• 멤브레인
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• 제30권1호
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• pp.30-37
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• 2020

리튬 덴드라이트의 효과적인 억제를 위해 유/무기 복합체를 리튬메탈 전극의 보호층으로 사용하였다. 유기물로는 PVDF-HFP가 사용되었으며 무기물로는 TiO₂가 사용되었다. 유기물로 사용된 PVDF-HFP는 높은 유연성을 가지는 고분자로서 무기물의 matrix 역할을 하며, 무기물로 사용된 TiO₂ 나노입자는 보호막의 기계적 강도와 이온전도성을 향상시켜주는 역할을 하였다. 합성된 보호막은 SEM, AFM, XRD를 통하여 PVDF-HFP matrix에 TiO₂가 잘 분산되어 있는 형태인 것을 확인할 수 있었다. 또한 전기화학적 분석 결과, 향상된 기계적 물성과 이온전도성으로 인해 polymer-inorganic composite은 비교 샘플(untreated 와 PVDF-HFP 보호층) 대비 100번째 사이클까지 80%의 높은 쿨롱 효율 및 20 mV 미만의 낮은 과전압을 나타내었다.

• Nuclear Engineering and Technology
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• 제54권12호
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• pp.4431-4440
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• 2022

An advanced nuclear reactor based on molten salts including a molten salt reactor and pyroprocessing needs a sensitive monitoring system suitable for operation in harsh environments with limited access. Multi-element detection is challenging with the conventional technologies that are compatible with the in-situ operation; hence laser-induced breakdown spectroscopy (LIBS) has been investigated as a potential alternative. However, limited precision is a chronic problem with LIBS. We increased the precision of LIBS under high temperature by protecting optics using a gas protective layer and correcting for shotto-shot variance and lens-to-sample distance using a laser-induced acoustic signal. This study investigates cerium as a surrogate for uranium and corrosion products for simulating corrosive environments in LiCl-KCl. While the un-corrected limit of detection (LOD) range is 425-513 ppm, the acoustic-corrected LOD range is 360-397 ppm. The typical cerium concentrations in pyroprocessing are about two orders of magnitude higher than the LOD found in this study. A LIBS monitoring system that adopts these methods could have a significant impact on the ability to monitor and provide early detection of the transient behavior of salt composition in advanced molten salt-based nuclear reactors.

• 한국진공학회지
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• 제8권1호
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• pp.70-74
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• 1999

Plasma Display Panel(PDP)에서 보호막 물질로 사용중인 MgO 특성을 개선하기 위하여 본 연구에서는 MgO-CaO 박막을 전자빔 증착법으로 제조하였다. MgO 최대 증착속도는 1025 $\AA$/min이었으며 CaO 첨가비가 증가함에 따라 증착속도는 감소하였고, XRD 패턴은 전체적으로 낮은 2$\theta$각 방향으로 이동하였다. MgO 대한 CaO의 최대 고용도는 0.13이다. 최적전압특성을 나타낸 조성은 Mg 47.1 at%, Ca 1.3 at%, O 51.6 at%이었으며 이때 방전개시전압은 176 V, 메모리마진은 0.5였으며 증착속도는 515$\AA$/min이었다.

• 한국재료학회지
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• 제19권7호
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• pp.349-355
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• 2009

Metal thin film patterns on a LTCC substrate, which was connected through inner via and metal paste for electrical signals, were formed by a screen printing process that used electric paste, such as silver and copper, in a conventional method. This method brought about many problems, such as non uniform thickness in printing, large line spaces, and non-clearance. As a result of these problems, it was very difficult to perform fine and high resolution for high frequency signals. In this study, the electric signal patterns were formed with the sputtered metal thin films (Ti, Cu) on an LTCC substrate that was coated with protective oxide layers, such as $TiO_2$ and $SiO_2$. These electric signal patterns' morphology, surface bonding strength, and effect on electro plating were also investigated. After putting a sold ball on the sputtered metal thin films, their adhesion strength on the LTCC substrate was also evaluated. The protective oxide layers were found to play important roles in creating a strong design for electric components and integrating circuit modules in high frequency ranges.

• Applied Science and Convergence Technology
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• 제24권6호
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• pp.232-236
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• 2015

The electro-optical characteristics of several functional layers over the MgO protective layer were studied during the continuous discharge of an AC-PDP. In order to observe the degradation of each functional layer on the MgO protection layer, we measured the surface morphology, cathodoluminescence (CL) spectrum, the secondary electron emission coefficient (${\gamma}$) and the discharge characteristics after 500 hours of discharge during the operation of the AC-PDP.

