• Title/Summary/Keyword: Proton distribution

Search Result 164, Processing Time 0.024 seconds

OXYGEN CONCENTRATION IN THE CATHODE CHANNEL OF PEM FUEL CELL USING GAS CHROMATOGRAPH

  • Ha, T.H.;Kim, H.S.;Min, K.D.
    • International Journal of Automotive Technology
    • /
    • v.8 no.1
    • /
    • pp.119-126
    • /
    • 2007
  • Because of the low temperature operation, proton exchange membrane (PEM) fuel cell has a water phase transition. Therefore, water management is an important operation issue in a PEM fuel cell because the liquid water in the fuel cell causes electrode flooding that can lower the cell performance under high current density conditions. In this study, in order to understand the reactant distributions in the cathode channels of the PEM fuel cell, an experimental technique that can measure the species concentrations of reactant gases by using gas chromatograph (GC) is applied for an operating PEM fuel cell. The oxygen distribution along the cathode flow channels of PEM fuel cell is mainly investigated with various operating conditions. Also, the relations between cathode flooding and oxygen concentrations and oxygen consumption pattern along the cathode channel configurations of the unit cell adopted for this study are discussed using GC measurement and visualization experiment of cathode flooding. It is found that the amount of oxygen consumption is very sensitive to various operating conditions of the fuel cell and was much affected by the flooding occurrence in cathode channels.

Updated Comparison Study of Extensive Air Shower Simulations with COSMOS and CORSIKA

  • Kim, Ji-Hee;Roh, Soon-Young;Ryu, Dong-Su
    • The Bulletin of The Korean Astronomical Society
    • /
    • v.36 no.2
    • /
    • pp.128.2-128.2
    • /
    • 2011
  • Experiments to study high-energy cosmic rays (CRs) employ Monte Carlo codes for extensive air shower (EAS) simulations to figure out the properties of CRs. COSMOS and CORSIKA among EAS simulation codes are currently being used to analyze the data of the Telescope Array experiment. We have generated a library of about 10,000 simulated EASs with the primary energy ranging from $10^{18.5}eV$ to $10^{20}eV$ and the zenith angle of primary particles ranging from 0 to 45 degree for proton and iron primaries. We have compared the results predicted by CORSIKA and COSMOS under the same condition. In this talk, we show the differences in the energy spectra at the ground, the longitudinal shower profile as a function of atmospheric depth, the Calorimetric energy, and the Xmax distribution. We also discuss the lateral distribution function obtained from GEANT4 simulations which is being used to measure the detector response.

  • PDF

Optimization of Automotive PEMFC Bipolar Plates considering Heat Transfer and Thermal Loads (열전달 및 열하중을 고려한 자동차 연료전지(PEMFC) 분리판의 두께 최적설계)

  • Kim, Young-Sung;Kim, Cheol
    • Transactions of the Korean Society of Automotive Engineers
    • /
    • v.23 no.1
    • /
    • pp.34-40
    • /
    • 2015
  • A stack in the proton exchange membrane fuel cell (PEMFC) consists of bipolar plates, a membrane electrode assembly, a gas diffusion layer, a collector and end plates. High current density is usually obtainable partially from uniform temperature distribution in the fuel cell. A size optimization method considering the thermal expansion effect of stacked plates was developed on the basis of finite element analyses. The thermal stresses in end, bipolar, and cooling plates were calculated based on temperature distribution obtained from thermal analyses. Finally, the optimization method was applied and optimum thicknesses of the three plates were calculated considering both fastening bolt tension and thermal expansion of each unit cell (72 cells, 5kW). The optimum design considering both thermal and mechanical loads increases the thickness of an end plate by 0.64-0.83% the case considering only mechanical load. The effect can be enlarged if the number of stack increases as in an automotive application to 200-300 stacks.

Analysis of Scatter Ray Distribution Using GEANT4-GATE Simulation and Effectiveness of Silicone Pad in Digital Mammography (디지털유방촬영에서 Geant4-GATE를 이용한 산란선의 영향분석과 감소방안에 관한 연구)

  • Kim, Myeong-soo;Kim, Young-kuen;Jang, Young-Il
    • Journal of radiological science and technology
    • /
    • v.42 no.3
    • /
    • pp.175-180
    • /
    • 2019
  • In this study, we have researched the effectiveness of silicone pad. A distribution of scatter ray in mammography was evaluated using Monte-Carlo (MC) simulation technique and then a silicone pad was applied to remove the scatter ray for improving image quality. Molybdenum target and Molybdenum filter combination made a difference of 59.8% to a number of photon at 17.5 keV. On the other hand, Tungsten target and Rhodium filter showed a variation of 24.5% at 20 keV. Mean 68 of SNR was increased in Selenia and mean 1.04 of SNR was raised in Senographe. Silicone pad was significantly effective to reduce the scatter ray that was generated by primary X-ray. It can decrease an absorption rate of scatter ray to patient body and whilst it improve the image quality from increasing SNR.

