• Journal of Magnetics
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• 제16권1호
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• pp.36-41
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• 2011

If gas is leaking out of gas pipelines, it could cause a huge explosion. Accordingly, it is important to ensure the integrity of gas pipelines. Traditionally, over the years, gas-operating companies have used the ILI system, which is based on axial magnetic flux leakage (MFL), to inspect the gas pipelines. Relatively, there is a low probability of detection (POD) for the axial defects with the axial MFL-based ILI. To prevent the buried pipeline from corrosion, it requires a protective coating. In addition to the potential damage to the coating by environmental factors and external forces, there could be defects on the damaged coating area. Thus, it is essential that nondestructive evaluation methods for detecting axial defects (axial cracks, axial groove) and damaged coating be developed. In this study, an electromagnetic acoustic transducer (EMAT) sensor was designed and fabricated for detecting axial defects and coating disbondment. In order to validate the performances of the developed EMAT sensor, experiments were performed with specimens from axial cracks, axial grooves, and coating disbondment. The experimental results showed that the developed EMAT sensor could detect not only the axial cracks (minimum 5% depth of wall thickness) and axial grooves (minimum 10% depth of wall thickness), but also the coating disbondment.

• Nuclear Engineering and Technology
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• 제51권5호
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• pp.1390-1397
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• 2019

SiC coating and SiC/glassy carbon composite coating were prepared on IG-110 nuclear graphite (Toyo Tanso Co., Ltd., Japan) to strengthen its inertness to molten fluoride salt used in molten salt reactor (MSR). Two kinds of modified graphite were obtained and correspondingly named as IG-110-1 and IG-110-2, which referred to modified IG-110 with a single SiC coating and a SiC/glassy carbon composite coating, respectively. Both structure and property of modified graphite were carefully researched and contrasted with virgin IG-110. Results indicated that modified graphite presented better comprehensive properties such as more compact structure and higher resistance to molten salt infiltration. With the protection of coatings, the infiltration amounts of fluoride salt into modified graphite were much less than that into virgin IG-110 at the same circumstance. Especially, the infiltration amount of fluoride salt into IG-110-2 under 5 atm was merely 0.26 wt%, which was much less than that into virgin IG-110 under 1.5 atm (13.5 wt%) and the critical index proposed for nuclear graphite used in MSR (0.5 wt%). The SiC/glassy carbon composite coating gave rise to highest resistance to molten salt infiltration into IG-110-2, and thus demonstrated it could be a promising protective coating for nuclear graphite used in MSR.

• Smart Structures and Systems
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• 제29권2호
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• pp.301-309
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• 2022

Protective coatings are most widely used anticorrosive structures for steel structures. The corrosion under the coating damages the host material, but this damage is completely hidden. Therefore, a field-applicable under-coating-corrosion visualization method has been desired for a long time. Laser ultrasonic technology has been studied in various fields as an in situ nondestructive inspection method. In this study, a comparative analysis was carried out between a guided-wave ultrasonic propagation imager (UPI) and pulse-echo UPI, which have the potential to be used in the field of under-coating-corrosion management. Both guided-wave UPI and pulse-echo UPI were able to successfully visualize the corrosion. Regarding the field application, the guided-wave UPI performing Q-switch laser scanning and piezoelectric sensing by magnetic attachment exhibited advantages owing to the larger distance and incident angle in the laser measurement than those of the pulse-echo UPI. Regarding the corrosion visualization methods, the combination of adjacent wave subtraction and variable time window amplitude mapping (VTWAM) provided acceptable results for the guided-wave UPI, while VTWAM was sufficient for the pule-echo UPI. In addition, the capability of multiple sensing in a single channel of the guided-wave UPI could improve the field applicability as well as the relatively smaller size of the system. Thus, we propose a guided-wave UPI as a tool for under-coating-corrosion management.

