• Title/Summary/Keyword: Pretreatment effect

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CHARACTERISTICS OF PLATED GOLD LAYER ON ANSI 304 STAINLESS STEEL ACCORDING TO THE VARIATION OF PRETREATMENTS AND ELECTROLYSIS CONDITIONS

  • Lee, Dong-hun;Lee, Jae-Bong
    • Journal of the Korean institute of surface engineering
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    • v.32 no.3
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    • pp.224-234
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    • 1999
  • An attempt was made to characterize the relationship between pretreatment processes, electrolysis conditions and behaviors of the plated gold layer. In order to investigate the effect of pretreatment processes on plating, rest potential measurements of various pretreated stainless steels and a.c.-impedance spectroscopy tests were carried out in the strike plating solution. Characteristics of plated gold layers and adhesions between plated gold layers and stainless steel substrates were examined by scratching tests and micro-Vickers hardness tests. The result shows that the strike plating enhanced the adhesion of interface, the cathodic electro-activation pretreatment process improving both corrosion resistance and adhesion strength. The preferred orientations of plated gold layers were examined by the X-ray diffraction technique. As the current density increases, [111] preferred orientation of plated gold layers was found to become well developed.

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Study for Related Mechanism of Anti-Inflammatory Effect Induced by Neddle electrode electrical stimulation in Mouse Air Pouch Model. (Mouse Air Pouch Model에서 침전극 저주파치료로 유도된 소염 작용에 관한 연구)

  • Chung, Jin-Woo;Hwang, Hyun-Sook;Lim, Jong-Soo
    • Journal of Korean Physical Therapy Science
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    • v.9 no.2
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    • pp.111-122
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    • 2002
  • In oriental medicine, manual-acupuncture and electroacupuncture (EA) have been widely utilized to cure several inflammatory diseases such as arthritis. We designed this experiment to find neurochemical mechanism related to electroacupuncture induced anti-inflammatory effect on mouse air pouch model. EA with both low frequency (1 Hz) and high frequency (120 Hz) was treated after induction of inflammation in air pouch using injection of zymosan. To verify the role of opioid system in electroacupuncture-induced anti-inflammatory effect, naloxone (10 mg/kg) was pretreated. In addition, idazoxan (5 mg/kg) was pre-treated to evaluate the possible effect of endogenous adrenergic system in autonomic system on EA induced anti-inflammatory effect. As results of this study, naloxone pretreatment did not change the anti-inflammatory effect evoked by high frequency EA, while low frequency EA(1 Hz) induced anti-inflammatory effect was dramatically suppressed by naloxone pretreatment. These data indicated that endogenous opioid system might be extensively involve in anti-inflammatory effect evoked by not high frequency, but low frequency EA. However, idazoxan pretreatment did not produce any modulatory effect on both low and high frequency EA induced anti-inflammatory effect, suggesting that EA induced anti-inflammatory effect was not mediated by endogenous adrenergic system. In conclusion, these data strongly suggested that EA induced anti-inflammatory effect is mediated by endogenous opioid system, not endogenous adrenergic system.

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The Effect of Pyrogallol on the Pharmacological Action of Ephedrine and Epinephrine (Ephedrine 및 Epinephrine 의 작용(作用)에 미치는 Pyrogallol 의 영향(影響))

  • Lim, Zoo-Taek
    • The Korean Journal of Pharmacology
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    • v.4 no.1 s.5
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    • pp.41-44
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    • 1968
  • Pyrogallol is recently known to be a inhibitor of catechol-o-methyl transferase (COMT) and increase the action of epinephrine on the isolated rabbit atria. In this experiment, the author attempated to investigate the influence of pyrogallol on the effect of ephedrine and epinephrine on the blood pressure of the rabbit and isolated atria and excised intestine of the rabbit. The results obtained were summarized as follows; 1. Pyrogallol tends to increase the blood pressure and respiration of the rabbit. But it has no significant effect on the excised rabbit atria and intestine. 2. The effect of ephedrine on the blood pressure and respiration, isolated atria and excised intestine of the rabbit were not influenced by the pretreatment with pyrogallol. 3. The effect of epinephrine on the blood pressure and isolated atria of the rabbit is potentiated with pyrogallol pretreatment.