Numerical Analysis of the Effect of a Three-Dimensional Baffle Structure with Variable Cross-Section on the Parallel Flow Field Performance of PEMFC

  • Xuejian Pei;Fayi Yan;Jian Yao;He Lu
    • Journal of Electrochemical Science and Technology
    • /
    • v.14 no.4
    • /
    • pp.333-348
    • /
    • 2023
  • In this study, a 3D model of the proton exchange membrane fuel cell is established, and a new 3D baffle structure is designed, which is combined with the parallel flow field and then optimized by numerical simulation methods. The number of baffles and the cross-sectional trapezoidal base angle are taken as the main variables, and their impacts on the performance indexes of the cathode side are analyzed. The results show that the 3D baffle can facilitate the convection and diffusion mass transfer of reactants, improve the uniformity of oxygen distribution, enhance the drainage capacity, and make the cell performance superior; however, too small angle will lead to excessive local convective mass flux, resulting in the decrease of the overall uniformity of oxygen distribution and lowering the cell performance. Among them, the optimal number of baffles and angle are 9 and 58°, respectively, which improves the net output power density by 10.8% than conventional flow field.

Do Inner Planets Modulate the Space Environment of the Earth?

  • Kim, Jung-Hee;Chang, Heon-Young
    • Journal of Astronomy and Space Sciences
    • /
    • v.31 no.1
    • /
    • pp.7-13
    • /
    • 2014
  • Variabilities in the solar wind cause disturbances throughout the heliosphere on all temporal and spatial scales, which leads to changeable space weather. As a view of space weather forecasting, in particular, it is important to know direct and indirect causes modulating the space environment near the Earth in advance. Recently, there are discussions on a role of the interaction of the solar wind with Mercury in affecting the solar wind velocity in the Earth's neighborhood during its inferior conjunctions. In this study we investigate a question of whether other parameters describing the space environment near the Earth are modulated by the inner planets' wake, by examining whether the interplanetary magnetic field and the proton density in the solar wind observed by the Advanced Composition Explorer (ACE) spacecraft, and the geomagnetic field via the Dst index and Auroral Electrojet index (AE index) are dependent upon the relative position of the inner planets. We find there are indeed apparent variations. For example, the mean variations of the geomagnetic fields measured in the Earth's neighborhood apparently have varied with a timescale of about 10 to 25 days. Those variations in the parameters we have studied, however, turn out to be a part of random fluctuations and have nothing to do with the relative position of inner planets. Moreover, it is found that variations of the proton density in the solar wind, the Dst index, and the AE index are distributed with the Gaussian distribution. Finally, we point out that some of properties in the behavior of the random fluctuation are to be studied.

Imperatorin is Transported through Blood-Brain Barrier by Carrier-Mediated Transporters

  • Tun, Temdara;Kang, Young-Sook
    • Biomolecules & Therapeutics
    • /
    • v.25 no.4
    • /
    • pp.441-451
    • /
    • 2017
  • Imperatorin, a major bioactive furanocoumarin with multifunctions, can be used for treating neurodegenerative diseases. In this study, we investigated the characteristics of imperatorin transport in the brain. Experiments of the present study were designed to study imperatorin transport across the blood-brain barrier both in vivo and in vitro. In vivo study was performed in rats using single intravenous injection and in situ carotid artery perfusion technique. Conditionally immortalized rat brain capillary endothelial cells were as an in vitro model of blood-brain barrier to examine the transport mechanism of imperatorin. Brain distribution volume of imperatorin was about 6 fold greater than that of sucrose, suggesting that the transport of imperatorin was through the blood-brain barrier in physiological state. Both in vivo and in vitro imperatorin transport studies demonstrated that imperatorin could be transported in a concentration-dependent manner with high affinity. Imperatorin uptake was dependent on proton gradient in an opposite direction. It was significantly reduced by pretreatment with sodium azide. However, its uptake was not inhibited by replacing extracellular sodium with potassium or N-methylglucamine. The uptake of imperatorin was inhibited by various cationic compounds, but not inhibited by TEA, choline and organic anion substances. Transfection of plasma membrane monoamine transporter, organic cation transporter 2 and organic cation/carnitine transporter 2/1 siRNA failed to alter imperatorin transport in brain capillary endothelial cells. Especially, tramadol, clonidine and pyrilamine inhibited the uptake of [$^3H$]imperatorin competitively. Therefore, imperatorin is actively transported from blood to brain across the blood-brain barrier by passive and carrier-mediated transporter.

