• 제목/요약/키워드: Proton exchange

검색결과 620건 처리시간 0.039초

Platinum nanocomposites and its applications: A review

  • Sharon, Madhuri;Nandgavkar, Isaac;Sharon, Maheshwar
    • Advances in materials Research
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    • 제6권2호
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    • pp.129-153
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    • 2017
  • Platinum is a transition metal that is very resistant to corrosion. It is used as catalyst for converting methyl alcohol to formaldehyde, as catalytic converter in cars, for hydrocracking of heavy oils, in Fuel Cell devices etc. Moreover, Platinum compounds are important ingredient for cancer chemotherapy drugs. The nano forms of Platinum due to its unique physico-chemical properties that are not found in its bulk counterpart, has been found to be of great importance in electronics, optoelectronics, enzyme immobilization etc. The stability of Platinum nanoparticles has supported its use for the development of efficient and durable proton exchange membrane Fuel Cells. The present review concentrates on the use of Platinum conjugated with various metal or compounds, to fabricate nanocomposites, to enhance the efficiency of Platinum nanoparticles. The recent advances in the synthesis methods of different Platinum-based nanocomposites and their applications in Fuel Cell, sensors, bioimaging, light emitting diode, dye sensitized solar cell, hydrogen generation and in biosystems has also been discussed.

접촉각에 따른 마이크로채널 내에서의 액적 거동에 대한 수치적 연구 (Numerical Study of Droplet Motion in a Microchannel with defferent contact angles)

  • 최지영;손기헌
    • 한국전산유체공학회:학술대회논문집
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    • 한국전산유체공학회 2008년도 춘계학술대회논문집
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    • pp.656-657
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    • 2008
  • The droplet dynamics in a hydrophilic/hydrophobic microchannel, which is applicable to a typical proton exchange membrane fuel cell (PEMFC), is studied numerically by solving the equations governing conservation of mass and momentum. The liquid-gas interface or droplet shape is determined by a level set method which is modified to treat contact angles. The matching conditions at the interface are accurately imposed by incorporating the ghost fluid approach based on a sharp-interface representation. The effects of contact angle, inlet flow velocity, droplet size and side wall on the droplet motion are investigated parametrically. Based on the numerical results, the droplet dynamics including the sliding and detachment of droplets is found to depend significantly on the contact angle. Also, a droplet removal process is demonstrated on the combination of hydrophilic and hydrophobic surfaces.

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고분자 전해질 연료전지의 개방회로 전위차 측정 및 분석 (Measurement and Analysis of Open Circuit Potential in PEFC)

  • 김홍건;김유신;김홍열
    • 한국공작기계학회:학술대회논문집
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    • 한국공작기계학회 2004년도 추계학술대회 논문집
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    • pp.134-138
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    • 2004
  • The discrepancies between theoretical values and measured data of PEFC(Proton Exchange Fuel Cell) is carried out for the machine tool power generation. Rudimental approach of theoretical fuel cell open circuit potential using Gibbs free energy is employed for the examination of PEFC module. The stack temperature, stack voltage and stack current are measured during the operation of PEFC module. It is found that stack voltage and current values show the pronounced discrepancy with the results calculated by Gibbs free energy approach. It is analysed that the discrepancy is due to activation polarization, concentration overvoltage and ohmic overvoltage.

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연료전지-태양전지 하이브리드 자동차에 대한 제어전략 및 특성평가 (Control Strategy and Characteristic Analysis of PEMFC/Photovoltaics Hybrid Vehicle)

  • 안효정;지현진;배중면;차석원
    • 대한기계학회논문집B
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    • 제31권10호
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    • pp.840-847
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    • 2007
  • This Paper focuses on modeling and simulation to analyze the characteristic of hybrid vehicle. The system includes a proton exchange membrane fuel cell(PEMFC), photovoltaic generator(PV), lead-acid battery, motor, vehicle and controller. Main electricity is produced by the PEMFC and battery to meet the requirements of a user load. When vehicle is parked in a sunny place, extra power is generated by the photovotaics and is charged in a battery for next drive. Further we evaluate usefulness of this hybrid vehicle by using ADVISOR - the advanced vehicle simulator written in the Matlab/Simulink environment. According to simulation results, the extra power obtained by photovoltaics which have been explored in nature conditions can help to reduce the electrical load of PEMFC and increase the efficiency (over 21 %).

운전조건에 따른 PEMFC 스택의 성능에 관한 실험적 연구 (An Experimental Study on the Performance of PEMFC Stack Depending on Operating Conditions)

  • 이지홍;이명용;이상석;남일상;이도형
    • Journal of Advanced Marine Engineering and Technology
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    • 제33권5호
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    • pp.770-777
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    • 2009
  • The energy depletion and the environmental pollution like global warming are worldwide issues. For correcting these problems there are many studies on new-renewable energy in Korea. A kind of new-renewable energy, PEMFC(Proton Exchange Membrane Fuel Cell) is a low temperature fuell cell and there are some cases of small craft or submarine adopted PEMFC system in maritime. PEMFC's performance is affected the operating conditions. Finding optimum operating conditions must be performed before adopting PEMFC to system. So in this study, we experiment about various operating conditions to apply 150W PEMFC stack for a model boat. And through the results, we find optimum operating conditions and study an effect of operating conditions to PEMFC.