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Ionic Liquid Pretreatment of Lignocellulosic Biomass

  • Han, Song-Yi;Park, Chan-Woo;Kwon, Gu-Joong;Kim, Nam-Hun;Kim, Jin-Chul;Lee, Seung-Hwan
    • Journal of Forest and Environmental Science
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    • v.36 no.2
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    • pp.69-77
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    • 2020
  • Lignocellulosic biomass has recalcitrant characteristics against chemical and biological conversion due to its structural heterogeneity and complexity. The pretreatment process to overcome these recalcitrant properties is essential, especially for the biochemical conversion of lignocellulosic biomass. In recent years, pretreatment methods using ionic liquids (ILs) and deep eutectic solvents (DESs) as the green solvent has attracted great attention because of their advantages such as easy recovery, chemical stability, temperature stability, nonflammability, low vapor pressure, and wide liquids range. However, there are some limitations such as high viscosity, poor economical feasibility, etc. to be solved for practical use. This paper reviewed the research activities on the pretreatment effect of various ILs including DESs and their co-solvents with organic solvents on the enzymatic saccharification efficiency of lignocellulosic biomass and the nanocellulose preparation from the pretreated products.

Effect of Malonic Acid-Catalyzed Pretreatment on the Hydrolysis of Gracilaria verrucosa (Malonic acid를 이용한 전처리가 꼬시레기의 가수분해에 미치는 영향)

  • Park, Mi-Ra;Jeong, Gwi-Taek
    • Korean Chemical Engineering Research
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    • v.56 no.4
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    • pp.542-546
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    • 2018
  • In this study, the effects of malonic acid-catalyzed pretreatment on the subsequent enzymatic hydrolysis of red macro-algae Gracilaria verrucosa for production of biosugar (total reducing sugar) were investigated. In the hydrothermal pretreatment condition of 300 mM malonic acid, 1:20 solid-to-liquid ratio at $130^{\circ}C$ for 60 min, a 49.2% biosugar yield was achieved. Moreover, by subsequent enzymatic hydrolysis after pretreatment, maximum yield of 64.5% was achieved.

Pretreatment of Wastepaper using Aqueous Glycerol under High Pressure to Enhance Enzymatic Hydrolysis (효소 가수분해 향상을 위해 고압조건에서 Glycerol 수용액을 사용한 폐지의 전처리)

  • Seo, Dong Il;Kim, Chang-Joon;Kim, Sung Bae
    • KSBB Journal
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    • v.29 no.3
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    • pp.193-198
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    • 2014
  • Pretreatment of wastepaper using aqueous glycerol under high pressure was studied to enhance the enzymatic hydrolysis. The pretreatment was conducted over a wide range of conditions including temperatures of $150{\sim}170^{\circ}C$, sulfuric acid concentrations of 0.5~1.5%, and reaction times of 30~90 minutes. After the effect of glycerol concentration on the pretreatment performance was investigated, 70% glycerol was selected. As glycerol concentration was increased, higher digestibility was achieved due to higher lignin removal. The optimum condition was found to be around $160^{\circ}C$, 1%, and 60 minutes. At this condition, 60% and 35% of hemicellulose and lignin, respectively, were removed, while only 5% of cellulose was lost. The enzymatic digestibility was 76%, meaning that 73% of the glucan present in the initial substrate was recovered as glucose after enzymatic hydrolysis. Also, it was found that the temperature and acid concentration than the reaction time were more strongly related to the compositional removals and enzymatic digestibility.

Wet Air Oxidation Pretreatment of Mixed Lignocellulosic Biomass to Enhance Enzymatic Convertibility

  • Sharma, A.;Ghosh, A.;Pandey, R.A.;Mudliar, S.N.
    • Korean Chemical Engineering Research
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    • v.53 no.2
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    • pp.216-223
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    • 2015
  • The present work explores the potential of wet air oxidation (WAO) for pretreatment of mixed lignocellulosic biomass to enhance enzymatic convertibility. Rice husk and wheat straw mixture (1:1 mass ratio) was used as a model mixed lignocellulosic biomass. Post-WAO treatment, cellulose recovery in the solid fraction was in the range of 86% to 99%, accompanied by a significant increase in enzymatic hydrolysis of cellulose present in the solid fraction. The highest enzymatic conversion efficiency, 63% (by weight), was achieved for the mixed biomass pretreated at $195^{\circ}C$, 5 bar, 10 minutes compared to only 19% in the untreated biomass. The pretreatment under the aforesaid condition also facilitated 52% lignin removal and 67% hemicellulose solubilization. A statistical design of experiments on WAO process conditions was conducted to understand the effect of process parameters on pretreatment, and the predicted responses were found to be in close agreement with the experimental data. Enzymatic hydrolysis experiments with WAO liquid fraction as diluent showed favorable results with sugar enhancement up to $10.4gL^{-1}$.