Three Dimensional Computational Study on Performance and Transport Characteristics of PEMFC by Flow Direction (유동방향 변화에 따른 고분자 전해질 연료전지의 성능 및 전달특성에 대한 3차원 수치해석적 연구)

  • Lee, Pil-Hyong;Han, Sang-Seok;Hwang, Sang-Soon
    • Journal of the Korean Electrochemical Society
    • /
    • v.11 no.1
    • /
    • pp.51-58
    • /
    • 2008
  • Many researches for effects of different flow configurations on performance of Proton Exchange Membrane Fuel Cell have extensively been done but the effects of flow direction at the same flow channel shape should be considered for optimal operation of fuel cell as well. In this paper a numerical computational methode for simulating entire reactive flow fields including anode and cathode flow has been developed and the effects of different flow direction at parallel flow was studied. Pressure drop along the flow channel and density distribution of reactant and products and water transport, ion conductivity across the membrane and I-V performance are compared in terms of flow directions(co-flow or counter-flow) using above numerical simulation method. The results show that the performance under counter-flow condition is superior to that under co-flow condition due to higher reactant and water transport resulting to higher ion conductivity of membrane.

The Optimum pH of Oxidoreductases: A Comparison Between Experimental and Calculated pH Optimum (산화환원 효소의 최적 pH 예측)

  • Kim, Jin Ryeon;Yang, Ji Hye;Yu, Yeong Je
    • Journal of the Korean Chemical Society
    • /
    • v.46 no.5
    • /
    • pp.432-449
    • /
    • 2002
  • For various oxidoreductases, the optimum pHs of the enzymes can be calculated using the rule based on proton transfer. Relative probability of a certain amino acid side chain to be in the water, or the relative affinity to the water was calculated using Boltzman distribution. Also, the protonated and deprotonated portions of a certain amino acid side chain were calculated using p$K_R$ of that and the effective protonated and deprotonated protions were the product of relative probability and the protonated and deproteonated protions. Where the total effective protonated portion was equal to the effective deprotonated portion of amino acid side chains, it was expected that oxidoreductases have max-imum activities. The optimum pHs calculated by our rule were compared with the experimental results.

Characterization of Size Distribution and Water Solubility of 15 Elements in Atmospheric Aerosols

  • Park, Jeong-Ho;Sun, Jeong-Min;Park, Kum-Chan
    • Journal of Korean Society for Atmospheric Environment
    • /
    • v.17 no.E1
    • /
    • pp.1-7
    • /
    • 2001
  • The elemental characteristics of atmospheric aerosols were investigated as a function of particle size and water solubility. The aerosol particles were samples at 12 individual size ranges between 0.01 and 30㎛. Collected aerosol particles were separated into both soluble and insoluble components. The concentrations of 15 elements in both components were determined by a PIXE analysis using a 2.0 MeV-proton beam. In general, the mass size distribution of particulate matter was represented as a bimodal distribution. The maximum rations of S in July and December were 5.5 and 3.8 %, and they appeared in the size range of 0.47∼1.17㎛(stage No. 6 or 7) . The ratios of a S at non-separated size were 3.1 and 2.2 % in July and December, respectively, On the other hand, the maximum rations of Si in July and December were 7.0 and 5.4% and they appeared in the size range of 5.1∼30㎛(stage No. 0∼2). The ratios of Si at the non-separated size were 2.1 and 1.8% in July and December, respectively, The mass diameter of 12 elements ranged between 0.59㎛ of S and 3.20 of Fe. More than 90% of atmospheric aerosols consisted of the light elements such as C, N, O, H and Al. The soluble component was dominant in the smaller size range and the insoluble component in the larger size range. Large portions of Si. Ti and Fe existed in insoluble state. By contrast, S, Cl, Ca, Zn and Br were dissolved in water.