• Title/Summary/Keyword: Product flow

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The Studies of Photocatalyst Development and the Optimum Operation Conditions for the Removal of Ammonia in a Mixed Reactor of Liquid-vapor Phase (기-액 복합 광반응기에서의 악취성 암모니아 제거를 위한 촉매개발과 반응시스템의 최적조건 색출 연구)

  • Kim, Hae-Ri;Jeon, Min-Kyu;Kim, Joon-Woo;Joo, Gwang-Tae;Choung, Suk-Jin
    • Journal of Korean Society for Atmospheric Environment
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    • v.24 no.5
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    • pp.512-522
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    • 2008
  • Ammonia is a major compound of odor in livestock house. To enhance the performance of ammonia oxidation (decomposition). the gas-liquid, two phase photocatalytic oxidation system was designed and prepared in this study. Commercial P-25 as $TiO_2$ catalyst was used for ammonia decomposition. V/P-25 catalyst prepared by sol gel method was also used for the removal of by-producted $NO_x$ in $NH_3$ oxidation reaction. When $TiO_2$ was used as a photocatalyst, the conversion to $N_2$ in ammonia decomposition reached above 90% until 200hr (The air flow rate of 4L/min with the ammonia concentration up to 25ppm.). However, considerable amounts of NO and $NO_2$ were formed as a result of $NH_3$ oxidation (as a by-product). Therefore, we added Vanadia impregnated $TiO_2$(P-25) catalyst for the removal of $NO_x$ at the end of reaction trail. The results of a pilot-scale operation were successful to achieve the simultaneous removal of $NH_3\;and\;NO_x$ about 81 and 87%, respectively.

Study on Plugging Criteria for Thru-wall Axial Crack in Roll Transition Zone of Steam Generator Tube (증기발생기 전열관 확관천이부위 축방향 관통균열의 관막음 기준에 관한 연구)

  • Park, Myeong-Gyu;Kim, Yeong-Jong;Jeon, Jang-Hwan;Kim, Jong-Min;Park, Jun-Su
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.20 no.9
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    • pp.2894-2900
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    • 1996
  • The stream generator tubes represent an integral part of a major barrier against the fission product release to the environment. So, the rupture of these tubes could permit flow of reactor coolant into the secondary system and injure the safety of reactor coolant system. Therefore, if the crack was detected during In-Service Inspection of tubes the cracked tube should be evaluated by the pulgging criteria and plugged or not. In this study, the fracture mechanics evaluation is carried out on the thru-wall axial crack due to Primary Water Stress Corrosion Cracking in the roll transition aone of steam generator tube to help the assurence the integrity of tubes and estabilish the plugging criteria. Due to the Inconel which is used as tube material is more ductile than others, the plastic instability repture theory was used to calculate the critical and allowable crack length. Based on Leak Before Break concept the leak rate for the critical crack length and the allowable leak rate are compared and the safety of tubes was given.

Development of Integrated System for Virtual Design and Performance Testing of Automobile Seat (자동차 시트 가상설계와 성능평가를 위한 통합시스템 개발)

  • Im, O-Gang;Yu, Wan-Seok;Jeong, Yung-Ho;Kim, Gwang-Seok;Lee, Jin-Sik;No, Hyo-Cheol
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.24 no.7 s.178
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    • pp.1779-1786
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    • 2000
  • Most of traditional design processes of mechanical parts are regarded as sequential and discrete, since different kinds of softwas should be introduced. In this paper, we develop an integrated fram ework for virtual design and performance testing of an automobile seat. The system is composed of four modules, i.e. CAD, static analysis, dynamic analysis, and draft drawing module. In the CAD module, PRO/ENGINEER 3D seat model is created using parameters to be modified with the result of static and dynamic analysis. In the static analysis, headrest tere used in each design stage make it difficult to feedback their results to upstream process. These discrete processes may result in time loss and cost rise. In recent years, life cycle of product is reduced. To have competence with others, new concept design processt is simulated using ANSYS. In the dynamic analysis module, FMVSS201 test is simulated using DADS. Overall data flow is controlled by Motif. The advantage of the system is that even a novice can perform and review the whole design process, without a good hand at professional design/analysis S/W in each stage. The system also provides a virtual design space, where engineers in different development stage can access common data of design models. The concept could be applied to other fields and it could reduce time and money required in design process.

