• 제목/요약/키워드: Produced water

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산성화 과정이 황사입자 내 금속성분의 용해도에 미치는 영향: 실험실 연구결과 (Impact of Acidification on the Solubility of Metal Species in Asian Desert Dusts: Results from Laboratory Experiments)

  • 심수영;박승식;김덕래;이석조
    • 한국대기환경학회지
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    • 제29권1호
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    • pp.64-73
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    • 2013
  • Because some particulate matter emission sources may inherently produce soluble species, or some soluble species may be produced during atmospheric transport, it is important to understand the origin of a particles's solubility when water-soluble tracers are used in source apportionment studies. Laboratory experiments were performed on three types of soils (Mongolia grassland, Mongolia desert, and Korean rural soils), to study the impact of acidification by nitric acid vapor on the solubility of metals in the soils. To achieve this goal, concentrations of water-soluble metals (Na, Mg, Al, K, Ca, Mn, and Fe) in the soils measured before and after acidification. Contributions of concentrations of water-soluble metal species before and after acidification attack to their total concentrations varied little with soil type. Concentrations of water-soluble Mg, Al, K, Ca, Mn, and Fe from the soils after interaction with nitric acid vapor increased, with significant increases in soluble Ca and Mn for all soil types suggesting soil acidification enhances the amount of leachable metal species in soil dust. There was little increase in water-soluble Na and K after acidification for each soil type. This experiment demonstrates that quantities of water-soluble metal species in particulate matter are produced under high gaseous nitric acid conditions.

비전통자원개발에 따른 수처리 최신 기술 (Recent Water Treatment Technology for Unconventional Natural Resource Development)

  • 김극태;정건용;박정규
    • Korean Chemical Engineering Research
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    • 제52권2호
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    • pp.154-165
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    • 2014
  • 최근 수평시추, 수압파쇄 등의 기술발전에 따라 셰일가스, 셰일오일, 석탄층 메탄가스 등 비전통자원개발이 활성화 되었다. 이러한 기술발전으로 생산성이 향상되었지만, 화학약품이 포함된 수압파쇄 유체와 오일, 가스와 고농도의 염과 방사성 물질을 함유하는 생산수가 가스 생산중 발생하게 된다. 이같이 생성된 대량의 폐수에 따른 부정적인 환경적 요인은 비전통자원개발에 주요 장애요소로 급격히 대두되고 있다. 본 연구에서는 비전통자원개발에 따른 회수수와 생산수의 처리방법에 대한 융합적인 토대를 제시하고, 새롭게 떠오르는 다양한 수처리 기술을 총설하고자 한다. 비전통 자원개발 현장에 적용 가능한 기본적인 분리공정인 막분리, 증발, 결정화, 탈염공정 기술을 소개하고 또한 대량의 수자원을 사용하는 비전통자원개발의 특성상 물의 재이용 및 재활용이 가능한 기술을 소개하고자 한다.

Incorporation of water sludge, silica fume, and rice husk ash in brick making

  • Hegazy, Badr El-Din Ezzat;Fouad, Hanan Ahmed;Hassanain, Ahmed Mohammed
    • Advances in environmental research
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    • 제1권1호
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    • pp.83-96
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    • 2012
  • The water sludge is generated from the treatment of water with alum. Disposing of sludge again to the streams raises the concentrations of aluminum oxides in water, which has been linked to Alzheimer's disease. The use of water treatment plant (WTP) sludge in manufacturing of constructional elements achieves both the economical and environmental benefits. Due to the similar mineralogical composition of clay and WTP sludge, this study investigated the complete substitution of brick clay by sludge incorporated with some of the agricultural and industrial wastes, such as rice husk ash (RHA) and silica fume (SF). Three different series of sludge to SF to RHA proportions by weight were tried, which were (25: 50: 25%), (50: 25: 25%), and (25: 25: 50%), respectively. Each brick series was fired at 900, 1000, 1100, and $1200^{\circ}C$. The physical and mechanical properties of the produced bricks were then determined and evaluated according to Egyptian Standard Specifications (E.S.S.) and compared to control clay-brick. From the obtained results, it was concluded that by operating at the temperature commonly practiced in the brick kiln, a mixture consists of 50% of sludge, 25% of SF, and 25% of RHA was the optimum materials proportions to produce brick from water sludge incorporated with SF and RHA. The produced bricks properties were obviously superior to the 100% clay control-brick and to those available in the Egyptian market.

