• Title/Summary/Keyword: Proton exchange

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Purification and Properties of Non-Cariogenicity Sugar Produced by Alkalophilic Bacillus sp. S-1013

  • Ryu, Il-Hwan;Kim, Sun-Sook;Lee, Kap-Sang
    • Journal of Microbiology and Biotechnology
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    • v.14 no.4
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    • pp.751-758
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    • 2004
  • The NCS(Non-Cariogenicity Sugar) from Bacillus sp. S-1013 was purified by cold acetone and methanol precipitation, and DEAE-cellulose ion-exchange and Sephadex G-100 column chromatographies, to yield an amorphous yellow syrup. The melting point and $[\alpha]_D^{20}$ were 155-$157^{\circ}C$ and +53, respectively. Instrumental analyses such as FT-IR, $^1H-NMR, and ^{13}C-NMR$ showed that the NCS contained an O-H group, C-H, C=O, $NH_2$, anomeric carbon, anomeric proton, N-acetylgalactose, fucose, and neuramic acid, thus, the NCS was determined to be a trisaccharide of Fuc($1\longrightarrow4$)GalNAc($2\longrightarrow6$) NeuAc.

The development of mobile fuel cell (모바일용 연료전지 개발)

  • Lee K.I.;Park M.S.;Cho Y.H.;Cho Y.H.;Sung Y.E.;Chu C.N.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2006.05a
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    • pp.549-550
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    • 2006
  • Mobile fuel cell is highlighted in these days because mobile fuel cell can contain more energy than existing batteries. Nowadays mobile devices like cellular phone, PMP(portable multi-media player), notebook, and etc. need more energy, But existing batteries like Li-ion or Ni-MH batteries are not going to satisfy such demands. In this paper, mobile fuel cell is developed. Its size is 50*70*8mm and it is made of aluminium plates. The fuel cell type is PEM and the fuel is pure hydrogen and oxygen.

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Proton Exchange Membrane from Hydrophobic-hydrophilic Block Copolymers based on Sulfonated Poly(arylene ether sulfone) in Fuel Cells (술폰화 폴리아릴렌에테르술폰 구조를 가진 소수성-친수성 블록공중합체 연료전지용 고분자 전해질막)

  • Park, Ji-Young;Choi, Jong-Ho;Kim, Hyung-Joong;Hong, Young-Taik
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.11a
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    • pp.195-196
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    • 2009
  • 술폰화 폴리아릴렌에테르술폰 공중합체를 기본구조로 한, 6F OH를 알코올 단량체로 사용하여 블록 공중합체를 직접 중합법으로 합성하였다. 이때 각각의 소수성-친수성 소중합체들은 동일한 분자량을 이용하여 합성했으며 그때의 두 소중합체의 몰비는 1:1로 하여 블록 공중합체의 술폰화도를 50%로 고정하였다. N-메틸-2피롤리돈(NMP) 용매 상에서 연료전지용 고분자 전해질 막을 제조하여 이온전도도 및 메탄올 투과도등의 측정을 통하여 최종 블록 공중합체 전해질 막의 기본 특성을 파악했다. 소수성-친수성 소중합체의 분자량을 조절함에 따라 최종 전해질 막의 이온 전도도를 향상시킬 수 있음이 확인되었고, 연료전지 성능 테스트 결과에서도 나피온(Nafion 115)과 비슷한 성능을 보였다.

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Performance change according to the catalyst intrusion rate in the MEA for the PEM water electrolysis (고분자전해질 수전해용 MEA의 촉매침투도에 따른 성능변화)

  • Kim, Hong-Youl
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.11a
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    • pp.254-256
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    • 2009
  • The performances of proton exchange membrane (PEM) water electrolysis depend on many factors such as materials, geometries, fabrication methods, operating conditions, and so forth. The fabrication method is concerned, membrane electrode assemblies (MEA) are a most important part to show different performances by different fabrication methods. The performance change of PEM water electrolysis was experimentally measured according to the fabrication differences of the anode electrodes. One point of view is the catalyst intrusion rate to the anode gas diffusion layer (GDL), and the other point of view is the catalyst loading distribution in depth of the anode GDL. Results show that the performances of MEA with deep intrusion of the catalysts are better in the range of low current densities but worse at higher current densities. The catalyst loading distribution does not affect significantly to the performance of PEM water electrolyser.

