• 제목/요약/키워드: Prediction mean squares error

검색결과 27건 처리시간 0.021초

A comparison of ATR-FTIR and Raman spectroscopy for the non-destructive examination of terpenoids in medicinal plants essential oils

  • Rahul Joshi;Sushma Kholiya;Himanshu Pandey;Ritu Joshi;Omia Emmanuel;Ameeta Tewari;Taehyun Kim;Byoung-Kwan Cho
    • 농업과학연구
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    • 제50권4호
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    • pp.675-696
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    • 2023
  • Terpenoids, also referred to as terpenes, are a large family of naturally occurring chemical compounds present in the essential oils extracted from medicinal plants. In this study, a nondestructive methodology was created by combining ATR-FT-IR (attenuated total reflectance-Fourier transform infrared), and Raman spectroscopy for the terpenoids assessment in medicinal plants essential oils from ten different geographical locations. Partial least squares regression (PLSR) and support vector regression (SVR) were used as machine learning methodologies. However, a deep learning based model called as one-dimensional convolutional neural network (1D CNN) were also developed for models comparison. With a correlation coefficient (R2) of 0.999 and a lowest RMSEP (root mean squared error of prediction) of 0.006% for the prediction datasets, the SVR model created for FT-IR spectral data outperformed both the PLSR and 1 D CNN models. On the other hand, for the classification of essential oils derived from plants collected from various geographical regions, the created SVM (support vector machine) classification model for Raman spectroscopic data obtained an overall classification accuracy of 0.997% which was superior than the FT-IR (0.986%) data. Based on the results we propose that FT-IR spectroscopy, when coupled with the SVR model, has a significant potential for the non-destructive identification of terpenoids in essential oils compared with destructive chemical analysis methods.

Melon Surface Color and Texture Analysis for Estimation of Soluble Solids Content and Firmness

  • Suh, Sang-Ryong;Lee, Kyeong-Hwan;Yu, Seung-Hwa;Shin, Hwa-Sun;Choi, Young-Soo;Yoo, Soo-Nam
    • Journal of Biosystems Engineering
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    • 제37권4호
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    • pp.252-257
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    • 2012
  • Purpose: The net rind pattern and color of melon surface are important for a high market value of melon fruits. The development of the net and color are closely related to the changes in shape, size, and maturing. Therefore, the net and color characteristics can be used indicators for assessment of melon quality. The goal of this study was to investigate the possibility of estimating melon soluble solids content (SSC) and firmness by analyzing the net and color characteristics of fruit surface. Methods: The true color images of melon surface obtained at fruit equator were analyzed with 18 color features and 9 texture features. The partial least squares (PLS) method was used to estimate SSC and firmness in melons using their color and texture features. Results: In sensing melon SSC, the coefficients of determination of validation (${R_v}^2$) of the prediction models using the color and texture features were 0.84 (root mean square error of validation, RMSEV: 1.92 $^{\circ}Brix$) and 0.96 (RMSEV: 0.60 $^{\circ}Brix$), respectively. The ${R_v}^2$ values of the models for predicting melon firmness using the color and texture features were 0.64 (RMSEV: 4.62 N) and 0.79 (RMSEV: 2.99 N), respectively. Conclusions: In general, the texture features were more useful for estimating melon internal quality than the color features. However, to strengthen the usefulness of the color and texture features of melon surface for estimation of melon quality, additional experiments with more fruit samples need to be conducted.

GLS와 Bass 모형을 결합한 하이브리드 모형을 이용한 영화 관객 수 예측 (Prediction of movie audience numbers using hybrid model combining GLS and Bass models)

  • 김보경;임창원
    • 응용통계연구
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    • 제31권4호
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    • pp.447-461
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    • 2018
  • 국내 영화 산업 매출은 매년 증가하고 있다. 극장은 영화의 1차 판매 경로이며, 극장을 이용하는 관객 수는 부가판권에 영향을 준다. 따라서 극장을 이용하는 관객의 수는 영화 산업 매출에 직결되는 중요한 요소이다. 본 논문에서 특정일의 관객 수를 예측하기 위하여 다중선형회귀모형과 Bass 모형을 결합한 Hybrid 모형을 고려한다. 두 모형을 결합함으로써 회귀분석의 예측값을 Bass 모형의 예측값으로 보정하였다. 분석에는 개봉일이 모두 다른 세 영화를 이용하였다. All subset regression 방법을 이용해 모든 가능한 조합을 생성하고 5중 교차검증(5-fold cross validation)을 통해 5번 모형을 추정한다. 이 때 제곱근평균오차가 가장 작은 모형으로 예측값을 구한 뒤 Bass 모형의 예측값과 결합해 최종 예측값을 구하게 된다. 과거데이터가 존재할수록 Bass 모형의 가중치는 증가하면서 예측값에 보정효과를 준다는 것을 확인할 수 있었다.

