shin, Kyo-Sic;Park, Hong-Ju;Hwang, Ho-Yon;Nam, Taewoo
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.41 no.5
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    • pp.391-403
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    • 2013
  • Propeller aircraft propelled by an electric propulsion system is gaining a renewed interest because of ever-increasing environmental concern on harmful emissions emitted from conventional jet engines and national energy security. Traditional aircraft sizing methods are not readily applicable to electric propulsion aircraft that utilize a variety of alternative energy sources and power generation systems. This study showcases an electric propulsion aircraft sizing exercise based on a generalized, power based sizing method. A general aviation aircraft is propelled by an electric propulsion system that comprises of a propeller, a high temperature super conducting motor, a Proton Exchange Membrance(PEM) fuel cell system fuelled with hydrogen, and power conditioning equipment. In order to assess the impact of technology progression, aircraft sizing was conducted for two different sets of technology assumptions for electric components, and the results were compared with conventional baseline aircraft.

Characteristics of Microbial Fuel Cells Using Pig Waste and sPAES Membrane (돼지 분뇨와 sPAES 막을 이용한 미생물 연료전지의 특성)

  • Lee, Se-Hoon;Mun, Ji-Yoon;Kim, Young-Sook;Chu, Cheun-Ho;Na, Il-Chai;Lee, Jeong-Hoon;Lee, Moo-Seok;Lee, Dong-Hoon;Park, Kwon-Pil
    • Korean Chemical Engineering Research
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    • v.54 no.4
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    • pp.453-458
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    • 2016
  • Microbial fuel cells (MFC) were operated with pig wastes and PEMFC (Proton Exchange Membrane Fuel Cells) MEA (Membrane and Electrode Assembly). Performance of hydrocarbon membrane was compared with that of perfluoro membrane at MFC condition. Sulfonated-Poly(Arylene Ether Sulfone) was used as hydrocarbon membrane and Gore membrane was used as perfluoro membrane. OCV of sPAES MEA was 50mV higher than that of Gore MEA and power density of sPAES MEA was similar that of Gore MEA. Reinforcement of sPAES membrane stabilized the performance of MEA in MFC. The highest performance was obtained at temperature of $45^{\circ}C$ and with culture solution circulation rate of 50 ml/min. The highest power density was $1,100mW/m^2$ at optimum condition in MFC using pig waste.

Degradation of MEA and Characteristics of Outlet Water According to Operation Condition in PEMFC (고분자 전해질 연료전지 구동 조건에 따른 MEA 열화 및 배출수 특성)

  • Hwang, Byungchan;Lee, Sehoon;Na, Il-Chai;Park, Kwonpil
    • Korean Chemical Engineering Research
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    • v.55 no.4
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    • pp.478-482
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    • 2017
  • Humidity control of proton exchange membrane fuel cell(PEMFC) is very important control condition during driving. In terms of water management, low humidification conditions are advantageous, and high humidification is advantageous in terms of drainage utilization and energy efficiency. In this study, the characteristics of outlet water in low humidification and high humidification process were studied in terms of utilization of discharged water. Since the impurities in the effluent are generated during the degradation of the membrane and the electrode assembly(MEA), degradation of the MEA under low humidification and high humidification conditions was also studied. The rate of radical generation was high at low humidification condition of the anode RH 0%, which showed that it was the main cause of the degradation of the polymer membrane. Analysis of effluent showed low concentration of fluoride ion concentration of about 20 ppb at high humidification (both electrodes RH 100%) and 0.6 V, which was enough to be used as the feed water for electrolysis. Very low concentration of platinum below 0.2 ppb was detected in the condensate discharged from the high humidification condition.

The production and application of therapeutic 67Cu radioisotope in nuclear medicine

  • Kim, Gye-Hong;Lee, Kyo Chul;Park, Ji-Ae;An, Gwang-Il;Lim, Sang Mo;Kim, Jung Young;Kim, Byung Il
    • Journal of Radiopharmaceuticals and Molecular Probes
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    • v.1 no.1
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    • pp.23-30
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    • 2015
  • Radioisotopes emitting low-range highly ionizing radiation such as ${\beta}$-particles are of increasing significance in internal radiotherapy. Among the ${\beta}$-particle emitting radioisotopes, $^{67}Cu$ is an attractive radioisotope for various nuclear medicine applications due to its medium energy ${\beta}$-particle, gamma emissions, and 61.83-hour half-life, which can also be used with $^{64}Cu$ for PET imaging. The production and application of the ${\beta}$-emitting radioisotope $^{67}Cu$ for therapeutic radiopharmaceutical are outlined, and different production routes are discussed. A survey of copper chelators used for antibody labeling is provided. It has been produced via proton, alpha, neutron, and gamma irradiations followed by solvent extraction, ion exchange, electrodeposition. Clinical studies using $^{67}Cu$-labelled antibodies in lymphoma, colon carcinoma and bladder cancer patients are reviewed. Widespread use of this isotope for clinical studies and preliminary treatments has been limited by unreliable supplies, cost, and difficulty in obtaining therapeutic quantities.

Synthesis of Potassium Hexatitanate with Non-Fibrous Shape as a Raw Material for Friction Material in Brake System (자동차 브레이크 마찰재용 비침상형 육티탄산칼륨의 합성 연구)

  • Lee, Jung Ju;Lee, Na-Ri;Pee, Jae-Hwan;Kim, Jong-Young;Kim, Jeong-Joo
    • Korean Journal of Materials Research
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    • v.27 no.3
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    • pp.132-136
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    • 2017
  • We synthesized potassium hexatitanate, ($K_2Ti_6O_{13}$, PT6), with a non-fibrous shape, by acid leaching and subsequent thermal treatment of potassium tetratitanate ($K_2Ti_4O_9$, PT4), with layered crystal structure. By controlling nucleation and growth of PT4 crystals, we obtained splinter-type crystals of PT6 with increased width and reduced thickness. The optimal holding temperature for the layered PT4 was found to be ${\sim}920^{\circ}C$. The length and width of the PT4 crystals were increased when the nucleation and growth time were increased. After a proton exchange reaction using aqueous 0.3 M HCl solution, and subsequent heat treatment at $850^{\circ}C$, the PT4 crystal transformed into splinter-type PT6 crystals. The frictional characteristics of the friction materials show that as the particle size of PT6 increases, the coefficient of friction (COF) and wear amounts of both the friction materials and counter disc increase.