• Title/Summary/Keyword: Primary pollutants

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Long-term Trends of Visibility and Air Quality in Seoul, Ganghwa, Susan, Gwangju, Jeju (서울, 강화, 서산, 광주, 제주지역에서의 장기간 대기오염 및 시정 변화경향에 대한 연구 : 1990년 1월~2001년 7월)

  • Han, J.S.;Moon, Kwang-Joo;Kong, B.J.;Hong, Y.D.;Lee, S.J.;Shin, J.Y.
    • Journal of Environmental Impact Assessment
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    • v.13 no.4
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    • pp.197-211
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    • 2004
  • Visibility impairment was known as an indicator of the increased air pollution. In many previous studies, it is known that both directly emitted fine particles mainly from vehicles and secondary aerosols from photochemical reactions could contribute to this visibility impairment in addition to the meteorological condition. Furthermore, the visibility showed different change patterns according to the geographical condition. In order to research into the influence of these factors on visibility, this study analyzed the visibility at 15:00, observed from 1990 to 2001 in Seoul, Ganghwa, Susan, Gwangju, Jeju. As a result, the visibility was increased in Seoul except the rainfall period, but in Susan, Gwangju, Jeju, it decreased with the relative humidity (RH). Especially, in Seoul, the number of low visibility days was larger than other sites and variations of the visibility were sensitive to the concentration of air pollutants, such as TSP, $NO_2$, $O_3$. The visibility impairment was mainly observed in meteorological condition of RH<50% and relatively stationary front. Therefore it is inferred that photochemical smog could lead to the low visibility in Seoul. On the other hands, in Ganghwa and Susan, when RH was 60~70%, the low visibility observed under the influence of the transports of air pollutants from nearby cities as well as humid air mass from coastal region. And in Jeju, sea fog and humid air mass caused the visibility impairment when the RH was larger than 80%. Finally, during the observational period, some cases of low visibility phenomena were simultaneously observed in the vast region including Seoul, Susan, Ganghwa. It not only includes the visibility aggravation by Asian Dust, but also could be caused by the movement and diffusion of flying dust or secondary aerosols. Moreover, the result shows that these phenomena could be mainly influenced by meteorological factors covering the wide regions.

Fabrication of ZnS Powder by Glycothermal Method and Its Photocatalytic Properties (Glycothermal법에 의한 ZnS 분말 합성 및 광촉매 특성)

  • Park, Sang-Jun;Lim, Dae-Young;Song, Jeong-Hwan
    • Korean Journal of Materials Research
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    • v.27 no.9
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    • pp.489-494
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    • 2017
  • ZnS powder was synthesized using a relatively facile and convenient glycothermal method at various reaction temperatures. ZnS was successfully synthesized at temperatures as low as $125^{\circ}C$ using zinc acetate and thiourea as raw materials, and diethylene glycol as the solvent. No mineralizers or precipitation processes were used in the fabrication, which suggests that the spherical ZnS powders were directly prepared in the glycothermal method. The phase composition, morphology, and optical properties of the prepared ZnS powders were characterized using XRD, FE-SEM, and UV-vis measurements. The prepared ZnS powders had a zinc blende structure and showed average primary particles with diameters of approximately 20~30 nm, calculated from the XRD peak width. All of the powders consisted of aggregated secondary powders with spherical morphology and a size of approximately $0.1{\sim}0.5{\mu}m$; these powders contained many small primary nanopowders. The as-prepared ZnS exhibited strong photo absorption in the UV region, and a red-shift in the optical absorption spectra due to the improvement in powder size and crystallinity with increasing reaction temperature. The effects of the reaction temperature on the photocatalytic properties of the ZnS powders were investigated. The photocatalytic properties of the as-synthesized ZnS powders were evaluated according to the removal degree of methyl orange (MO) under UV irradiation (${\lambda}=365nm$). It was found that the ZnS powder prepared at above $175^{\circ}C$ exhibited the highest photocatalytic degradation, with nearly 95 % of MO decomposed through the mediation of photo-generated hydroxyl radicals after irradiation for 60 min. These results suggest that the ZnS powders could potentially be applicable as photocatalysts for the efficient degradation of organic pollutants.

Alternatives for The Stable Operation of Wastewater Treatment Plant in Combined Sewer System during Wet Weather (합류식 하수관거 지역에서 강우시 하수처리장 적정운영방안에 관한 연구)

  • Lee, Doo-jin;Shin, Eung-Bai;Hong, Chul-ui;Ahn, Se-young
    • Journal of Korean Society on Water Environment
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    • v.20 no.2
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    • pp.132-144
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    • 2004
  • The purpose of this study was to evaluate alternatives for stable operation of WWTP(Wastewater Treatment Plant) with a higher rate of inflows and a higher concentration of pollutants during wet weather to minimize the pollution loads being discharged into receiving waters. 3Q(Q: dry weather flow) of a base flow is normally intercepted and flows into WWTP as it was current practice. It is revealed by simulation that the bypassing alternative of 1Q through secondary treatment and 2Q into the stream after primary treatment was as good as it is expected. The bypass pollution loads were in the range of 23.9 ~ 38.5 % of the total loads flowing into the WWTP indicating that the bypassed flows need an extra treatment such as stormwater detention reservoir, high-rate coagulation with sedimentation, and step-feed. The high-rate coagulation with sedimentation was the most effective with respect to removal of the pollution loads.