혐기성 발효에서 수소 생산 시 온도의 영향에 관한 연구 (Effects of Temperature on Production of Hydrogen in Anaerobic Fermentation)

  • 김충곤;강선홍
    • 상하수도학회지
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    • 제21권4호
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    • pp.467-475
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    • 2007
  • This study was conducted to examine temperature effects on hydrogen production in anaerobic fermentation. 18 batch reactors were operated at mesophilic ($35^{\circ}C$) and thermophilic conditions ($55^{\circ}C$) to achieve maximum hydrogen production in anaerobic fermentation. Optimum hydrogen production conditions were also investigated at each temperature. Different trends were observed regarding pH effects on hydrogen production. This effect was not significant for mesophilic fermentation ($35^{\circ}C$). In this case, pH may not drop to interfere hydrogen production during the test. However, hydrogen production decreased without pH control for thermophilic condition ($55^{\circ}C$). Effects of heat treatment were observed for both fermentation process. Hydrogen production with heat treatment was higher than hydrogen production without heat treatment for both fermentation processes. The amount of produced hydrogen for each substrate concentration with temperature changes showed that more hydrogen was produced at $35^{\circ}C$ than at $55^{\circ}C$.

분말야금공법으로 제조된 CAD/CAM용 Co-Cr-Mo 합금의 미세조직 및 기계적 특성 (Microstructure and Mechanical Properties of Co-Cr-Mo alloy for CAD/CAM Applications fabricated by Powder Metallurgy Process)

  • 차성수
    • 대한치과기공학회지
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    • 제37권4호
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    • pp.235-242
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    • 2015
  • Purpose: The aims of this study are compare with microstructure and mechanical properties of Co-Cr-Mo alloys fabricated by powder metallurgy(P/M) process and casting process respectively. Methods: Microstructure and micro-hardness were tested by SEM and Vickers Hardness Tester. The sintered specimen was produced by furnace-coolling after sintering, however the casting specimen were produced thru air-cooling and water-cooling after the casting. For observation of phase transformation during sintering, DSC analyzing was carried out. Results: Mean pore size of sintered Co-Cr-Mo alloy was $4.32{\mu}m$ and that of casting alloy was $1.63{\mu}m$. Hardness of sintered alloy was lower than water-quenched casting alloy. Conclusion: Proper sintering temperature of Co-Cr-Mo alloy was above $1,200^{\circ}C$ and pore size of casting specimen were finer than sintered specimen, but hardness were similar.

전기분해 방식에 의한 혼합산화제 소독 특성 평가 (Evaluation of Disinfection Characteristics for Mixed Oxidants Produced by Electro-chemical Method)

  • 이경혁;임재림;이두진;김성수;안효원
    • 상하수도학회지
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    • 제19권5호
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    • pp.625-631
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    • 2005
  • Disinfection characteristics of mixed oxidants produced by mean of electro-chemical method were evaluated. Inactivation rate of B. subtilis spore on the mixed oxidants were similar with that of chlorine. Based on the experimental results, activation energy of mixed oxidants and chlorine with B. subtilis spore at pH 8.3 were calculated as 30.8, $34.7kJ{\cdot}mol^{-1}$ respectively. UV absorption spectrum of both chlorine and mixed oxidants present similar. Molar extinction coefficients of chlorine and mixed oxidants at 292nm, which is maximum absorption wavelength of $OCl^-$ were 357, $377M^{-1}cm^{-1}$, respectively. Disinfectant decay rate and formation rate of THM in the S WTP filtrate also shows insignificant difference for both mixed oxidants and chlorine. In consequent, it was confirmed that high portion of chlorine presents in the mixed oxidants.

