• Title/Summary/Keyword: Presence Agent

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Natural Dispersing Agent from Korean Seaweed Extract to Enhance the Safeness and UV Protection Properties of Inorganic Sunscreen Based on TiO2 Nanoparticles

  • Pestaria Sinaga;Sung-Hwan Bae
    • Korean Journal of Materials Research
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    • v.34 no.2
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    • pp.95-104
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    • 2024
  • Nanoparticles are commonly used to avoid the opaque white color of TiO2 based sunscreen. However, a dispersing agent is typically required because of the tendency of the nanoparticles (NPs) to agglomerate. Stearic acid is one kind of dispersing agent often used for sunscreen products. However, according to the MSDS data sheet on stearic acid, stearic acid is highly hazardous to aquatic life and causes irritation on human skin. To avoid this problem, in this study a safer organic dispersing agent extracted from Korean seaweed has been studied to disperse TiO2 nanoparticles, and further use as an active agent in sunscreen products. The presence of phytochemicals in seaweed extract, especially alginate, can disperse TiO2 nanoparticles and improve TiO2 dispersion properties. Results show that seaweed extract can improve the dispersion properties of TiO2 nanoparticles and sunscreen products. Reducing the agglomeration of TiO2 nanoparticles improves sunscreen properties, by making it less opaque white in color, and increasing UV protection value. It was also confirmed that adding seaweed extract into sunscreen products had no irritating effects on the human skin, making it more desirable for cosmetics application.

Antioxidant enzyme activities and intracellular reactive oxygen intermediate (ROI) levels of flavonol quercetin in the presence of taurine on Bl6F10 murine melanoma cells.

  • Sim, Hue-Jeong;Kim, An-Keun
    • Proceedings of the Korean Society of Applied Pharmacology
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    • 2003.11a
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    • pp.66-66
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    • 2003
  • Flavonoids are phenolic compounds widely distributed in wide variety of edible plants including leafy vegetables, fruits, beverages. Quercetin is one of bioflavonoid compounds and has anti-tumor effect by suppressing tumor growth in vitro and in vivo, including multiple biological effects by antioxidant and effective anti-inflammatory agent. The present study investigated whether quercetin can enhance antioxidant enzyme activities (glutathione peroxidase: GPX, superoxide dismutase : SOD, catalase: CAT) and intracellular reactive oxygen intermediate (ROI) levels in the presence of taurine on B16F10 murine melanoma cells. From this result, the antioxidant enzyme activities of quercetin in the presence of taurine was enhanced. In addition, the same treatments decreased intracellular reactive oxygen intermediate levels on B16F10 murine melanoma cells. Taken together, these results demonstrate that the antioxidant effect of quercetin can enhance in the presence of taurine and it might play an important role in anti-tumor effect.

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Reduction of Selected Carbonyl Compounds with 8-Oxyquinoline Dihydroboronite. Selective Reduction of Aldehydes in the Presence of Ketones

  • Kim, Sung-Gak;Yang, Sung-Bong;Kang, Ho-Jung
    • Bulletin of the Korean Chemical Society
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    • v.5 no.6
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    • pp.240-244
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    • 1984
  • 8-Oxyquinoline dihydroboronite is prepared by mixing equimolar amounts of 8-hydroxyquinoline and borane-dimethyl sulfide complex in tetrahydrofuran at room temperature and its structure is determined by spectroscopic methods. The reagent is shown to be an extremely mild reducing agent and reduces aldehydes, cyclohexanones, and acid chlorides to some extent. The reagent in the presence of 0.1 equiv of boron trifluoride etherate in tetrahydrofuran at room temperature reduces selectively aldehydes in the presence of ketones, while the reagent in the presence of 1 equiv of boron trifluoride etherate rapidly reduces simple aldehydes and ketones but does not reduce carboxylic acids, esters, and amides.