Variations of Air Quality in Kunsan, Taegu, and Pohang due to the Characteristics of Local Weather (국지 기상 특성에 따른 군산, 대구 및 포항의 대기질의 일변화)

  • 서기수;윤일희
    • Journal of Environmental Science International
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    • v.6 no.6
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    • pp.613-628
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    • 1997
  • Diurnal variations of air quality due to the characteristic features of local weather phenomena over Kunsan, Taegu, and Pohang are analyzed using various synoptic wand fields and the characteristics of local weather during the period of 1990 to 1992. The air pollutants analyzed are sulfur dioxide($SO2_$), nitrogen dioxide($NO_2$), and oxidants ($0_3$). The synoptic wind fields estimated at over the 850 hPa geopotential height are divided in terms of four wand directions and two wand speed categories for each season. The synoptic weather conditions are also classified Into two categories depending on the 850 hPa cloud amounts. The present study shows that the $SO_2$ concentration over Kunsan, and Taegu was maximum at the two or three hours after sunrise and second primary was three or flour hours after sunset. On the other hand, Its concentration over Kunsan was malnmum at 1900 LST or 2000 LST The $O_3$ concentration over the three cities shows Its mapdmum In the afternoon when the solar radiation is strong. The $NO_2$ concentration over Kansan shows in reverse proportion to the $O_3$ concentration over the Kunsan.

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Greenbelt Systems Play an Important Role in the Prevention of Landscape Degradation Due to Urbanization

  • Cho, Yong-Chan;Cho, Hyun-Je;Lee, Chang-Seok
    • Journal of Ecology and Environment
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    • v.32 no.3
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    • pp.207-215
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    • 2009
  • Greenbelts were designated by the Korean government in 1971 in 14 large cities to prevent uncontrolled urban expansion. Recently, deregulation of the greenbelt system has resulted in further development, but the ecological role of greenbelts has not been fully considered when decisions about urban management are being made. We examined the ecological roles of the greenbelt system in the Seoul metropolitan area and prepared sustainable management and improvement plans based on our analysis of landscape characteristics using satellite images covering a ${\sim}30$-year period. The loss of forest cover during this period in the greenbelt areas was lower than that in the areas outside and inside of the greenbelt. Fragmentation of forest cover was correlated with the pattern of loss of forest cover. The NDVI of the greenbelt remained steady at 90% of that in outside of the GB for three decades. This suggests that the greenbelt system has performed its primary roles well. However, the remaining green space was not adequate to provide a sink for air pollutants even when the greenbelt area was included. We discuss how the negative effects of urbanization can be reduced through sustainable management and restoration to promote ecological functioning in greenbelts and urban landscapes.

Selection of coagulant using jar test and analytic hierarchy process: A case study of Mazandaran textile wastewater

  • Asadollahfardi, Gholamreza;Zangooei, Hossein;Motamedi, Vahid;Davoodi, Mostafa
    • Advances in environmental research
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    • v.7 no.1
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    • pp.1-11
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    • 2018
  • Textile factories are one of the industries which its wastewater treatment is a challenging issue, especially in developing countries and a conventional treatment cannot treat all its pollutants properly. Using chemical coagulants is a technique for physical and chemical primary treatment of the wastewater. We applied jar test for selection of suitable coagulant among the five coagulants including alum, calcium hydroxide, ferrous sulfate, ferrous chloride and barium chloride for the effluent of wastewater in Mazandran textile factory located in Mazandran Province, Iran. In addition, jar test, we also used analytic hierarchy process (AHP) method considering criteria which included coagulation cost, sensitivity to pH change, the amount of sludge generation and side effects for coagulation. The results of the jar test indicated that calcium hydroxide was proper among the coagulants which it removed 92.9% total suspended solid (TSS), 70% dye and 30% chemical oxygen demand. The AHP analysis presented that calcium hydroxide is more suitable than other coagulants considering five criteria.