Application of Near Infrared Spectroscopy for Nondestructive Evaluation of Nitrogen Content in Ginseng

  • Lin, Gou-lin;Sohn, Mi-Ryeong;Kim, Eun-Ok;Kwon, Young-Kil;Cho, Rae-Kwang
    • 한국근적외분광분석학회:학술대회논문집
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    • 한국근적외분광분석학회 2001년도 NIR-2001
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    • pp.1528-1528
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    • 2001
  • Ginseng cultivated in different country or growing condition has generally different components such as saponin and protein, and it relates to efficacy and action. Protein content assumes by nitrogen content in ginseng radix. Nitrogen content could be determined by chemical analysis such as kjeldahl or extraction methods. However, these methods require long analysis time and result environmental pollution and sample damage. In this work we investigated possibility of non-destructive determination of nitrogen content in ginseng radix using near-infrared spectroscopy. Ginseng radix, root of Panax ginseng C. A. Meyer, was studied. Total 120 samples were used in this study and it was consisted of 6 sample sets, 4, 5 and 6-year-old Korea ginseng and 7, 8 and 9-year-old China ginseng, respectively. Each sample set has 20 sample. Nigrogen content was measured by electronic analysis. NIR reflectance spectra were collected over the 1100 to 2500 nm spectral region with a InfraAlyzer 500C (Bran+Luebbe, Germany) equipped with a halogen lapmp and PbS detector and data were collected every 2 nm data point intervals. The calibration models were carried out by multiple linear regression (MLR) and partial least squares (PLS) analysis using IDAS and SESAME software. Result of electronic analysis, Korean ginseng were different mean value in nitrogen content of China ginseng. Ginseng tend to generally decrease the nitrogen content according as cultivation year is over 6 years. The MLR calibration model with 8 wavelengths using IDAS software accurately predicted nitrogen contents with correlation coefficient (R) and standard error of prediction of 0.985 and 0.855%, respectively. In case of SESAME software, the MLR calibration with 9 wavelength was selected the best calibration, R and SEP were 0.972 and 0.596%, respectively. The PLSR calibration model result in 0.969 of R and 0.630 of RMSEP. This study shows the NIR spectroscopy could be applied to determine the nitrogen content in ginseng radix with high accuracy.

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Discrimination and Quantitative Analysis of Watercore in Apple Fruit by Near Infrared Transmittance Spectroscopy

  • Kim, Eun-Ok;Sohn, Mi-Ryeong;Kwon, Young-Kil;Lin, Gou-Lin;Cho, Rae-Kwang
    • 한국근적외분광분석학회:학술대회논문집
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    • 한국근적외분광분석학회 2001년도 NIR-2001
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    • pp.1529-1529
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    • 2001
  • The watercore in apple is very important factor in storage and sorting of fruit. Most consumers tend to prefer the apple included watercore in immediately after harvest, however the watercore causes fruit flesh to brown during storage and lose the worth after all. But it is practically impossible to judge to the naked eye whether an apple has watercore or not. Therefore, the rapid, accurate and non-destructive analysis method for discrimination of watercore should be settled without delay. In this study we attempted the discrimination and quantitative analysis of watercore in apple fruit using near-infrared transmittance spectroscopy ‘Fuji’ apple fruits produced in Kyungpook of Korea was used in this experiment. The watercore content in apple was evaluated by graphic treatment of culled slice sections(10 mm). NIR transmittance spectra were collected over the 500 to 1000 nm spectral region with a spectrometer (Sentronic Co., Germany). The calibration models were carried out by partial least squares (PLS) analysis between NIR spectra data of apples and chemical data of watercore content. The spectra were different in absorbance between apple included watercore and not included one. Apple included watercore had higher absorption band than sample not included one at 732 and 820 nm. The calibration model seems to be accurate to predict the watercore content in apple fruit, the correlation coefficient (R) and root mean square error of prediction (RMSEP) were 0.99 and 0.93%, respectively. This result indicates that the PLSR calibration model by using NIR transmittance spectroscopy could be used for discrimination of watercore in apple fruit.