Effects of Alkali-Activated Soil Stabilizer Binder Based on Recycling BP By-Products on Soil Improvement (BP부산물을 재활용한 알칼리활성화 지반개량재의 지반개량효과에 관한 연구)

  • Lee, Yeong-Won;Kang, Suk-Pyo;Kim, Jae-Hwan
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.2 no.2
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    • pp.158-165
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    • 2014
  • The enormous quantity of 'Bayer-Process by-products' (BP by-products) discharged by industries producing alumina from bauxite represents an environmental and economical problem. As it is mainly composed of $Fe_2O_3$, $Al_2O_3$, $SiO_2$, CaO and $Na_2O$, it is thought that using BP by-products as a construction material is an effective way to consume such a large quantity of alkaline waste. In this study, This study evaluates the effect of alkali-activated binder based on recycling BP by-products on soil improvement through the evaluation of slope stability and seepage flow numerical analysis. The results of analysis of ground slope safety at dry season and wet season meet standard (Ministry of Land, Infrastructure and Transport, 2006) Especially, when wet season, the ground used soil improving material meet standard, while the ground used soil-nailing method doesn't. Also, permeability coefficient of improved soil is smaller than that of natural soil and saturation depth of reinforced ground surface with improve soil is lower than that of natural soil.

Characterization of aluminized RDX for chemical propulsion

  • Yoh, Jai-ick;Kim, Yoocheon;Kim, Bohoon;Kim, Minsung;Lee, Kyung-Cheol;Park, Jungsu;Yang, Seungho;Park, Honglae
    • International Journal of Aeronautical and Space Sciences
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    • v.16 no.3
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    • pp.418-424
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    • 2015
  • The chemical response of energetic materials is analyzed in terms of 1) the thermal decomposition under the thermal stimulus and 2) the reactive flow upon the mechanical impact, both of which give rise to an exothermic thermal runaway or an explosion. The present study aims at building a set of chemical kinetics that can precisely model both thermal and impact initiation of a heavily aluminized cyclotrimethylene-trinitramine (RDX) which contains 35% of aluminum. For a thermal decomposition model, the differential scanning calorimetry (DSC) measurement is used together with the Friedman isoconversional method for defining the frequency factor and activation energy in the form of Arrhenius rate law that are extracted from the evolution of product mass fraction. As for modelling the impact response, a series of unconfined rate stick data are used to construct the size effect curve which represents the relationship between detonation velocity and inverse radius of the sample. For validation of the modeled results, a cook-off test and a pressure chamber test are used to compare the predicted chemical response of the aluminized RDX that is either thermally or mechanically loaded.

Development of Degassing Valves for Food Packaging using Ring Type Rubber Disk (링타입 고무막을 이용한 식품 포장용 가스배출 밸브(Degassing Valve) 개발)

  • Yu, Ha Kyoung;Lee, Kyungo Ho;Oh, Jae Young
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.20 no.2
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    • pp.35-39
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    • 2014
  • One-way degassing valves are designed to allow pressure to be released from an air-tight package while preventing air from getting back into the package. Air, especially the oxygen ($O_2$) portion of air, can have negative effects on the package contents and its freshness. The most common application of the one-way degassing valve is for fresh roasted coffee. Demands of one-way degassing valves have been increasing with the high growth of global coffee market. In this study, we have developed one-way degassing valves for coffee and food packaging using ring type rubber disk, named SP valve. Its quality and performance was verified with test results to be equal with that of global top maker's product, Goglio valve. SP valves showed 820~1200 Pa of opening pressure, 10~50 Pa of closing pressure, 1.2~1.6 L/ min of flow rate. And, the SP valve applicable to ferment food packaging is expected to contribute to globalize Korean traditional food.

