• Title/Summary/Keyword: Proton exchange

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Grid-tied Power Conditioning System for Fuel Cell Composed of Three-phase Current-fed DC-DC Converter and PWM Inverter

  • Jeong, Jong-Kyou;Lee, Ji-Heon;Han, Byung-Moon;Cha, Han-Ju
    • Journal of Electrical Engineering and Technology
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    • v.6 no.2
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    • pp.255-262
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    • 2011
  • This paper proposes a grid-tied power conditioning system for fuel cell, which consists of three-phase current-fed DC-DC converter and three-phase PWM inverter. The three-phase current-fed DC-DC converter boosts fuel cell voltage of 26-48 V up to 400 V with zero-voltage switching (ZVS) scheme, while the three-phase PWM(Pulse Width Modulation) inverter controls the active and reactive power supplied to the grid. The operation of the proposed power conditioning system with fuel cell model is verified through simulations with PSCAD/EMTDC software. The feasibility of hardware implementation is verified through experimental works with a laboratory prototype with 1.2 kW proton exchange membrane (PEM) fuel cell stack. The proposed power conditioning system can be commercialized to interconnect the fuel cell with the power grid.

A Feasibility Design of PEMFC Parallel Operation for a Fuel Cell Generation System

  • Kang, Hyun-Soo;Choe, Gyu-Yeong;Lee, Byoung-Kuk;Hur, Jin
    • Journal of Electrical Engineering and Technology
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    • v.3 no.3
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    • pp.408-421
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    • 2008
  • In this paper, the parallel operation for a FC generation system is introduced and designed in order to increase the capacity for the distributed generation of a proton exchange membrane fuel cell (PEMFC) system. The equipment is the type that is used by parallel operated PEMFC generation systems which have two PEMFC systems, two dc/dc boost converters with shared dc link, and a grid-connected dc/ac inverter for embedded generation. The system requirement for the purpose of parallel operated generation using PEMFC system is also described. Aspects related to the mechanical (MBOP) and electrical (EBOP) component, size, and system complexity of the distributed generation system, it is explained in order to design an optimal distributed generation system using PEMFC. The optimal controller design for the parallel operation of the converter is suggested and informative simulations and experimental results are provided.

Multi-film coated bipolar plates for PEMFC (Proton Exchange Membrane Fuel Cell) application (다층박막 코팅된 PEMFC (Proton Exchange Membrane Fuel Cell)용 바이폴라 플레이트)

  • Jeon, Gwang-Yeon;Yun, Young-Hoon;Cha, In-Su
    • Proceedings of the KIPE Conference
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    • 2008.06a
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    • pp.646-648
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    • 2008
  • The multi-films of a metallic film and a transparent conducting oxide (TCO, indium-tin oxide, ITO) film were formed on the stainless steel 316 and 304 plates by a sputtering method and an E-beam method and then the external metallic region of the stainless steel bipolar plates was converted into the metal nitride films through an annealing process. The multi-film formed on the stainless steel bipolar plates showed the XRD patterns of the typical indium-tin oxide, the metallic phase and the metal substrate and the external nitride film. The XRD pattern of the thin film on the bipolar plates modified showed two metal nitride phases of CrN and $Cr_2N$ compound. Surface microstructural morphology of the multi-film deposited bipolar plates was observed by AFM and FE-SEM. The electrical resistivity of the stainless steel bipolar plates modified was evaluated.

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Fabrication of a Optical Planar Waveguide Lens by Ti-Indiffused Proton-Exchange (Ti 내부확산/양자교환(TIPE)방식에 의한 평면 광도파로 렌즈의 제작)

  • 정석문;최성식;윤태훈;김재창
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.17 no.4
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    • pp.371-378
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    • 1992
  • In this paper we report the fabrication of a planar optical wavehuide lens on a Y-cut LiNbO3 substrate by Ti_indiffusion and Ti-indiffused proton-exchange(TIPE). LiNbo3 planar waveguides are fabricated and refractive indices of the waveguides are fabricated and refractive indices of the waveguides are measured. Based on the measured indices, palanr waveguide lenses are designed and fabricated. The measured focal point and spot size of the fabricated lens are in good agreement with those of the designed lens.

