• 한국추진공학회지
• /
• 제18권3호
• /
• pp.17-25
• /
• 2014

본 논문은 장약포의 저장기간에 따른 파단하중 저하에 관하여 감마과정 모델을 이용하여 저장수명을 예측하는 방법에 대한 연구결과이다. 추진제의 자연분해로 발생하는 질소화합물과 장약포의 화학반응은 파단하중을 저하시킨다. 장약포의 가속수명시험 결과에 감마과정 모델을 적용하여 시간의 경과에 따른 상태와 수명을 확률분포로 표현하였다. 저장수명은 중위수로 표현하고 품질보증을 위한 정책결정기준으로 $B_1$ 또는 $B_5$ 수명을 활용하는 것이 적절하다.

• 품질경영학회지
• /
• 제42권3호
• /
• pp.291-300
• /
• 2014

Purpose: The purpose of this study is to provide a statistical method from the data of ASRP's results and to apply to the reliability assessment of 155mm propelling charge, KM4A2. Methods: The accumulated data through ASRP for 155mm propelling charge were analyzed using regression analysis and MINITAB reliability analysis. The analysis methods used for this study were applied to statistical data types such as continuous data, binominal data. Results: The results of this study are as follows; The failure of 155mm propelling charge is mainly due to the broken charge bag, the decline of stabilizer content. The shelf-life(B5) regarding broken charge bag is 21.1years. The stabilizer content decrease with 0.0227%/year and safety storage period of propellant is 34.6years. Conclusion: The shelf-life of 155mm propelling charge determined by charge bag is estimated 21.1years.

• 한국안전학회지
• /
• 제11권4호
• /
• pp.97-106
• /
• 1996

Some of accidents are based on unstable chemical substances. These chemicals are easily decomposed or Ignited by heats or mechanical shocks like sodium azide. Sodium azide is commonly used as propellant for inflating automotive safety bags and the other chemical manufacturing purposes. The investigation of thermal hazard potential of sodium azide is very important because unexpected traffic accident can be occureed. The experiments were carried out by DSC, TG an ARC in air, oxygen, argon and nitrogen atmosphere. The decomposition temperatures were about $410^{\circ}C$~$420^{\circ}C$ by DSC and $330^{\circ}C$~$370^{\circ}C$ by ARC, this is very significant result for treatment of chemical. The heats of decomposition were about 81 kcal/mol in ai. and 10 kcal/mol in other atmosphere.