• Title/Summary/Keyword: Primary aluminum

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An Environmental Evaluation of Copper and Aluminum Metal Resources Circulation by Life Cycle Assessment (LCA기법을 적용한 구리 및 알루미늄 금속자원 순환의 환경성 평가)

  • Shin, Woochul;Hwang, Yongwoo;Moon, Jinyoung;Kong, Chanhwi
    • Journal of Korean Society of Environmental Engineers
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    • v.36 no.2
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    • pp.139-146
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    • 2014
  • In this research, we quantified the environmental load while using and not using secondary resources. During the process of primary processed product of metal resources (copper, aluminum), we applied LCA technique and analyzed by dividing into 8 environmental impact categories that affect the environment. Furthermore, we analyzed the greenhouse gas that occur during the process of primary processed product domestically and globally according to the changes of each metal resource's recycling rate. Consequently, when producing 1 ton of copper using secondary resources, the environmental effects were found to be 6.09E + 01 person-yr/f.u. and 7.23E + 01 person-yr/f.u. Additionally, as the recycling rate increased both globally and domestically, the amount of greenhouse gas decreased. Producing 1 ton of Aluminum using secondary resources, the environmental effects were found to be 2.34E + 02 person-yr/f.u. and 3.01E + 02 person-yr/f.u. Moreover, as the recycling rate domestically decreased, the amount of greenhouse gas increased, however the globally was decreased.

Development of standard gas mixtures of hydrocarbons in methane contained in aluminum cylinders (알루미늄 실린더에서 혼합 탄화수소(C6-C10) 표준가스 개발)

  • Kim, Yong-Doo;Bae, Hyun-Kil;Woo, Jin-Chun;Lee, Sangil;Oh, Sang-Hyub;Lee, Jin Hong
    • Analytical Science and Technology
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    • v.30 no.5
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    • pp.287-294
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    • 2017
  • As the demand for natural gas increases with industrial development, the supply of natural gas is expected to become unstable with a shortage of imported natural gas. It is hence necessary to meet this demand by introducing and developing various types of natural gas, such as pipeline natural gas (PNG) and substituted natural gas (SNG), in addition to liquefied natural gas (LNG). The components included in PNG as well as their concentrations must be measured accurately, and a standard gas should be developed to accurately measure hydrocarbons ($C_6-C_{10}$), which are trace components included in natural gas. The components in the primary standard gas mixtures (PSMs) developed in the present study were hexane, heptane, octane, nonane, and decane with concentrations of $10-30{\mu}mol/mol$ with methane as the balance gas. Standard hydrocarbon ($C_6-C_{10}$) gas mixtures were prepared in aluminum cylinders by a gravimetric method with traceability following ISO 6142 with raw material gases, for which the purity of each component was analyzed completely. The prepared standard gas mixtures were analyzed by to evaluate the preparation consistency between the standard gas mixtures, the adsorbability of the cylinders, the variation of the stability, and the uncertainty. The results showed that aluminum cylinders have little adsorptive loss on their internal surfaces with excellent long-term stability. The developed standard gas mixture, containing hexane, heptane, octane, nonane, and decane with concentrations of $10-30{\mu}mol/mol$, showed an uncertainty in a range of 0.79 % - 1.63 %.

A Study on the Lightweight Design of Hybrid Modular Carbody Structures Made of Sandwich Composites and Aluminum Extrusions Using Optimum Analysis Method (최적화 해석기법을 이용한 샌드위치 복합재와 알루미늄 압출재 하이브리드 모듈화 차체구조물의 경량 설계 연구)

  • Jang, Hyung-Jin;Shin, Kwang-Bok;Han, Sung-Ho
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.36 no.11
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    • pp.1335-1343
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    • 2012
  • In this study, the lightweight modular design of hybrid railway carbody structures made of sandwich composites and aluminum extrusions was investigated by using topology and size optimization techniques. The topology optimum design was used to select the best material for parts of the carbody structure at the initial design stage, and then, the size optimum design was used to find the optimal design parameters of hybrid carbody structures using first-order and sub-problem methods. Through the topology optimization analysis, it was found that aluminum extrusions were suitable for primary members such as the underframe and lower side panel module to improve the stiffness and manufacturability of the carbody structures, and sandwich composites were appropriate for secondary members such as the roof and middle side panel module to minimize its weight. Furthermore, the results obtained by size optimization analysis showed that the weight of hybrid carbody structures composed of aluminum extrusions and sandwich composites could be reduced by a maximum of approximately 17.7% in comparison with carbody structures made of only sandwich composites.