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A study on fabrication and characterization of coupling optical switch (결합형 광 스위치 제작 및 특성 연구)

  • 강기성;소대화
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1995.11a
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    • pp.351-356
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    • 1995
  • A optical switch which on the LiNbO$_3$substrate is fabricated by using proton exchange method and self-alignet method. The annealing at 400[$^{\circ}C$] was carried out to control waveguide width and depth. A self-aligned method, which doesn\`t need the additional mask precesses, was applied to simplify the fabrication processes and to maximize efficiency of electric field application. The depths of the two annealed optical waveguides, which were measured by using ${\alpha}$-step, ware 1.435[K${\AA}$] and 1,380[K${\AA}$]. Using ${\alpha}$-step facility, we examined that the width of waveguides is increased from 5[$\mu\textrm{m}$] to 6.45[$\mu\textrm{m}$] and 6.3[$\mu\textrm{m}$] due to the annealing effects. The process of proton exchange was done at 400[$^{\circ}C$] for 60[min] and annealing process was done at 400[$^{\circ}C$] for 60[min]. The high speed optical modulator has very good figures of merits: the measured voltage of the input waveguide power is 3.5[V], the voltage of the coupling waveguide power is 3.9[mV], and -29.5[dB] crosstalk and 8[V] switching voltage were achieved.

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Thermal and Flow Analysis in a Proton Exchange Membrane Fuel Cell

  • Jung, Hye-Mi;Koo, Ja-Ye
    • Journal of Mechanical Science and Technology
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    • v.17 no.9
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    • pp.1358-1370
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    • 2003
  • The effects of anode, cathode, and cooling channels for a Proton Exchange Membrane Fuel Cell (PEMFC) on flow fields have been investigated numerically. Continuous open-faced fluid flow channels formed in the surface of the bipolar plates traverse the central area of the plate surface in a plurality of passes such as a serpentine manner. The pressure distributions and velocity profiles of the hydrogen, air and water channels on bipolar plates of the PEMFC are analyzed using a two-dimensional simulation. The conservation equations of mass, momentum, and energy in the three-dimensional flow solver are modified to include electro-chemical characteristics of the fuel cell. In our three-dimensional numerical simulations, the operation of electro-chemical in Membrane Electrolyte Assembly (MEA) is assumed to be steady-state, involving multi-species. Supplied gases are consumed by chemical reaction. The distributions of oxygen and hydrogen concentration with constant humidity are calculated. The concentration of hydrogen is the highest at the center region of the active area, while the concentration of oxygen is the highest at the inlet region. The flow and thermal profiles are evaluated to determine the flow patterns of gas supplied and cooling plates for an optimal fuel cell stack design.

Heteroatom-doped carbon nanostructures as non-precious cathode catalysts for PEMFC (이종 원자 도핑 탄소 나노재료를 이용한 PEMFC Cathode용 촉매 합성 및 평가)

  • Jo, G.Y.;Shanmugam, S.
    • 한국태양에너지학회:학술대회논문집
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    • 2012.03a
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    • pp.406-409
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    • 2012
  • Recently, enormous research efforts have been focused on the development of non-precious catalysts to replace Pt for electrocatalytic oxygen reduction reaction (ORR), and to reduce the cost of proton exchange membrane fuel cells (PEMFCs). In recent years, heteroatom (N, B, and P) doped carbon nanostructures have been received enormous importance as a non-precious electrode materials for oxygen reduction. Doping of foreign atom into carbon is able to modify electronic properties of carbon materials. In this study, nitrogen and boron doped carbon nanostructures were synthesized by using a facile and cost-effective thermal annealing route and prepared nanostructures were used as a non-precious electrocatalysts for the ORR in alkaline electrolyte. The nitrogen doped carbon nanocapsules (NCNCs) exhibited higher activity than that of a commercial Pt/C catalyst, excellent stability and resistance to methanol oxidation. The boron-doped carbon nanostructure (BC) prepared at $900^{\circ}C$ showed higher ORR activity than BCs prepared lower temperature (800, $700^{\circ}C$). The heteroatom doped carbon nanomaterials could be promising candidates as a metal-free catalysts for ORR in the PEMFCs.