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A Feasibility Study of Low-Cost Hybrid Fuel-Cell System for Ship Auxiliary Power (선박 보조전원을 위한 저가형 하이브리드 연료전지 시스템 적용 타당성 연구)

  • Yang, Geun Ryoung;An, Sang Yong;Choo, Jin Hoon
    • New & Renewable Energy
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    • v.9 no.4
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    • pp.3-12
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    • 2013
  • This paper proposes the hybrid fuel cell system that can solve disadvantages of existing fuel cell system and ensure high reliability and high stability. The system consists of PEM fuel cell, Ni-MH battery and power management system. In this system, when the power provided from the fuel cell is higher than the load power, the extra energy may be used to charge the Ni-MH battery. When the fuel cell can not provide enough energy to the load, the shortage of energy will be supplied by the Ni-MH battery. Experimental results show that the output voltage is regulated well during load variations. Also, high system efficiency is achieved.

Characterization of Humic and Fulvic Acids Extracted at the Soils of Korea and Its DB Establishment (국내 토양 휴믹물질의 특성 규명 및 DB 구축에 대한 연구)

  • 이창훈;유지호;신현상;정근호;이창우
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.04a
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    • pp.397-400
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    • 2003
  • In this study, humic and fulvic acids in soils at the vicinity of domestic atomic power plants(NPPs), located in Yungkwang(YK), Uljin(UJ), Kori(KR), Koseong(KS), Wolseong(WS) area, and in volcanic ash soils of the Cheju island(Mt. Hanla(HL), Manjanggul(MJ)) were isolated, and characterized using chemical(elemental analysis, proton exchange capacity, molecular size distribution) and spectroscopic(UV/Vis., IR, FL, $^{13}$ C NMR spectra) methods. The results were compared with one another and compiled for their DB establishments. The humic substances distribution (humic acid, fulvic acid, Humin) in the soils were also determined by IHSS standard method. Main purpose of this study was to provide a basic data needed to evaluate the effect of humic substances on the migrational behaviour of radioactive elements in contaminated surface soil.

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Nanostructured Polymer Electrolytes for Li-Batteries and Fuel Cells

  • Park, Mun-Jeong
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2012.05a
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    • pp.71.2-71.2
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    • 2012
  • There are rising demands for developing more efficient energy materials to stem the depletion of fossil fuels, which have prompted significant research efforts on proton exchange fuel cells (PEFCs) and lithium ion batteries (LIBs). To date, both PEFCs and LIBs are being widely developed to power small electronics, however, their utilization to medium-large sized electric power resources such as vehicle and stationary energy storage systems still appears distant. These technologies increasingly rely upon polymer electrolyte membranes (PEMs) that transport ions from the anode to the cathode to balance the flow of electrons in an external circuit, and therefore play a central role in determining the efficiency of the devices; as ion transport is a kinetic bottleneck compared to electrical conductivity, enormous efforts have been devoted to improving the transport properties of PEMs. In present study, we carried out an in-depth analysis of the morphology effects on transport properties of PEMs. How parameters such as self-assembled nanostructures, domain sizes, and domain orientations affect conductivities of PEMs will be presented.

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First Principles Computational Study of Surface Reactions Toward Design Concepts of High Functional Electrocatalysts for Oxygen Reduction Reaction in a Fuel Cell System

  • Hwang, Jeemin;Noh, Seunghyo;Kang, Joonhee;Han, Byungchan
    • Journal of Surface Science and Engineering
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    • v.50 no.1
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    • pp.1-9
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    • 2017
  • Design of novel materials in renewable energy systems plays a key role in powering transportation vehicles and portable electronics. This review introduces the research work of first principles-based computational design for the materials over the last decade to accomplish the goal with less financial and temporal cost beyond the conventional approach, especially, focusing on electrocatalyst toward a proton exchange membrane fuel cell (PEMFC). It is proposed that the new method combined with experimental validation, can provide fundamental descriptors and mechanical understanding for optimal efficiency control of a whole system. Advancing these methods can even realize a computational platform of the materials genome, which can substantially reduce the time period from discovery to commercialization into markets of new materials.