Characteristics in Microstructure of Particle Reinforced Al Matrix Composites Fabricated by Spray-Cast Forming Process (분사주조한 입자강화 알루미늄 복합재료의 미세조직 특성)

  • Park, Chong-Sung;Lee, In-Woo;Kim, Myung-Ho
    • Journal of Korea Foundry Society
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    • v.14 no.6
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    • pp.530-540
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    • 1994
  • Aluminium-silicon alloy(JIS AC8A) matrix composites reinforced with SiC particles were fabricated by spray-cast forming process, and the microstructure of powders and preforms produced were studied by using an optical and scanning electron microscopy. SiC particles were co-sprayed by mixed phase injection method during the spray casting process. Most of the composite powders formed by this mixed phase injection method exhibit morphology of particle-embedded type, and some exhibits the morphology of particle attached type due to additional attachment of the SiC particles on the surface of the powders in flight. The preforms deposited were resulted in dispersed type microstructure. The pre-solidified droplets and the deposited preform of SiC-reinforced aluminium alloy exhibit finer equiaxed grain size than that of unreinforced aluminium alloy. Eutectic silicons of granular type are crystallized at the corner of the aluminum grains in the preforms deposited, and some SiC particles seem to act as nucleation sites for primary/eutectic silicon during solidification. Such primary/eutectic silicons seem to retard grain growth during the continued spray casting process. It is envisaged from the microstructural observations for the deposited preform that the resultant distribution of SiC injected particles in the Al-Si microsturcture is affected by the amount of liquid phase in the top part of the preform and by the solidification rate of the preform deposited.

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Mechanical Behavior of A356 depending on the Variation of Microstructure (A356 합금 미세조직변화에 따른 기계적 특성에 관한 연구)

  • Kim K. J.;Kwon Y. N.;Lee Y. S.;Lee J. H.;Lee S. H.;Lee J. H.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2004.05a
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    • pp.273-276
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    • 2004
  • A356 alloy is one of the most popular casting aluminum alloys due to its good castability. It is well known that the mechanical properties of A356 alloy strongly depend on its characteristic microstructure, such as the size of eutectic Si, primary $\alpha$ dendrite and so on. These microstructural features are determined during the casting and solidification process, which implies the strong relationship with mechanical properties with solidification methods. In the present study, the mechanical characteristics of A356 alloy was investigated by using squeeze cast control arm in terms of the microstructural features, such as the size of eutectic Si, primary a dendrite. By doing so, the most favorable microstructure of A356 could be determined for Al control arm that should be one of the most reliable parts in automobile.

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A Study on the Fine Particle Dispensing Conditions for a Spiral Surface of Round Aluminum Bars (알루미늄 환봉의 나선형 표면 미세입자 분사가공의 조건에 대한 연구)

  • Choi, Sung-Yun;Lee, Eun-Ju;Lee, Sea-Han;Kwon, Dae-Gyu
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.19 no.8
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    • pp.88-93
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    • 2020
  • The goal of this study is to determine the influence of major factors on the spiral surface microparticle injection machining of cylindrical specimens by the statistical method ANOVA. Before the experiment, rod-shaped test specimens and jigs for helical surface spraying were prepared, and the surface roughness was measured with a surface roughness meter. The injection particle, nozzle diameter, and injection pressure were the primary parameters of the experiment. Other factors that were considered were injection height, injection time, revolutions, and feed distance. The surface roughness after machining was measured, and the effects of the surface roughness data on the primary factors were determined with ANOVA.

Effect of Particle Loading Ratio and Orifice Exit Velocity on a Particle-Laden Jet

  • Paik, Kyong-Yup;Yoon, Jung-Soo;Hwang, Jeong-Jae;Chung, Jae-Mook;Bouvet, Nicolas;Yoon, Young-Bin
    • International Journal of Aeronautical and Space Sciences
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    • v.12 no.3
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    • pp.296-304
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    • 2011
  • In order to design a shear coaxial injector of solid particles with water, basic experiments on a particle laden jet are necessary. The purpose of the present study is to understand the effect of particle loading ratio on the particle spray characteristics (i.e. spreading angle, distribution of particle number density, velocity profiles, and particle developing region length). Hydro-reactive Al2O3 particles with a primary particle diameter of 35~50 ${\mu}m$ are used in this experiment. An automated particle feeder was designed to supply constant particle mass flowrates. Air is used as the carrier gas. To determine the air velocity at the orifice exit, tracers (aluminum oxide, 0.5~2 ${\mu}m$ primary diameter) are also supplied by a tracer feeder. A plain orifice type injector with 3 mm diameter, and 20 mm length was adopted. Particle image velocimetry is used to measure the mean and fluctuating velocity components along the axial and radial directions.

