• Title/Summary/Keyword: Pre-polymer

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Structural modeling of actuation of IPMC in dry environment: effect of water content and activity

  • Swarrup, J. Sakthi;Ranjan, Ganguli;Giridhar, Madras
    • Smart Structures and Systems
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    • v.19 no.5
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    • pp.553-565
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    • 2017
  • Structural modeling of unencapsulated ionic polymer metal composite (u-IPMC) actuators that are used for flapping the insect scale-flapping wing of micro air vehicles (FMAV) in dry environmental conditions is carried out. Structural modeling for optimization of design parameters for retention of water, maximize actuation performance and to study the influence of water activity on the actuation characteristics of u-IPMC is explored for use in FMAV. The influence of equivalent weight of Nafion polymer, cations, concentration of cations, pre-treatment procedures on retention of water of u-IPMCs and on actuation parameters, flapping angle, flexural stiffness and actuation displacement are investigated. IPMC designed with Nafion having equivalent weight 900-1100, pre-heated at $30^{\circ}C$ and with sodium as the cations is promising for optimum retention of water and actuation performance. The actuation parameters while in operation in dry and humid environment with varying water activity can be tuned to desirable frequency, deflection, flap angle and flexural stiffness by changing the water activity and operational temperature of the environment.

X-ray Scattering Studies for Phase Separated Composite Organic Films

  • Choi, H.;Eom, K.E.;Wang, Q.;Kumar, S.;Kim, J.H.;Shin, S.T.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.1229-1232
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    • 2004
  • The ratio of optimized concentration on optical characteristics for phase-separated composite organic films (PSCOF) liquid crystal display is 30% of pre-polymer (NOA65) and 70% of ferroelectric liquid crystal (Felix). The layer structure in ferroelectric liquid crystal cell made by 30% NOA65 and 70% Felix materials is tilt-bookshelf layer structure. The angle of tilt-bookshelf structure are 17$^{\circ}$, 12$^{\circ}$ which are almost same of tilt angle of ferroelectric liquid crystal in Sm $C^{\ast}$ phase. We know that this result is from compensating the layer buckling. In this paper, we will discuss the effect of layer structure in PSCOF cell on ratio of concentration between pre-polymer and liquid crystal by x-ray measurements. We believe that technology of PSCOF is a good solution to solve the problems of align-defect and mechanical shock for future TV application and plastic LCD.

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Fabrication of in-situ Formed Namo-Composite Using Polymer Precursor : I. Adsorption Behavior of Polymer Followed $SiO_2$ Surface formation onto Silicon Nitride Surface (폴리머 Precursor를 이용한 in-situ 나노 복합체의 제조 : I. 질화규소 표면에서의 $SiO_2$ 피막형성에 따른 폴리머의 흡착거동)

  • 정연길;백운규
    • Journal of the Korean Ceramic Society
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    • v.37 no.3
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    • pp.280-287
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    • 2000
  • Adsorption behavior and amount of phenolic resin followed silica (SiO2) formation onto silicon nitride(Si3N4) surface were investigated using electrokinetic sonic amplitude (ESA) technique and with UV spectrometer, to fabricate Si3N4/SiC nano-composite based on reaction between SiO2 formed and phenolic resin absorbed onto Si3N4 particle. The amount of SiO2 formed and carbon from phenolic resin absorbed onto Si3N4 surface were calculated quantitatively to adjust the reaction between SiO2 and phenolic resin, resulting in no residual SiO2 and carbon. As a result, pre-heated tempeature for optimized reaction was below 25$0^{\circ}C$, in which there was no residual SiO2 and carbon.

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Molecularly Imprinted Polymers for Solid-Phase Extraction of Sarcosine as Prostate Cancer Biomarker from Human Urine

  • Hashemi-Moghaddam, Hamid;Rahimian, Majid;Niromand, Bahman
    • Bulletin of the Korean Chemical Society
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    • v.34 no.8
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    • pp.2330-2334
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    • 2013
  • A highly selective molecularly imprinted polymer (MIP) for sarcosine, a cancer marker, was prepared and its use as solid-phase extraction (SPE) sorbent material was demonstrated. The MIP was prepared by a very simple procedure using methacrylic acid as functional monomer and a mixture acetonitrile/water (4/1, v/v) as porogen, overcoming in this way the problems usually related to the imprinting of biological polar compounds. The MIP was tested in batch experiments in order to evaluate its binding properties and then used as SPE sorbent for the selective clean-up and pre-concentration of sarcosine. The extraction protocol was successfully applied to the direct extraction of sarcosine from spiked human urine indicating that the MIP allowed sarcosine to be pre-concentrated while simultaneously interfering compounds were removed from the matrix.

Pre-shaping of ionic polymer metal composite actuators by heat treatment and characterization (이온성 고분자 금속 복합물(IPMC) 액추에이터의 열처리에 의한 성형 및 특성분석)

  • Park, Shin-Ho;Kim, Dong-Ik;Park, Man-Jun;Lee, Seung-Ki
    • Journal of Sensor Science and Technology
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    • v.18 no.5
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    • pp.353-358
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    • 2009
  • Ionic polymer metal composite(IPMC) has been used as a promising material for various actuator applications. The IPMC actuator is difficult to be fabricated with complicated 3-dimensional shape. We propose a simple heat treatment process that can fabricate IPMC actuator with various shapes. Experimental results show the pre-shaped IPMC actuator by heat treatment does not show any degradation of its actuation abilities such as bending displacement, generation force and reliability in bending motion.