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Simultaneous Determination of Six Components in the Traditional Herbal Medicine 'Oryeongsan' by HPLC-DAD and LC-MS/MS

  • Lee, Jiwoo;Weon, Jin Bae;Lee, Bohyoung;Yun, Bo-Ra;Eom, Min Rye;Ma, Choong Je
    • Natural Product Sciences
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    • v.19 no.1
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    • pp.20-27
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    • 2013
  • A simple high performance liquid chromatography - diode array detector (HPLC-DAD) method has been developed and validated for simultaneous determination of the six components (cinnamic acid, cinnamaldehyde, eugenol, atractylenolide I, atractylenolide III, and ergosterol) in Oryeongsan. In addition, identification of six marker compounds was conducted by a LC-MS/MS analysis. The six compounds in Oryeongsan were separated on Shishedo $C_{18}$ column (5 ${\mu}m$, $4.6{\times}250$ mm) at a column temperature of $30^{\circ}C$. The mobile phase was a mixture of 0.1% trifluoroacetic acid (TFA) water and acetonitrile employing gradient elution at a flow rate of 1.0 mL/min. The detection wavelength was set at 205, 250, 280, and 330 nm. The developed method had good linearity ($R^2$ > 0.9997) and the limit of detection (LOD) and limit of quantification (LOQ) were observed within the ranges 0.01~0.15 and 0.05~0.45 ${\mu}g/mL$, respectively. The relative standard deviation (RSD) values of intra- and inter-day testing were indicated that less than 3% and 90.31~103.31% of accuracy. The results of recovery test were 90.56~106.72% and RSD range was measured from 0.84 to 2.95%. In conclusion, this HPLC-DAD method has been successfully applied to the simultaneous determination of six compounds in Oryeongsan samples.

A Study on the Unit Hydrograph Derivation by the Triangular Form (삼각도형에 의한 단위도의 유도에 관한 연구)

  • Yun, Hak-Gi;Kim, Si-Won;Seo, Seung-Deok
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.19 no.2
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    • pp.4377-4384
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    • 1977
  • The curvilinear hydrograph can be replaced by an equivalent triangular hydrograph which is more easily constructed and, for routing through reservoirs or stream channels, gives results about as accurate as those obtained using the curvilinear hydrograph. A synthetic hydrograph is prepared using the data from a number of watersheds to develop a dimensionless unit hydrograph applicable to ungauged watersheds. The dimensionless unit hydrograph for the NakDong River Basin was prepared from the unit hydrographs of a variety of nine subwatersheds. The equation for the peak rate of flow (unit volume of runoff in 1.0mm) was derived as {{{{ { q}_{p } = { 0.21AR} over { {T }_{p } } }}}} The results summarized in this study are as follows: 1) It found that the watershed lag time (Lg, hrs) could be expressed by Lg=0.253(L.Lca)0.4171 The product L.Lca is a measure of the size and shape of the watershed. Correlation coefficient for Lg was 0.97 which defined with high significance. 2) The base length of the unitgraph, in hours, was adopted as Tb=17.51+2.073Lg with high significant correlation coefficient, 0.92. 3) Time in hour from start of rise to peak rate (TP) generally occured at the position of 0.289 Tb with some indication of higher values for larger watershed. 4) Triangular hydrograph is a dimensionless unitgraph prepared from the 40 unitgraphs. The equation is shown as {{{{ { q}_{p } = { K.A.R} over { { T}_{p } } }}}}. The constant K=0.21 is defined to NakDong River basin. 5) In the light of the results analyzed in this study, average errors in the peak discharge of the Trjangular unitgraph was estimated as 5.34 percent to the peak of observed average unitgraph. Each ordinate of the Triangular unitgraph was approached closely to the observed one.