Potential Suppression of Dental Caries by Maltosyl-Mannitol Produced by Bacillus stearothermophilus Maltogenic Amylase

  • Cho Kil-Soon;Shin Sang-Ick;Cheong Jong-Joo;Park Kwan-Hwa;Moon Tae-Wha
    • Journal of Microbiology and Biotechnology
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    • 제16권3호
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    • pp.484-486
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    • 2006
  • Maltosyl (G2)-mannitol, produced by the transglycosylation of mannitol with maltotriose by Bacillus stearothermophilus maltogenic amylase, was not found to support lactic acid production by Streptococcus sobrinus NRRL 14555. Furthermore, the synthesis of water-insoluble glucans from maltosyl-mannitol by S. sobrinus NRRL 14555 was much lower than that from xylitol or mannitol. Consequently, these results suggest that maltosyl-mannitol could be used as a noncariogenic sugar substitute in food products.

Life Cycle Assessment(LCA)를 도입(導入)한 오니처리(汚泥處理)시스템의 평가(評價) (Life Cycle Assessment (LCA) on Sludge Treatment System)

  • 황용우;권봉기;유성호
    • 상하수도학회지
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    • 제11권2호
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    • pp.50-64
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    • 1997
  • Life cycle assessment (LCA) on total sewage sludge treatment system from thickening to incineration and melting was performed for estimating global environmental impact as $CO_2$. In general, the life cycles of actual treatment facilities consist of construction, operation and dismantlement. In this study, the amount of $CO_2$ produced from both whole and each life cycle step of currently used unit sludge treatment processes were calculated by inventory analysis. In addition, in the all processes investigated in this study, individual $CO_2$ production unit (CPU), i.e. total produced $CO_2$ by treating a unit weight of sludge was also calculated. By using the CPU matrix of the unit processes, it was possible to simulate the $CO_2$ production for any type of complex-system as well as to trace a dominant cause of $CO_2$ production in each process. Four selected alternatives examined here, each involve the same disposal way but differ substantially in the $CO_2$ exhaust.

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유동화재 변화에 따른 초미립자 시멘트의 유동특성 (Flow properties of Ultra Fine Cement with Superplasticizer)

  • 채재홍;이종열;이웅종;박경상;김진춘;이세웅
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 1999년도 봄 학술발표회 논문집(I)
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    • pp.58-63
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    • 1999
  • Almost all concrete structures have many inevitable cracks for various reasons such as drying shrinkage, heat liberation of cement, fatigues or repeating loads and movements. Conventionally, they are repaired with epoxy materials. The Epoxy resins used by repair materials are different from properties of the base concrete materials such as thermal and mechanical properties - thermal expansion coefficients, bending strength. And the epoxy resin cannot release the water inside the concrete structure and cause corrosion of the steel bars. In this study, before the experiment got launched, we had analyzed cement and slag. Then We blended the two grades of ultra fine cement using high blaine cement and slag. And the cement slurry was produced by water and suprplasticizer to each blended ultra fine cement in various conditions. The slurry produced by each conditions was evaluated with flow properties such as viscosity, dropping time, segregation and observation of dry surface after injection.

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순환잔골재를 사용한 굳지 않은 콘크리트의 특성 (Properties of Fresh Concrete with Recycled fine Aggregates)

  • 최기선;유영찬;윤현도;김긍환
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2008년도 추계 학술발표회 제20권2호
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    • pp.373-376
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    • 2008
  • The objective of this study is to investigate the properties of fresh concrete with recycled fine aggregates. Three different kinds of fine aggregate with natural, high and low quality recycled aggregates were prepared. The concrete mixtures were produced with test parameters of replacement ratio of recycled fine aggregate. The properties of the fresh concrete were measured by means of slump and air content according to elapsed time. Quality control method to maintain the constant total mixing water for recycled aggregate concrete was suggested. The all concrete mixtures were produced with approximately the same slump on the job site after an hour. Test results indicated that compressive strength of the concrete mixtures with constant slump is not affected by the replacement ratio of recycled fine aggregate. Therefore, the practical way for the quality control of recycled aggregate concrete is to maintain the constant total mixing water.

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