• 한국전기전자재료학회논문지
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• 제21권5호
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• pp.468-473
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• 2008

A MgO layer is used as electrode protective film in the alternating current plasma display panel (AC PDP). The properties of MgO layer are thought to be one of the most important factors that affects the panel reliability through the firing voltage variation. In this study, we investigated the relations between the surface characteristics and e-beam evaporation process parameters such as deposition rate, temperature of substrate and distance between the MgO pellet and substrate. To produce the MgO layer of (200) crystal orientation, we suggest the high temperature of the substrate, the long distance between the pellet and substrate and the high deposition rate.

• Tribology and Lubricants
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• 제7권1호
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• pp.16-27
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• 1991

The mechanism of failure of lubricated surfaces at high sliding speeds was investigated. Experiments were performed with the ball-on-flat and cylinder-on-flat geometries, using lubricants of four different chemical reactivities. Surface failure was found to not be predictable using the ratio, $\lambda$, of fluid film thickness to composite surface roughness except when chemically inert lubricants are used. Even then the influence of temperature rise on fluid film thickness does not adequately explain the low load carrying capacity of lubricants at high sliding speeds, which causes surface failure. The protective layers on sliding surfaces that form by chemical reaction with the lubricant were found to reduce the surface roughening and increase the load carrying capacity of surfaces to values of $\lambda$ as low as 0.03. Neither the surface roughening nor the formation of the protective layers have been incorporated into failure models for lubricated systems.

• 한국화재소방학회논문지
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• 제28권4호
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• pp.97-103
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• 2014

소방보호복은 고열유속에 의한 화상방지를 위해 3층 이상의 복합소재로 구성되어 있으며, 각 소재 사이는 공기 간극이 존재한다. 화재에 의한 고열유속 노출 시 공기 간극 내에서의 열전달은 대류와 복사에 의해 주로 발생하며, 그로 인해 간극의 크기에 따라서 비선형 특징의 열 저항 크기를 갖게 된다. 그러므로 본 연구에서는 보호복 소재 사이의 여러 가지 공기 간극(0~7 mm)에 대한 보호복의 열 보호성능을 자세히 파악하기 위한 실험을 수행하였다. 복사 열 유속 입사시에 시간에 따른 각 소재의 온도 변화뿐만 아니라, 열 보호성능을 가장 효과적으로 나타낼 수 있는 지표(Radiant Protective Performance, RPP) 값의 공기간극에 대한 변화 특성을 파악하였다. 공기간극이 증가할수록 단열효과가 커짐으로 인해 후면의 온도는 낮아지고, RPP는 커짐을 확인할 수 있었다. 특히 일정 열유속 조건에서 공기간극에 대한 RPP 값은 선형적인 특성을 나타내었고, 그러한 결과를 바탕으로 다양한 입사 열유속 및 공기 간극 조건에 대해 비교적 간단한 형태의 RPP 지표 예측 식을 제안하였고, 좋은 예측 결과를 얻을 수 있었다.

• 한국의류산업학회지
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• 제21권5호
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• pp.606-617
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• 2019

The present study newly developed a firefighters' protective jacket and pants using a Nomex honeycomb structured layer (HPC) in cases of being exposed to flashover or flameover. This study evaluated the protective and comfort functions of an HPC compared to the current KFI firefighters' protective clothing (FPC). The results are as follows. First, thermal protective performance (TPP) of fabric layers was 2.75 times greater for HPC than FPC at $125kW/m^2$. Second, the predicted second and third degree burn areas were smaller for HPC than FPC when using a flame manikin. Third, thermal insulation using a thermal manikin was 0.2 clo greater for HPC than FPC. Fourth, there were no marked differences in maximal performance, mobility, and microclimate temperature/humidity between FPC and HPC through human wear trials. The thermal insulation of HPC was higher than that of FPC; however, any negative effect of HPC thermal insulation on the comfort functions for firefighters was not found. In conclusion, the newly-developed HPC provided more protection in reducing burn injuries from $125kW/m^2$, while no negative impact on maximal performance, mobility and thermal comfort functions of firefighters, which is appropriate for quick-evasive tactics at the flashover, flameover or back draft fires.

• 한국윤활학회:학술대회논문집
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• 한국윤활학회 2002년도 proceedings of the second asia international conference on tribology
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• pp.153-154
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• 2002

Wear map of silver coatings on AISI 52100 has been constructed to delineate the wear transition behavior with the change in operating conditions in various environments. Three main regimes were clearly identified: (i) elastic/plastic deformation of silver coating without failure. (ii) mild wear regime after initial failure of silver coating and (iii) severe wear regime. In the mild wear regime, the contact surfaces were covered with transfer layers of agglomerated wear particles. The transfer layer acted as a protective layer and resulted in low friction even after the initial failure of the coated films, whose characteristics were strongly dependent on both the operating and environmental conditions. Also, the existence of the critical sliding speed, above which no transfer layer was able to form, was discussed in the work.