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담수호 Multiple Box 수질모형의 개발과 적용 (Development and Application of Multiple Box Water Quality Model for Estuary Reservoirs)

  • 임종환;권순국
    • 한국농공학회지
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    • 제31권4호
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    • pp.111-122
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    • 1989
  • A multiple box model which is suitable for the prediction of water quality in shallow lakes with active mixing is a water quality model expected to be used widely in estuary reservoir. In this study, a multiple box water quality model for estuary reservoirs (MBQER) was developed arid the applicability of the MBQER was tested by applying data obtained from Asan-estuary reservoir. The results of this study can be summarized as follows. 1. The MBQER, dynamic water quality model, was developed to estimate 10-day water qualities of estuary reservoirs. For the proper analysis and the application of hydraulics needed to build a model, lake hydraulics was simplified by condisering only hydrological inflow and lake mixing currents. The box division in the MBQER is longitudinal one dimension for upper and middle part, and two layers for lower part of the reservoir. 2. The methods of box division for the multiple box model were ekamined and applied to Asan-estuary reservoir. For determining the number of boxes, Pe number and Pk number were used. In case of three boxes, the error by the model simplification would be estimated about 5 % Therefore, in Asan reservoir, the proper number of boxes was three. 3. The MBQER was calibrated and verified using measured data in Asan-estuary reservoir from 1986 to 1988. The Root Mean Squares(RMS) for the differences between measured data and simulated results by the MBQER were 1.10$^{\circ}$C C for water temperature, 75.8mg/1 for salinity, 0.082mg/1 for total-phosphorus showing good estimations. 4. Through the simulation of water temperature and salinity by the MBQER, the exchange flow and the mixing coefficients for the estuary lake were determined. As a result of simulation, the horizontal mixing coefficients in Asan-estuary reservoir were in the range of 1.07X 105 to 1.12X 105 cm$^2$/sec and vertical mixing coefficient was 2.90X 10-1 cm$^2$/sec.

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Yield Prediction of Chinese Cabbage (Brassicaceae) Using Broadband Multispectral Imagery Mounted Unmanned Aerial System in the Air and Narrowband Hyperspectral Imagery on the Ground

  • Kang, Ye Seong;Ryu, Chan Seok;Kim, Seong Heon;Jun, Sae Rom;Jang, Si Hyeong;Park, Jun Woo;Sarkar, Tapash Kumar;Song, Hye young
    • Journal of Biosystems Engineering
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    • 제43권2호
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    • pp.138-147
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    • 2018
  • Purpose: A narrowband hyperspectral imaging sensor of high-dimensional spectral bands is advantageous for identifying the reflectance by selecting the significant spectral bands for predicting crop yield over the broadband multispectral imaging sensor for each wavelength range of the crop canopy. The images acquired by each imaging sensor were used to develop the models for predicting the Chinese cabbage yield. Methods: The models for predicting the Chinese cabbage (Brassica campestris L.) yield, with multispectral images based on unmanned aerial vehicle (UAV), were developed by simple linear regression (SLR) using vegetation indices, and forward stepwise multiple linear regression (MLR) using four spectral bands. The model with hyperspectral images based on the ground were developed using forward stepwise MLR from the significant spectral bands selected by dimension reduction methods based on a partial least squares regression (PLSR) model of high precision and accuracy. Results: The SLR model by the multispectral image cannot predict the yield well because of its low sensitivity in high fresh weight. Despite improved sensitivity in high fresh weight of the MLR model, its precision and accuracy was unsuitable for predicting the yield as its $R^2$ is 0.697, root-mean-square error (RMSE) is 1170 g/plant, relative error (RE) is 67.1%. When selecting the significant spectral bands for predicting the yield using hyperspectral images, the MLR model using four spectral bands show high precision and accuracy, with 0.891 for $R^2$, 616 g/plant for the RMSE, and 35.3% for the RE. Conclusions: Little difference was observed in the precision and accuracy of the PLSR model of 0.896 for $R^2$, 576.7 g/plant for the RMSE, and 33.1% for the RE, compared with the MLR model. If the multispectral imaging sensor composed of the significant spectral bands is produced, the crop yield of a wide area can be predicted using a UAV.