Impacts of Asian Dust on Atmospheric Environment (황사의 대기환경영향)

  • Ghim, Young-Sung
    • Journal of Korean Society for Atmospheric Environment
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    • v.27 no.3
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    • pp.255-271
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    • 2011
  • ACE-Asia (Asian Pacific Regional Aerosol Characterization Experiment) in spring 2001 was a turning point to trigger international research interest on Asian dust (AD). This basically arose from the lack of research on AD, the important natural phenomenon to characterize the Northeast Asia. In contrast, health risk related to AD has been the primary concern in Korea. Although due in part to severe AD events of 2001~2002, research and mitigation measures on AD in Korea are typically based on the assumption that AD events are increasing in frequency and severity. However, contrary to the trend in Korea, the number of AD days and emission amounts of AD in China have decreased since 1980s. This paper reviews the impacts of AD on ambient air quality and variations in toxic substances during the AD event, reflecting the concern in Korea. While a great amount of dust particles flow into Korea during the AD event, a considerable amount of dust particles are locally generated as well. Since dust particles are mixed with toxic substances as they pass over polluted areas, the levels of toxic substances become lower in dust particles that do not pass over polluted areas. Broadening the research scope on AD is warranted to understand the AD as an important natural phenomenon, irrespective of its associated health risk.

The Development of VOC Measurement System Uging PCA & ANN (PCA와 ANN을 이용한 VOC 측정기기 개발)

  • Lee Jang-Hoon;Kwon Hyuk-Ku;Park Seung Ho;Kim Dong-Jin;Hong Chol-Ho
    • Environmental Analysis Health and Toxicology
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    • v.19 no.2
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    • pp.161-167
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    • 2004
  • Air quality monitoring is a primary activity for industrial and social environment. The government identifies the pollutants that each industry must monitor. Especially, the VOCs (Volatile Organic Compounds), which are very harmful to human body and environment atmosphere, should be controlled under the government policy. However, the VOCs, which have not been confirmed in emission sources are very difficult to monitor. It is needed to develop the monitoring system that allow the continuous and in situ measurement of VOCs mixture in different environmental matrices. Gas chromatography and mass spectrometry are the most prevalent current techniques among those available for the analysis of VOCs. But, they need a large size analytical instrument, which costs a great deal for purchase and operation. In addition, it has some limitations for realtime environmental monitoring such as location problems and slow processing time. Recently, several companies have commercialized a portable VOCs measurement systems, which cannot classify various kinds of VOCs but total quantities. We have developed a VOCs measurement system, which recognizes various kinds and quantities of VOCs, such as benzene, toluene, and xylene (BTX). Also, it can be used as a stand- alone type and/or fixed type in the vehicle with rack for real -time environmental monitoring.

Atmospheric Photochemistry in Low-and High-NOx Regimes

  • Kim, Do-Yong;Soda, Satoshi;Kendo, Akira;Oh, Jai-Ho
    • Journal of Environmental Science International
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    • v.16 no.1
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    • pp.1-8
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    • 2007
  • Atmospheric photochemistry of $O_3-NOx-RH$ were considered theoretically, to clarify the reasons for the different trends of between the formation of photochemical oxidants (Ox) and its primary pollutants for the Low-and High-NOx regimes. Equations of OH, $HO_2$, and production of ozone ($O_3$) as a function of nitrogen oxides (NOx) and reactive hydrocarbons (RH) were represented in this study. For the Low-NOx regime, $HO_2$ radical is proportional to RH but independent of NOx. OH radical is proportional to NOx but inversely-proportional to RH. $O_3$ production is proportional to NOx but has a weak dependence on RH. For the High-NOx regime, OH and $HO_2$ radicals concentrations and $O_3$ production are proportional to RH but inversely-proportional to NOx. In addition, the Osaka Bay and surrounding areas of Japan were evaluated with the mass balance of odd-hydrogen radicals (Odd-H) using CBM-IV photochemical mechanism, in order to distinguish the Low- and High-NOx regimes. The Harima area (emission ratio, RH/NOx = 6.1) was classified to the Low-NOx regime. The Hanshin area (RH/NOx = 3.5) and Osaka area (RH/NOx = 4.3) were classified to the High-NOx regime.

Application of Discrete Wavelet Transform for Detection of Long- and Short-Term Components in Real-Time TOC Data (실시간 TOC 자료의 장.단기 성분의 검출을 위한 이산형 웨이블렛 변환의 적용)

  • Jin, Young-Hoon;Park, Sung-Chun
    • Journal of Environmental Science International
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    • v.15 no.9
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    • pp.865-870
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    • 2006
  • Recently, Total Organic Carbon (TOC) which can be measured instantly can be used as an organic pollutant index instead of BOD or COD due to the diversity of pollutants and non-degradable problem. The primary purpose of the present study is to reveal the properties of time series data for TOC which have been measured by real-time monitoring in Juam Lake and, in particularly, to understand the long- and short-term characteristics with the extraction of the respective components based on the different return periods. For the purpose, we proposed Discrete Wavelet Transform (DWT) as the methodology. The results from the DWT showed that the different components according to the respective periodicities could be extracted from the time series data for TOC and the variation of each component with respect to time could emerge from the return periods and the respective energy ratios of the decomposed components against the raw data.