Hybrid salts precipitation-nanofiltration pretreatment of MSF and RO seawater desalination feed

  • Al-Rawajfeh, Aiman Eid
    • Membrane and Water Treatment
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    • v.3 no.4
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    • pp.253-266
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    • 2012
  • In this work, the effect of hybrid salts precipitation-nanofiltration (SP-NF) process on the scale deposits in thermal and membrane desalination processes has been studied. The analysis was carried out to study the scale formation from the Arabian Gulf seawater in MSF and RO reference processes by changing the percentage of pretreatment from 0 to 100%. Four different SP-NF configurations were suggested. A targeted Top Brine Temperature (TBT) of $130^{\circ}C$ may be achieved if 30% portion is pretreated by SP and/or NF processes. As a rule of thumb, each 1% pretreatment portion increases the reference TBT of $115^{\circ}C$ by $0.6^{\circ}C$. For both MSF and RO, parallel pretreatment of certain percentage of the feed by SP and the rest by NF, showed the lowest scale values. The case showed the best values for sulfate scale prevention and the highest values of increasing the monovalent ions relative to the divalent scale forming ions. Sulfate scale is significant in MSF process while carbonate scale is significant in RO. Salt precipitation was suggested because it is less costly than nanofiltration, but nanofiltration was used here because it is efficient in sulfate ions removal.

Preparation of Polyester Using Waste Ethylene Glycol Generated from the Wastepaper Pretreatment Process (Ethylene glycol을 사용한 폐지의 전처리공정에서 발생된 폐액으로부터 polyester 제조)

  • Lee, Dong-Hun;Kim, Chang-Joon;Kim, Sung-Bae
    • KSBB Journal
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    • v.27 no.1
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    • pp.51-56
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    • 2012
  • This research was to investigate the polyester preparation using waste ethylene glycol (EG) generated from the wastepaper pretreatment process. Waste EG was obtained from using EG five times repeatedly in the pretreatment of wastepaper. The hydroxyl value of the waste EG was 441 mg KOH/g and its composition was 0.68% cellulose, 6.5% hemicellulose, 6.1% lignin, and 86.7% EG. Maleic acid was used as carboxylic acid. The effect of reaction temperature and time except carboxyl group/hydroxyl group ratio on the crosslinkage of the prepared polyester was marginal. Citric acid, lithium hydroxide and dicumyl peroxide were used as additive or catalyst to enhance the crosslinkage of polyester. Among them, 10% of citric acid was found to be most effective. The crosslinkage was 86% when the polyester was prepared at an optimum condition such as $130^{\circ}C$ and 15 minutes, 1.5 of C/H ratio, and 10% of citric acid, and its insoluble percentage in boiling water for 6 hours was 47%. The weight loss of the prepared polyester was approximately 40% when it was buried in damp soil for 5 months, indicating that it is readily biodegradable. This results can provide some information for future development of wastepaper pretreatment by organic solvent.

Effect of Applying Pretreatment Methods before cooking for decreasing the Microbiological Hazard of Cooked Dried fish in Foodservice establishments (건어물을 이용한 조리음식의 미생물학적 위해 감소를 위한 조리 전처리 적용 효과)

  • 배현주;이재학;오세인
    • Korean journal of food and cookery science
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    • v.19 no.5
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    • pp.555-561
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    • 2003
  • The purpose of this study was to analyze the microbiological hazards of dried fish (Jwieochae, Ojingeochae and Bugeochae), and to apply pretreatment methods to increase the safety of cooked dried fish within foodservice establishments. Microbiological inspections were conducted on Total Plate Count, Coliforms, E. coli, E. coli O157:H7, Staphylococcus aureus, Salmonella spp. and Listeria monocytogenes. The study results are summarized as follows. According to the Hazard analysis, there are many problems showing high numbers in terms of Total Plate Count and Coliforms, which were both well over acceptable standard levels. E. coli and Staphylococcus aureus were detected at certain foodservice establishments, while E. coli O157:H7, Salmonella spp. and Listeria monocytogenes were not detected at all. By applying various pretreatment methods, such as washing, blanching, pan frying and microwave heating, the levels of microbiological hazards were able to be controlled and lowered. Blanching was the most effective method, followed by panfrying, microwave heating and washing. The Total Plate Counts gradually decreased with increasing number of times washed and seconds panfried. From these results, it is concluded that to guarantee food safety, cooked dried fish raw materials should be kept hygienically and appropriate pretreatment methods applied before cooking.