Liquid Crystal Orientation Properties on Homogeneous Polymer Surface by Various Alignment Methods

  • Kim, Young-Hwan;Lee, Kang-Min;Kim, Byoung-Yong;Oh, Byeong-Yun;Han, Jeong-Min;Seo, Dae-Shik
    • Transactions on Electrical and Electronic Materials
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    • v.10 no.1
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    • pp.16-19
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    • 2009
  • We have studied the liquid crystal alignment properties for various alignment methods on the homogeneous polyimide surface. Suitable liquid crystal alignment for one-side alignment cell on the polyimide surface by all alignment method was observed. Highly pre-tilt angle of the NLC for both-side rubbing cell was measured. But, low pre-tilt angle of the NLC for one-side ion beam and UV irradiation cell was observed. We consider that the pre-tilt angle of NLC for one-side ion beam and UV irradiation on the PI surface is lower than that of the PI surface with rubbing. Also, the suitable transmittance-voltage curves for the one-side rubbing TN-LCD on the PI surface with one-side UV irradiation were measured. Also, good response time characteristics of the one-side rubbing TN-LCD on the polyimide surface with one-side UV irradiation can be measured.

Electroactive Polymer Composites as a Tactile Sensor for Biomedical Applications

  • Kim GeunHyung
    • Macromolecular Research
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    • v.12 no.6
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    • pp.564-572
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    • 2004
  • Modem applications could benefit from multifunctional materials having anisotropic optical, electrical, thermal, or mechanical properties, especially when coupled with locally controlled distribution of the directional response. Such materials are difficult to engineer by conventional methods, but the electric field-aided technology presented herein is able to locally tailor electroactive composites. Applying an electric field to a polymer in its liquid state allows the orientation of chain- or fiber-like inclusions or phases from what was originally an isotropic material. Such composites can be formed from liquid solutions, melts, or mixtures of pre-polymers and cross-linking agents. Upon curing, a 'created composite' results; it consists of these 'pseudofibers' embedded in a matrix. One can also create oriented composites from embedded spheres, flakes, or fiber-like shapes in a liquid plastic. Orientation of the externally applied electric field defines the orientation of the field-aided self-assembled composites. The strength and duration of exposure of the electric field control the degree of anisotropy created. Results of electromechanical testing of these modified materials, which are relevant to sensing and actuation applications, are presented. The materials' micro/nanostructures were analyzed using microscopy and X-ray diffraction techniques.

Computer Simulation on Insulation Characteristics of Composite Material O-rings (복합소재 O-링 접합계면의 단열특성에 관한 컴퓨터 시뮬레이션)

  • Kim, Chung-Kyun;Kim, Sung-Won;Cho, Seung-Hyun
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2002.05a
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    • pp.291-295
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    • 2002
  • O-ring seal is usual component part in various mechanical apparatus for sealing that makes efficient performance of the equipments. The sealing performance of O-ring is affected in environments of the O-rings, like that applied pressure, working temperature, pre-compressed ratio and materials. In this paper, a pressurized, compressed elastomeric bi-polymer O-ring inserted into a rectangular groove is analyzed numerically using the MARC finite element program. The calculated FEM results showed that bi-polymer O-ring that is manufactured by NBR for an inner and FFKM for an outer ring shows a low temperature distribution among various bi-polymer O-ring models. But, the normal contact stress between the flange and upper part of the O-ring is small compared to other bi-polymer model.

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Novel RGB Polymer Dispersed Liquid Crystal Display using Color Pigments.

  • Shim, S.H.;Choi, S.Y.;Baek, D.H.;Kim, W.;Choi, S.E.;Son, G.;Suh, D.H.;Choia, J.W.;Lee, J.Y.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.784-787
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    • 2006
  • We have developed a RGB polymer dispersed liquid crystal film (RGB PDLC). To obtain the color display, color pigments are mixed in the prepolymer. We have presented an electro-optical performance of our cell and analyzed the electro optical properties for varying LC/ pre-polymer ratio and polymer type.

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Design of an Intelligent Polymer-Matrix-Composite Using Shape Memory Alloy (형상기억합금을 이용한 지능형 고분자 복합재료의 설계)

  • Jeong, Tae-Heon
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.21 no.10
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    • pp.1609-1618
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    • 1997
  • Thermo-mechanical behaviors of polymer matrix composite(PMC) with continuous TiNi fiber are studied using theoretical analysis with 1-D analytical model and numerical analysis with 2-D multi-fiber finite element(FE) model. It is found that both compressive stress in matrix and tensile stress in TiNi fiber are the source of strengthening mechanisms and thermo-mechanical coupling. Thermal expansion of continuous TiNi fiber reinforced PMC has been compared with various mechanical behaviors as a function of fiber volume fraction, degree of pre-strain and modulus ratio between TiNi fiber and polymer matrix. Based on the concept of so-called shape memory composite(SMC) with a permanent shape memory effect, the critical modulus ratio is determined to obtain a smart composite with no or minimum thermal deformation. The critical modulus ratio should be a major factor for design and manufacturing of SMC.