• Title/Summary/Keyword: Propylenediaminetetraacetate

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NMR Studies on the Isomerization of Vanadium(V)-Propylenediaminetetraacetate Complex in Solution

  • Han, Sang-Gyu;Park, Sam-Soo;Lee, Man-Ho;Park, Heai-Ku
    • Bulletin of the Korean Chemical Society
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    • v.25 no.1
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    • pp.106-108
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    • 2004

  • In this paper we have determined the thermodynamic parameters for the isomerization between the ${\alpha}$-cis and the ${\beta}$-cis isomers in vanadium(V)-propylenediaminetetraacetate complex in water by $^{51}V$ NMR spectroscopy. In addition, the effects of organic solvents (methanol, formamide and dimethylsulfoxide) and inorganic salts (NaCl, $NaClO_4\;and\;NH_4Cl$) on the isomerization in solution have been investigated.

  • https://doi.org/10.5012/bkcs.2004.25.1.106 인용 PDF KSCI