• Advances in materials Research
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• 제9권3호
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• pp.219-231
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• 2020

The aim of this study is to investigate the durability of fly ash based geopolymer mortar with and without protective coatings in aggressive chemical environments. The source materials for geopolymer are Fly ash and Ground Granulated Blast furnace Slag (GGBS) and they are considered in the combination of 80% & 20% respectively. Two Molarities of NaOH solution were considered such as 8M and 10M. The ratio of binder to sand and Sodium silicate to Sodium hydroxide solution (Na₂SiO₃/NaOH) are taken as 1:2 and 2 respectively. The alkaline liquid to binder ratio is 0.4. Compressive strength tests were conducted at various ages of the mortar specimens. In order to evaluate the performance of coatings on geopolymer mortar under aggressive chemical environment, the mortar specimens were coated with two different types of coatings such as epoxy and Acrylic. They were then subjected to different chemical environments by immersing them in 10% standard solutions of each ammonium nitrate, sodium chloride and sulphuric acid. Drop in compressive strength as a result of chemical exposure was considered as a measure of chemical attack and the drop in compressive strength was measured after 30 and 60 days of chemical exposure. The compressive strength results following chemical exposure indicated that the specimens containing the acrylic coating proved to be more resistant to chemical attacks. The control specimen without coating showed a much greater degree of deterioration. Therefore, the application of acrylic coating was invariably much more effective in improving the compressive strength as well as the resistance of mortar against chemical attacks. The results also indicated that among all the aggressive attacks, the sulphate environment has the most adverse effect in terms of lowering the strength.

• 한국결정성장학회지
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• 제31권3호
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• pp.137-142
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• 2021

본 연구에서는 상온경화형 silica-based 코팅제의 제조 및 해양구조물에 적용하여 가혹한 해양환경에서 방식 및 방오 성능 발현을 위한 실용화 개발 연구를 수행하였다. 구조상 외부에 노출된 부분이 많은 해양(플랜트) 구조물은 강한 자외선, 극심한 온도차, 염수에 의한 부식 등 가혹한 해양환경에 고립되어 운용된다. 이러한 환경 하에서는 쉽게 열화 되고 파도 등 물리적 자극에도 쉽게 침식되는 유기계 페인트들은 그 역할을 제대로 할 수 없다. 해양구조물에 치밀한 세라믹 코팅을 형성시킬 경우 녹이 발생하지 않고 경도가 높아 시설물을 해수환경 하에서도 치밀하게 보호할 수 있다. 세라믹 코팅제의 경우 그 기능의 장점들로 인해 해양 구조물에서 그 용도와 적용범위는 크게 증진될 수 있을 것이다. 따라서 colloidal silica를 기반으로 실란계 커플링제, 경화제 및 세라믹 충진제로 구성된 silica-based 코팅제 조성개발과 해수중 방식 및 방오용 보호코팅제로의 응용에 대해 연구하였다.

• Corrosion Science and Technology
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• 제4권6호
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• pp.242-249
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• 2005

A lot of parts in FGD (Flue Gas Desulfurization) systems of fossil-fuel power plants show the environments in which are highly changeable and extremely acidic corrosive medium according to time and locations, e.g. in duct works, coolers and re-heaters etc. These conditions are formed when system materials are immersed in fluid that flows on them or when exhausted gas is condensed into thin layered acidic medium to contact materials of the system walls and roofs. These environments make troublesome corrosion and air pollution problems that are occurred from the leakage of the condensed solution. To cathodically protect the metallic structures in extremely acidic fluid, the properties of the protective coatings on the metal surface were very important, and epoxy Novolac coating was applied in this work. On the base of acid immersion tests, hot sulfuric acid decreased the hardness of the coatings and reduced greatly the content of $Na_2O$, $Al_2O_3$, and $SiO_2$ among the main components of the coating. A special kind of CP(Cathodic Protection) system has been developed and tested in a real scale of the FGD facility. Applied coating for this CP system was peeled off and cracked in some parts of the facility. However, the exposed metal surface to extremely acidic fluid by the failure of the coatings was successfully protected by the new CP system.