An Energy Efficient Distributed Approach-Based Agent Migration Scheme for Data Aggregation in Wireless Sensor Networks

  • Gupta, Govind P.;Misra, Manoj;Garg, Kumkum
    • Journal of Information Processing Systems
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    • v.11 no.1
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    • pp.148-164
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    • 2015
  • The use of mobile agents for collaborative processing in wireless sensor network has gained considerable attention. This is when mobile agents are used for data aggregation to exploit redundant and correlated data. The efficiency of agent-based data aggregation depends on the agent migration scheme. However, in general, most of the proposed schemes are centralized approach-based schemes where the sink node determines the migration paths for the agents before dispatching them in the sensor network. The main limitations with such schemes are that they need global network topology information for deriving the migration paths of the agents, which incurs additional communication overhead, since each node has a very limited communication range. In addition, a centralized approach does not provide fault tolerant and adaptive migration paths. In order to solve such problems, we have proposed a distributed approach-based scheme for determining the migration path of the agents where at each hop, the local information is used to decide the migration of the agents. In addition, we also propose a local repair mechanism for dealing with the faulty nodes. The simulation results show that the proposed scheme performs better than existing schemes in the presence of faulty nodes within the networks, and manages to report the aggregated data to the sink faster.

A Study on the Decomposition Characteristics of CFC-113 by Activated Carbon (활성탄 촉매를 이용한 CFC-113의 분해특성에 관한 연구)

  • 이우근;정주영;김진범
    • Journal of Korean Society for Atmospheric Environment
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    • v.13 no.4
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    • pp.319-325
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    • 1997
  • The catalytic decomposition of CFC-113(1,1,2-trichloro-1,2,2-trifluoroethane) was studied over an activated carbon catalyst in a fixed-bed reactor at the temperature from 300 to 600$^\circ$C, the space velocity (SV) of 1800 $\sim 14400h^{-1}$ and the mole ratio(decomposition agent/CFC-113) of 0.25 $\sim$ 5. In the absence of a decomposition agent, the decomposition efficiency of CFC-113 was low but when a decomposition agent was added to the gas stream, it was dramatically increased with the increase of temperature. In particular, in the presence of n-hexane as the decomposition agent it showed a high decomposition efficiency compared with benzene at 400$^\circ$C. It was found that the decomposition activity of CFC-113 was very sensitive to reaction temperature. Thus it is expected that to raise the reaction temperature is more effective than to increase the residence time and the amount of decomposition agent. Over the activated carbon catalyst more than 99% decomposition was achieved at the reaction temperature of 600$^\circ$C, SV of 7200$h^{-1}$, the mole ration $(C_6H_{14}/CFC-113)$ of 1 in this study.

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Effect of the Variation of Speccfic Gravity and the Addition of Water Repellent Agent on the Physical Properties of Autoclaved Lightweight Concrete (비중의 변화와 발수제 첨가가 경량기포콘크리트의 물성에 미치는 영향)

  • 노재성;황의환;홍성수;이범재
    • Magazine of the Korea Concrete Institute
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    • v.9 no.2
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    • pp.137-144
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    • 1997
  • The effcct of specific g~avity cont~olled In the .range fiom O.4 to 0.7 by particle size and added amount of A1 powder in the presence or absence of water repellent agent on the physical properties of ALC was examined to evaluate frost resistance and durability. The compressive sttcngth and the tensile strength are increased and independency with water repellent agent when the specific gravity is increased in the range from 0.4 to 0.7. According as the added amount of water repellent agent was increased. frost resistance was improved and absorption ratio was decreased. ALC produced from fine Al powder has a low volume reduction by scaling and a sound apperance after freezing/thawing test and top surface freezing test.