작동조건을 고려한 자동차용 PEM 연료전지 시스템 성능 시뮬레이션 (1) (The Simulation of PEMFC System Performance for Automotive Application (1))

  • 방정환;김한상;이동훈;민경덕;김민수;조영만
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2003년도 추계학술대회
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    • pp.460-465
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    • 2003
  • The modeling of PEM (Proton Exchange Membrane) fuel cell system consisting of fuel cell stack and BOP (Balance of Plant) is presented in this paper. The effects of temperature, pressure (air, hydrogen), and humidity on the fuel cell system performance were mainly investigated using thermo-dynamical and electro-chemical equations. To understand the power distribution characteristics of fuel cell system, the effects of operating temperature and air pressure on maximum power and system power were also demonstrated. Through this study, we can get the basic insight into the fuel cell stack and BOP component sizing and it can be used effectively for the optimization of the practical fuel cell systems in purpose.

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연료전지 전원 시스템의 설계 및 분석을 위한 PEMFC의 회로 모델 (A Circuit Model of PEMFC for Design and Analyze Fuel Cell Power System)

  • 이수호;이현우;권순걸
    • 전력전자학회:학술대회논문집
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    • 전력전자학회 2006년도 전력전자학술대회 논문집
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    • pp.197-199
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    • 2006
  • The Proton Exchange Membrane Fuel Cells (PEMFCs) are being used in a variety of applications including portable power generation, transportation and back-up power systems. In this paper presents a novel circuit model for a PEMFC that can be used to design and analyze fuel-cell power system. The Pspice-based model uses BJTs, L and C elements available in the Pspice library with some modification. The model includes the phenomena like activation polarization, ohmic polarization and mass transport effect present in a PEM fuel cell. Simulated characteristics of the fuel cell were compared with the experimental results obtained on a commercial fuel cell.

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Cuk 컨버터를 이용한 휴대용 연료전지 충전기의 개발 (Development of the Portable Fuel Cell Charger Using Cuk Converter)

  • 김태훈;이승준;최우진
    • 전력전자학회:학술대회논문집
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    • 전력전자학회 2010년도 하계학술대회 논문집
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    • pp.408-409
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    • 2010
  • 본 논문에서는 소형 PEM(Proton Exchange Membrane) 연료전지를 이용하는 충전기에 관해 서술한다. 기존에 개발된 대부분의 충전기는 On-Grid 방식으로 벅타입 컨버터를 이용한 감압 충전방식을 사용하였으나, 연료전지를 이용할 경우 승압식 컨버터를 통해 배터리를 충전하여야 한다. 그러나 승압형 컨버터의 출력단에 인덕터가 없는 경우 큰 리플전류를 유도하게 되며, 이는 시스템의 효율 및 배터리의 수명에 좋지 않은 영향을 끼치게 된다. 본 논문에서는 Cuk 컨버터를 이용하는 충전용 전력변환기의 제어방법에 관해 제안하고 그 타당성을 검증하였다.

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Advanced Interchangeable Dynamic Simulation Model for the Optimal Design of a Fuel Cell Power Conditioning System

  • Kim, Jong-Soo;Choe, Gyu-Yeong;Lee, Byoung-Kuk;Shim, Jae-Sun
    • Journal of Electrical Engineering and Technology
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    • 제5권4호
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    • pp.561-570
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    • 2010
  • This paper presents an advanced dynamic simulation model of a proton exchange membrane fuel cell for the optimal design of a fuel cell power conditioning system (FC-PCS). For the development of fuel cell models, the dynamic characteristics of the fuel cell are considered, including its static characteristics. Then, software fuel cell simulation is realized using Matlab-Simulink. Specifically, the design consideration of PCS (i.e., power semiconductor switch, capacitor, and inductor) is discussed by comparatively analyzing the developed simulator and ideal DC source. In addition, a cosimulation between the fuel cell model and PCS realized using the PSIM software is performed with the help of the SimCoupler module. Detailed analysis and informative simulation results are provided for the optimal design of fuel cell PCS.

High-Efficiency Grid-Tied Power Conditioning System for Fuel Cell Power Generation

  • Jeong, Jong-Kyou;Han, Byung-Moon;Lee, Jun-Young;Choi, Nam-Sup
    • Journal of Power Electronics
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    • 제11권4호
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    • pp.551-560
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    • 2011
  • This paper proposes a grid-tied power conditioning system for the fuel cell power generation, which consists of a 2-stage DC-DC converter and a 3-phase PWM inverter. The 2-stage DC-DC converter boosts the fuel cell stack voltage of 26-48V up to 400V, using a hard-switching boost converter and a high-frequency unregulated LLC resonant converter. The operation of the proposed power conditioning system was verified through simulations with PSCAD/EMTDC software. Based on the simulation results, a laboratory experimental set-up was built with a 1.2kW PEM fuel-cell stack to verify the feasibility of hardware implementation. The developed power conditioning system shows a high efficiency of 91%, which is a very positive result for the commercialization.