Measures to improve water quality of Lake Euiam by controlling the incoming pollutants to the lake (의암호에 유입되는 오염물질 관리를 통한 호소 수질개선 방안)

  • Hwang, Hwan-Min;Yi, Geon-Ho;Kim, Mi-Yeon;Kim, Dong-Jin;Kim, Yeong-Kwan
    • Journal of Korean Society of Water and Wastewater
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    • v.25 no.5
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    • pp.783-790
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    • 2011
  • The purpose of this study was to suggest the alternative measures to properly manage the water quality of Lake Euiam, Chuncheon. Current pollution level of Gongji stream (influent to Lake Euiam) and sources of contamination in Lake Euiam were investigated. Particle size, organic matter and nutrient contents, heavy metals were analyzed for sediment samples taken from lower region of Gongji stream. Average organic matter content of nine sediment samples was 5.7%, and for nitrogen and phosphorus it was 750 mg/kg and 977mg/kg, respectively. Heavy metals including aluminum, iron, manganese and zinc were measured, whereas Cd and As were not detected. Effluent from Chuncheon Wastewater Treatment Plant appeared to be one of the main cause of organic matter and nutrients level in Lake Euiam. Inhibition of primary production and consequent reduction of organic matter content within the Lake should be a key measure to protect the water quality of Lake Euiam. Preventive measures to reduce the level of nutrients in wastewater treatment effluent were found necessary.

The Preparation of Blue CoAl2O4 Powders by the Malonate Method: The Effect of the Amount of Malonic Acid Used, the Formation Pathway of CoAl2O4 Crystallites and the Characteristics of the Prepared Powders

  • Lee, Gong-Yeol;Ryu, Kwang-Hyun;Kim, Hong-Gun;Kim, Yoo-Young
    • Bulletin of the Korean Chemical Society
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    • v.30 no.2
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    • pp.373-377
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    • 2009
  • A pathway for the formation of normal $CoAl_2O_4$ particles is suggested. The optimal amount of malonic acid was determined, and the characteristics of the obtained powders were investigated. Normal $CoAl_2O_4$ powders were prepared using solutions of malonic acid and metal nitrates. X-ray diffraction, Brunauer-Emmett-Teller (BET) and scanning electron microscope (SEM) measurements, as well as Fourier transform infrared (FTIR) and ultraviolet/visible (UV-Vis) spectroscopy were carried out. Normal $CoAl_2O_4$ crystallites were formed by a solid state reaction between $CoAl_2O_4$ and amorphous aluminum oxide. The optimal molar ratio of malonic acid to the nitrate anions present in the initial solution was found to be 0.30~0.35. The particles were composed of agglomerates of primary particles. The primary particles were 40 nm in size. This size was relatively constant regardless of the preparation temperature. However, the size of the agglomerated particles increased to 220 nm with increasing temperature.

Reaction of Lithium Gallium Hydride with Selected Organic Compounds Containing Representative Functional Groups

  • Choe, Jeong Hun;Yun, Mun Yeong;Yun, Jong Hun;Jeong, Dong Won
    • Bulletin of the Korean Chemical Society
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    • v.16 no.5
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    • pp.416-421
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    • 1995
  • The approximate rates and stoichiometry of the reaction of excess lithium gallium hydride with selected organic compounds containing representative functional groups were examined under the standard conditions (diethyl ether, 0 $^{\circ}C)$ in order to compare its reducing characteristics with lithium aluminum hydride and lithium borohydride previously reported, and enlarge the scope of its applicability as a reducing agent. Alcohols, phenol, and amines evolve hydrogen rapidly and quantitatively. However lithium gallium hydride reacts with only one active hydrogen of primary amine. Aldehydes and ketones of diverse structure are rapidly reduced to the corresponding alcohols. Conjugated aldehyde and ketone such as cinnamaldehyde and methyl vinyl ketone are rapidly reduced to the corresponding saturated alcohols. p-Benzoquinone is mainly reduces to hydroquinone. Caproic acid and benzoic acid liberate hydrogen rapidly and quantitatively, but reduction proceeds slowly. The acid chlorides and esters tested are all rapidly reduced to the corresponding alcohols. Alkyl halides and epoxides are reduced rapidly with an uptake of 1 equiv of hydride. Styrene oxide is reduced to give 1-phenylethanol quantitatively. Primary amides are reduced slowly. Benzonitrile consumes 2.0 equiv of hydride rapidly, whereas capronitrile is reduced slowly. Nitro compounds consumed 2.9 equiv of hydride, of which 1.9 equiv is for reduction, whereas azobenzene, and azoxybenzene are inert toward this reagent. Cyclohexanone oxime is reduced consuming 2.0 equiv of hydride for reduction at a moderate rate. Pyridine is inert toward this reagent. Disulfides and sulfoxides are reduced slowly, whereas sulfide, sulfone, and sulfonate are inert under these reaction conditions. Sulfonic acid evolves 1 equiv of hydrogen instantly, but reduction is not proceeded.