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The study of proton exchange membrane fuel cell and Li-poly battery hybrid system (로봇용 연료전지 이차전지 하이브리드 시스템 개발)

  • Kwon, O-Sung;Lee, Sang-Cheol;Lee, Sang-Woo;Lee, Dong-Ha
    • 한국태양에너지학회:학술대회논문집
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    • 2012.03a
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    • pp.229-233
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    • 2012
  • Proton exchange membrane fuel cell (PEMFC) is the most promising energy source for the robot applications because it has unique advantages such as high energy density, no power drop during operating, and easy to make compact size. However, PEMFC has intrinsic disadvantages which are delay to start up and difficulty to correspond drastic load changes. These disadvantages can be compensated by hybrid operating with a Li-poly battery. This study is focus to build and understand the hybrid system for the robot system. In this study, we build the PEMFC hybrid system using EOS-320 PEMFC stack, Li-poly battery and G-Philos FDX1-250BU dc-dc converter. The hybrid system is accurately monitored by CAN and RS485. The system was studied under two conditions such as non-loaded and loaded operating conditions. The results show that the system has delay to start up without hybrid operating and it can be compensated with the hybrid operating.

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Characterization of refractive index profile in LiNbO3 waveguides fabricated by high temperature proton exchange method (고온 양자교환법으로 제작된 LiNbO3 도파로의 굴절률 분포)

  • Shin, Myung-Jin;Cho, Hyun-Ju;Lee, Jae-Cheul
    • Korean Journal of Optics and Photonics
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    • v.15 no.6
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    • pp.563-568
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    • 2004
  • The high temperature proton exchange (HTPE) method was used to fabricate optical waveguides based on LiNbO$_3$, which gives rise to low propagation loss and high polarization extinction ratio. To characterize the refractive index distribution of the fabricated waveguides, the guided modes of each waveguide were observed using the prism coupling method and then the refractive index profile was calculated by the inverse WKB method with the least square fitting. Finally, we showed how the HTPE parameters such as the temperature of PE, the concentration of lithium additive, and the time of PE effect the refractive index profile.

Sorption of Chromium Ions from Aqueous Solution onto Chemically Activated Carbons Developed from Maize Cobs

  • Youssef, A.M.;El-Nabarawy, Th.;Shouman, Mona A.;Khedr, S.A.
    • Carbon letters
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    • v.9 no.4
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    • pp.275-282
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    • 2008
  • Chemically activated carbons were prepared from maize cobs, using phosphoric acid of variable concentration. The textural parameters of the activated carbons were determined from the nitrogen adsorption isotherms measured at 77 K. The chemistry of the carbon surface was determined by measuring the surface pH, the pHPZC and the concentration of the carbon - oxygen groups of the acid type on the carbon surface. Kinetics of Cr(VI) sorption/reduction was investigated at 303 K. Two processes were investigated in terms of kinetics and equilibrium namely; Cr(VI) removal and chromium sorption were studied at various initial pH (1-7). Removal of Cr(VI) shows a maximum at pH 2.5. At pH<2.5, sorption decreases because of the proton competition with evolved Cr(III) for ion exchange sites. The decrease of sorption at pH>2.5 is due to proton insufficiency and to the decrease of the extent of Cr(VI) reduction. The chemistry of the surface of activated carbon is an important factor in determining its adsorption capacity from aqueous solutions particularly when the sorption process involves ion exchange.