• Membrane and Water Treatment
• /
• 제7권5호
• /
• pp.403-416
• /
• 2016

The possibility of using carica papaya leaf powder for removal of copper from wastewater as a low cost adsorbent was explored. Different parameters that affect the adsorption process like initial concentration of metal ion, time of contact, adsorbent quantity and pH were evaluated and the outcome of the study was tested using adsorption isotherm models. A maximum of 90%-94.1% copper removal was possible from wastewater having low concentration of the metal using papaya leaf powder under optimum conditions by conducting experimental studies. The biosorption of copper ion was influenced by pH and outcome of experimental results indicate the optimum pH as 7.0 for maximum copper removal. Copper distribution between the solid and liquid phases in batch studies was described by isotherms like Langmuir adsorption and Freundlich models. The adsorption process was better represented by the Freundlich isotherm model. The maximum adsorption capacity of copper was measured to be 24.51 mg/g through the Langmuir model. Pseudo-second order rate equation was better suited for the adsorption process. A dynamic mode study was also conducted to analyse the ability of papaya leaf powder to remove copper (II) ions from aqueous solution and the breakthrough curve was described by an S profile. Present study revealed that papaya leaf powder can be used for the removal of copper from the wastewater and low cost water treatment techniques can be developed using this adsorbent.

• 천문학회보
• /
• 제41권2호
• /
• pp.66.2-66.2
• /
• 2016

KASI and NAOJ are making collaborating efforts to implement faster mapping capability into the new 275-500 GHz Atacama Submillimeter Telescope Experiment focal plane array (FPA). Feed horn antenna is one of critical parts of the FPA. Required fractional bandwidth is almost 60 % while that of traditional conical horn is less than 50 %. Therefore, to achieve this wideband performance, we adopted a horn of which the corrugation depths have a longitudinal profile. A profiled horn has features not only of wide bandwidth but also of shorter length compared to a linear-tapered corrugated horn, and lower cost fabrication with less error can be feasible. In our design process the flare region is represented by a cubic splined curve with several parameters. Parameters of the flare region and each dimension of the throat region are optimized by a differential evolution algorithm to keep >20 dB return loss and >30 dB maximum cross-polarization level over the operation bandwidth. To evaluate RF performance of the horn generated by the optimizer, we used a commercial mode matching software, WASP-NET. Also, Gaussian beam (GB) masks to far fields were applied to give better GB behavior over frequencies. The optimized design shows >23 dB return loss and >33 dB maximum cross-polarization level over the whole band. Gaussicity of the horn is over 96.6 %. The length of the horn is 12.5 mm which is just 57 % of the ALMA band 8 feed horn (21.96 mm).

• 한국전산유체공학회지
• /
• 제21권1호
• /
• pp.43-49
• /
• 2016

Thermal cracking is commonly modeled as plug flow reaction, neglecting the lateral gradients present. In this paper, 2-dimensional computational fluid dynamics including turbulence model and molecular reaction scheme are carried out. This simulation is solved by means of coupled implicit scheme for stable convergence of solution. The reactor is modeled as an isothermal tube, whose length is 1.2 m and radius is 0.01 m, respectively. At first, The radial profile of velocity and temperature at each point are predicted in its condition. Then the bulk temperature and conversion curve along the axial direction are compared with other published data to identify the reason why discussed variations of properties are important to product yield. Finally, defining a new non-dimensional number, Effect of interaction with turbulence, heat transfer and chemical reaction are discussed for design of thermal cracking furnace.

• Bulletin of the Korean Chemical Society
• /
• 제35권7호
• /
• pp.2130-2134
• /
• 2014

A kinetic study is reported on nucleophilic substitution reactions of 4-nitrophenyl isonicotinate (7) with a series of cyclic secondary amines in MeCN. The plots of $k_{obsd}$ vs. [amine] curve upward for the reactions with weakly basic amines (e.g., morpholine, 1-(2-hydroxyethyl)piperazine, and piperazine) but are linear for those with strongly basic amines (e.g., piperidine and 3-methylpiperidine). The curved plots for the reactions with the weakly basic amines are typical for reactions reported previously to proceed through uncatalyzed and catalyzed routes with two intermediates (e.g., a zwitterionic tetrahedral intermediate $T^{\pm}$ and its deprotonated form $T^-$). In contrast, the linear plots for the reactions with the strongly basic amines indicate that the catalytic route (i.e., the deprotonation process to yield $T^-$ from $T^{\pm}$ by a second amine molecule) is absent. The Br${\o}$nsted-type plots for $Kk_2$ and $Kk_3$ (i.e., the rate constants for the uncatalyzed and catalyzed routes, respectively) exhibit excellent linear correlations with ${\beta}_{nuc}$ = 0.99 and 0.69, respectively. The effect of amine basicity on the reaction mechanism is discussed in detail.

• 설비공학논문집
• /
• 제26권3호
• /
• pp.122-129
• /
• 2014

In order to extract shaft power from thermal energy in a R134a Rankine cycle as waste heat recovery system of a passenger car, a scroll expander has been designed. Algebraic spiral is adopted as the base curve for scroll wrap profile in the compact scroll design. About 19% reduction in scroll diameter is accomplished when compared to the conventional involute scroll. Performance analysis on the designed scroll expander shows that the expander efficiency is 85.5% at the vehicle speed of 120 km/hr and it decreases to 67.2% at 60 km/hr, provided that the scroll clearance is kept at 10 ${\mu}m$. The expander can produce shaft power equivalent to about 13~14% of the driving power within the speed range of 60~120 km/hr.