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Simultaneous Determination and Recognition Analysis of Coumarins in Angelica decursiva and Peucedanum praeruptorum by HPLC-DAD

  • Kim, Hye Mi;Jeong, Su Yang;Kim, Sun Min;Lee, Kyu Ha;Kim, Jong Hwan;Seong, Rack Seon
    • Natural Product Sciences
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    • v.22 no.3
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    • pp.162-167
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    • 2016
  • Peucedani Radix is the root of Angelica decursiva Franchet et Savatier (=Peucedanum decursivum Maximowicz) or Peucedanum praeruptorum Dunn in several Asian countries. The coumarins contained in Peucedani Radix were quantitatively analyzed using HPLC-DAD to develop a simultaneous determination for the quality control of A. decursiva and P. praeruptorum. For quantitative analysis, four major coumarins contained in these medicinal plants were assessed. Nodakenin (1), nodakenetin (2), praeruptorin A (3), and praeruptorin B (4) were separated with a Phenomenex Luna C18 column ($5{\mu}m$, $4.6{\times}250mm$) under the gradient conditions using distilled water with 0.1% phosphoric acid and acetonitrile with 0.1% phosphoric acid as the mobile phase, at a flow rate of 1.0 ml/min and a detection wavelength of 330 nm. This method was fully validated for linearity, accuracy, precision, recovery, and limit of detection and quantification. As a result, A. decursiva and P. praeruptorum were clearly classified by the quantification of four major coumarins in extracts. Also, the pattern recognition analysis based on HPLC indicates that all of the samples were largely clustered into two groups. Therefore, it is possible to distinguish between A. decursiva and P. praeruptorum and contribute to quality control.

Inhibitory Effect of D-chiro-inositol on Both Growth and Recurrence of Breast Tumor from MDA-MB-231 Cancer Cells

  • Kim, Yoon-seob;Park, Ji-sung;Kim, Minji;Hwang, Bang Yeon;Lee, Chong-kil;Song, Sukgil
    • Natural Product Sciences
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    • v.23 no.1
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    • pp.35-39
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    • 2017
  • D-chiro-inositol (DCI) is a secondary messenger in insulin signal transduction. It is produced in vivo from myo-inositol via action of epimerase. In this study, we evaluated antitumor activity of DCI against human breast cancer both in vitro and in vivo. In order to determine the inhibitory effects of DCI on growth of human breast cancer cells (MDA-MB-231), two different assessment methods were implemented: MTT assay and mouse xenograft assay. MTT assay demonstrated downturn in cell proliferation by DCI treatment (1, 5, 10, 20 and 40 mM) groups by 18.3% (p < 0.05), 17.2% (p < 0.05), 17.5% (p < 0.05), 18.4% (p < 0.05), and 24.9% (p < 0.01), respectively. Also, inhibition of tumor growth was investigated in mouse xenograft model. DCI was administered orally at the dose of 500 mg/kg and 1000 mg/kg body weight to treat nude mouse for 45 consecutive days. On the 45th day, tumor growth of DCI (500 mg/kg and 1000 mg/kg) groups was suppressed by 22.1% and 67.6% as mean tumor volumes were $9313.8{\pm}474.1mm^3$ and $3879.1{\pm}1044.1mm^3$, respectively. Furthermore, breast cancer stem cell (CSC) phenotype ($CD44^+/C24^-$) was measured using flow cytometry. On the 46th day, CSC ratios of DCI (500 mg/kg) and co-treatment with doxorubicin (4 mg/kg) and DCI (500 mg/kg) group decreased by 24.7% and 53.9% (p < 0.01), respectively. Finally, from tumor recurrence assay, delay of 5 days in the co-treatment group compared to doxorubicin (4 mg/kg) alone group was observed. Based on these findings, we propose that DCI holds potential as an anti-cancer drug for treatment of breast cancer.