Effect of fiber-matrix adhesion on the fracture behavior of a carbon fiber reinforced thermoplastic-modified epoxy matrix

  • Carrillo-Escalante, H.J.;Alvarez-Castillo, A.;Valadez-Gonzalez, A.;Herrera-Franco, P. J.
    • Carbon letters
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    • v.19
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    • pp.47-56
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    • 2016
  • In this study, the fracture behavior of a thermoplastic-modified epoxy resin reinforced with continuous carbon fibers for two levels of fiber-matrix adhesion was performed. A carbon fiber with commercial sizing was used and also treated with a known silane, (3-glycidoxy propyl trimethoxysilane) coupling agent. Toughness was determined using the double cantilever test, together with surface analysis after failure using scanning electron microscope. The presence of polysulfone particles improved the fracture behavior of the composite, but fiber-matrix adhesion seemed to play a very important role in the performance of the composite material. There appeared to be a synergy between the matrix modifier and the fiber-matrix adhesion coupling agent.

Effect of $TiO_2$ Nanoparticle on the Mechanical and Thermal Properties of Epoxy Resin Composites (에폭시수지 복합재료의 기계적.열적 성질에 대한 $TiO_2$ 나노입자의 영향)

  • Moon, Y.J.;Choi, J.Y.;Kim, B.A.;Moon, C.K.
    • Journal of Power System Engineering
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    • v.14 no.4
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    • pp.68-75
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    • 2010
  • The effect of dispersion agent, the content and size of nanoparticle on the mechanical and thermal properties has been investigated in $TiO_2$ nanoparticle/epoxy resin composites(nanocomposites). The weight fraction of fabricated nanocomposites were 0, 1, 3, 5%, respectively. The glass transition temperature was lower than pure epoxy resin and decreased with the increasing of nanopaticle content. This is considered that the cross link of epoxy resin during solidification was hindered by the presence of nanoparticles. Nanocomposites of 3wt% content with dispersion agent showed the best tensile strength. The tensile strength of 20㎚ $TiO_2$ nanocomposites were higher than one of 200nm $TiO_2$ nanocomposites.

Method Development of Verapamil in Presence of NSAIDs using RP-HPLC Technique

  • Sultana, Najma;Arayne, M. Saeed;Waheed, Abdul
    • Bulletin of the Korean Chemical Society
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    • v.32 no.7
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    • pp.2274-2278
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    • 2011
  • Verapamil is a calcium channel blocker and is classified as a class IV anti-arrhythmic agent. It is used in the control of supra ventricular tachyarrhythmias, and in the management of classical and variant angina pectoris. It is also used in the treatment of hypertension and used as an important therapeutic agent for angina pectoris, ischemic heart disease, hypertension and hypertrophic cardiomyopathy. Verapamil commonly co-administered with NSAIDs (non-steroidal anti-inflammatory drugs) i.e. diclofenac sodium, flurbiprofen, Ibuprofen, mefanamic acid and meloxicam. A simple and rapid RP-HPLC method for simultaneous determination and quantification of verapamil and NSAIDs was developed and validated. The mobile phase constituted of acetonitrile: water (55:45) whose pH was adjusted at 2.7 and pumped at a flow rate of 2.0 mL $min^{-1}$ at 230 nm. The proposed method is simple, precise, accurate, low cost and least time consuming for the simultaneous determination of verapamil and NSAIDs which can be effectively applied for the analysis of human serum.

Drying shrinkage and Pore Structure of Blast Furnace Slag Concrete Mixed Alkaline Stimulation (알칼리 자극제 혼입 고로슬래그 콘크리트의 건조수축과 공극구조)

  • Park, Ji-Woong;Lee, Gun-Cheol;Gao, Shan
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2016.10a
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    • pp.32-33
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    • 2016
  • This purpose of this study is to find the properties of pore structure and length change of blast furnace slag cement added alkali powder stimulant on shrinkage reducing agent presence. In length change, the specimen added alkaline stimulant was smaller than normal blast furnace slag concrete. And the specimen added shrinkage reduction agent was confirmed to show smaller rate of length change than the length. In MIP analysis of 1day-age, 0.1㎛ subsequent pore amount of the specimen added alkaline stimulant was significantly smaller value the normal blast furnace slag concrete specimen.

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