• Geomechanics and Engineering
• /
• 제15권1호
• /
• pp.621-630
• /
• 2018

In the note a comprehensive and optimal passive-active mode for describing the limit failure of circular shallow tunnel with settlement is put forward to predict the catastrophic stability during the geotechnical construction. Since the surrounding soil mass around tunnel roof is not homogeneous, with tools of variation calculus, several different curve functions which depict several failure shapes in different soil layers are obtained using virtual work formulae. By making reference to the simple-form of Power-law failure criteria based on numerous experiments, a numerical procedure with consideration of combination of upper bound theorem and stochastic medium theory is applied to the optimal analysis of shallow-buried tunnel failure. With help of functional catastrophe theory, this work presented a more accurate and optimal failure profile compared with previous work. Lastly the note discusses different effects of parameters in new yield rule and soil mechanical coefficients on failure mechanisms. The scope of failure block becomes smaller with increase of the parameter A and the range of failure soil mass tends to decrease with decrease of unit weight of the soil and tunnel radius, which verifies the geomechanics and practical case in engineering.

• Ocean and Polar Research
• /
• 제34권2호
• /
• pp.265-273
• /
• 2012

A new algorithm was developed, not only to detect the existence of a thermocline, but also to extract the thermocline parameters (such as thermocline thickness, mixed layer thickness, maximum temperature gradient, and temperature difference of thermocline), using the vertical profile of water temperature. According to Kappa analysis, in order to find adequate threshold values of vertical water temperature gradients ${\Delta}T$ ($^{\circ}C/m$), agreement and reliability were 87% and 0.74 respectively, in the conditions of maximum ${\Delta}T{\geq}0.5$ and surface and bottom layers ${\Delta}T<{\mid}0.2{\mid}$. Also, three different kinds of methods, viz. 1. Gradient method, 2. Hyperbolic tangent method, and 3. Differential hyperbolic tangent method, were tested to extract the key parameters of a thermocline. Comparing the results of three different methods, the differential hyperbolic tangent method was the most appropriate to extract the start and end point of a thermocline curve.

• 유체기계공업학회:학술대회논문집
• /
• 유체기계공업학회 1998년도 강연회 및 연구개발 발표회 논문집
• /
• pp.128-135
• /
• 1998

Procedures and results of aerodynamic design of a centrifugal compressor are presented for development of a 40kW class turbogenerator gas turbine. Specification of higher level of total pressure ratio of 4 and total efficiency of $80\%$ requires advanced methods of design and analysis. In the meanline design/analysis, a method with conventional loss modeling and a method with the two-zone model are alternately used for more reliable prediction. In the impeller blade generation, a series of Bezier curve are combined to produce meridional contours and distributions of blade camber angle and blade thickness. Intermediate profiles of blades are repeatedly produced and changed to be finally fixed through quasi-three dimensional Euler flow analysis. Three dimensional compressible turbulent flow analysis is then performed for the impeller to be confirmed in the final step of design. Satisfactory results in the aerodynamic performance are obtained, which assures that there is no need of aerodynamic re-design.

• International Journal of Precision Engineering and Manufacturing
• /
• 제8권3호
• /
• pp.64-70
• /
• 2007

Of all the rapid tooling (RT) methods currently available, thick-layer laminated tooling is the most suitable for large-scale, low-cost dies and molds. Currently, the determination of a lamina's contour or profile and the associated slicing algorithms are based on existing rapid prototyping (RP) data manipulation technology. This paper presents a new adaptive slicing algorithm developed exclusively for profiled edge laminae (PEL) tooling PEL tooling is a thick-layer RT technique that involves the assembly of an array of laminae, whose top edges are simultaneously profiled and beveled using a line-of-sight cutting method based on a CAD model of the intended tool surface. The cutting profiles are based on the intersection curve obtained directly from the CAD model to ensure geometrical accuracy. The slicing algorithm determines the lamina thicknesses that minimize the dimensional error using a new tool shape error index. At the same time, the algorithm considers the available lamination thicknesses and desired lamina interface locations. We demonstrate the new slicing algorithm by developing a simple industrial PEL tool based on a CAD part shape.

• 대한기계학회논문집B
• /
• 제26권1호
• /
• pp.125-132
• /
• 2002

An experimental study on the characteristics of stability of propane turbulent nonpremixed jet flames discharged normal to air free-streams with uniform velocity profile is conducted. Experimental observations are focused on the flame shape, the stability considering two kinds of flame, lift-off distance, and the flame length according to velocity ratio. In order to investigate the mixing structure of the flame base at the lower limit, we employ the RMS technique and measure the species concentration by a gas chromatography. In the results of the stability curve and lifted flame, it is fecund that the dependency of nozzle diameter is closely related to the large-scale vortical structure representing counter-rotating vortices pair. Also, the detailed discussion on the phenomenon of blowout due to this large vortical motion, is provided.