• 한국의류산업학회지
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• 제15권4호
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• pp.630-634
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• 2013

Cow leather coated with polyurethane film that contains various organic photosensitizers was investigated to demonstrate the antimicrobial properties in the application of the material to protective clothing and home appliances. To prepare the antimicrobial coating on leather surfaces with high potency against microbes, photoactive agents, such as benzophenone (BP), 4,4'-bis(dimethylamino) benzophenone (MK), 4,4'-dihydroxybenzophenone (DHBP) and methylene blue (MB), were incorporated into polyurethane-based coating solutions. The photoactive antimicrobial agent treated leather samples were characterized by SEM, color appearance, color fastness against abrasion, and antimicrobial tests. The optical properties of organic photosensitizers indicated that active UV absorbance ranges were different: BP (around 250 nm), MK (around 360 nm), DHBP (around 305 nm) and MB (around 295 nm &570 nm-685 nm). The intensity of the UV absorbance curve at the UVA light wavelength for the antimicrobial test showed the highest value with MK; subsequently, this was followed by MB, DHBP and BP in decreasing order. The treated-leather samples demonstrated excellent antibacterial activity under UVA light. The antimicrobial effects for the Staphylococcus aureus were superior to Escherichia coli. Moreover, the polyurethane finishing showed an effective durability to abrasion. The overall results indicated that DHBP is the most suitable PU coating additive to provide antimicrobial properties to leather as well as color and surface appearance than MK, MB, and BP.

• 대한소아치과학회지
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• 제24권3호
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• pp.495-510
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• 1997

The purpose of this study was to evaluate the efficacy of several surface coating agents in preventing microleakage and increasing microhardness of light-cured glass ionomer restoration. 50 and 25 sound molar teeth were used for the microleakage test and microhardness test respectively. Data were analyzed statistically using Kruskal-Wallis and/or Mann-Whitney test. The results of the present study were as follows: 1. The effect of surface coating in reducing microleakage was proven only at the gingival margin of restorations with statistical significance(p<.05). 2. The distribution of microleakage score at gingival margin was shown to be better than that of occlusal margin in general but with no statistically significant differences(p>.05). 3. No statistically significant differences in microhardness could be found between groups (p>.05) regardless of depth of measurement. 4. Under the present experimental conditions, the types or application of surface coating agents did not impose any significant effect on microhardness of glass ionomer restorative material whereas the protective effect of surface coating in reducing microleakage was partly proven.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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• pp.205.2-205.2
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• 2014

The effects of ion beam mixing of a SiC film coated on super alloys (hastelloy X substrates) were studied, aiming at developing highly sustainable materials at above $900^{\circ}C$ in decomposed sulfuric acid gas (SO2/SO3/H2O) channels of a process heat exchanger. The bonding between two dissimilar materials is often problematic, particularly in coating metals with a ceramics protective layer. A strong bonding between SiC and hastelloy X was achieved by mixing the atoms at the interface by an ion-beam: The film was not peeled-off at ${\geq}900^{\circ}C$, confirming excellent adhesion, although the thermal expansion coefficient of hastelloy X is about three times higher than that of SiC. Instead, the SiC film was cracked along the grain boundary of the substrate at above $700^{\circ}C$. At ${\geq}900^{\circ}C$, the film was crystallized forming islands on the substrate so that a considerable part of the substrate surface could be exposed to the corrosive environment. To cover the exposed areas and cracks multiple coating/IBM processes have been developed. An immersion corrosion test in 80% sulfuric acid at $300^{\circ}C$ for 100 h showed that the weight retain rate was gradually increased when increasing the processing time.

• 한국재료학회지
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• 제23권12호
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• pp.702-707
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• 2013

High-quality ${\beta}$-silicon carbide (SiC) coatings are expected to prevent the oxidation degradation of carbon fibers in carbon fiber/silicon carbide (C/SiC) composites at high temperature. Uniform and dense ${\beta}$-SiC coatings were deposited on carbon fibers by low-pressure chemical vapor deposition (LP-CVD) using silane ($SiH_4$) and acetylene ($C_2H_2$) as source gases which were carried by hydrogen gas. SiC coating layers with nanometer scale microstructures were obtained by optimization of the processing parameters considering deposition mechanisms. The thickness and morphology of ${\beta}$-SiC coatings can be controlled by adjustment of the amount of source gas flow, the mean velocity of the gas flow, and deposition time. XRD and FE-SEM analyses showed that dense and crack-free ${\beta}$-SiC coating layers are crystallized in ${\beta}$-SiC structure with a thickness of around 2 micrometers depending on the processing parameters. The fine and dense microstructures with micrometer level thickness of the SiC coating layers are anticipated to effectively protect carbon fibers against the oxidation at high-temperatures.