• Journal of the Korea Academia-Industrial cooperation Society
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• v.19 no.7
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• pp.493-503
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• 2018

Recently, as living standards have improved, many people are becoming more interested in health, and self-training is increasing through exercise to prevent and manage pre-illness. In general, an imbalance of muscles causes asymmetry of posture, which can cause various diseases by accompanying an adjustment force, circulation action, displacement of internal organs, etc.. In this study, the development of fitness software that can be self - training among smart wears has attracted considerable attention in recent years. In this study, a technology was proposed for the commercialization of self - trainer fitness wear by a simulation through Android - based applications. Self - trainer fitness software was developed by combining a conductive polymer, fashion design, sewing, and electric and electronic technology to monitor the unbalance of the muscles during exercise and make smart wear that can calibrate the asymmetry by oneself. In particular, a polymer sensor was fabricated by deriving the optimal MWCNT concentration, and the electrode signal was collected by attaching the electrode to the optimal position, where the electrode signal line using the conductive fiber was designed and attached to collect the signal. A signal module that converts the bio-signals collected through electrical signal conversion and transmits them using Bluetooth communication was designed and manufactured. Self-trainer fitness software that can be commercialized was developed by combining noise cancellation with Android-based self-training application using a software algorithm method.

• Applied Chemistry for Engineering
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• v.26 no.6
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• pp.640-647
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• 2015

As the need for next-generation flexible electronics grows, novel materials and technologies that can replace conventional indium tin oxide (ITO) for transparent electrodes have been of great interest. Among them, a conducting polymer, especially poly(3,4-ethylenedioxythiophene) : poly(styrene sulfonate) (PEDOT : PSS) is one of the most promising candidates because it is mechanically flexible, inexpensive, and capable of being processed in solution. Currently, there are a lot of research efforts on enhancing its electrical conductivity to the level of ITO or metal electrodes through chemical and/or physical processing. In this review article, we present various additives and pre-/post-deposition processing methods for improving the electrical conductivity of PEDOT : PSS. Some of representative reports are also introduced, which demonstrated the use of conductivity-enhanced PEDOT : PSS as transparent electrodes in electronics and energy conversion.

• Corrosion Science and Technology
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• v.7 no.1
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• pp.50-60
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• 2008

The majority of the described experimental results deal with relatively pure aluminium. Variations were made in the pretreatment of the aluminum substrates and an investigation was performed on the resulting changes in oxide layer composition and chemistry. Subsequently, the bonding behavior of the surfaces was investigated by using model adhesion molecules. These molecules were chosen to represent the bonding functionality of an organic polymer. They were applied onto the pretreated surfaces as a monolayer and the bonding behavior was studied using infrared reflection absorption spectroscopy. A direct and clear relation was found between the hydroxyl fraction on the oxide surfaces and the amount of molecules that subsequently bonded to the surface. Moreover, it was found that most bonds between the oxide surface and organic functional groups are not stable in the presence of water. The best performance was obtained using molecules, which are capable of chemisorption with the oxide surface. Finally, it was found that freshly prepared relatively pure aluminum substrates, which are left in air, rapidly lose their bonding capacity towards organic functional groups. This can be attributed to the adsorption of contamination and water to the oxide surface. In addition the adhesion of a typical epoxy-coated aluminum system was investigated during exposure to water at different temperatures. The coating was found to quite rapidly lose its adhesion upon exposure to water. This rapid loss of adhesion corresponds well with the data where it was demonstrated that the studied epoxy coating only bonds through physisorptive hydrogen bonding, these bonds not being stable in the presence of water. After the initial loss the adhesion of the coating was however found to recover again and even exceeded the adhesion prior to exposure. The improvement could be ascribed to the growth of a thin oxyhydroxide layer on the aluminum substrate, which forms a new, water-stable and stronger bond with the epoxy coating. Two routes for improvement of adhesion are finally decribed including an interphasial polymeric thin layer and a treatment in boiling water of the substrate before coating takes place. The adhesion properties were finely also studied as a function of the Mg content of the alloys. It was shown that an enrichment of Mg in the oxide could take place when Mg containing alloys are heat-treated. It is expected that for these alloys the (hydr)oxide fraction also depends on the pre-treatment and on the distribution of magnesium as compared to the aluminium hydroxides, with a direct impact on adhesive properties.

• Journal of Korean Society of Environmental Engineers
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• v.28 no.5
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• pp.527-534
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• 2006

The purpose of this study is the development of more effective filter-type polymer adsorbent for removal of anionic pollutants from wastewater. In order to synthesize the polymer adsorbent that possesses anionic exchangeable function, carboxyl(-COOH) group of PP-g-AA nonwoven fabric was converted into amine($-NH_2$) group by the chemical modification using diethylene triamine(DETA). FT-IR data indicate that amine group was introduced into PP-g-AA through amidation of grafted acrylic acid by reaction with DETA. The degree of amination increased with increase in the reaction time and temperature of the chemical modification process, and was significantly improved by the pre-swelling treatment of PP-g-AA with solvent and addition of metal chlorides as a catalyst in following order as $NH_4OH>MeOH{\geq}HCl{\geq}H_2O\;and\;AlCl_3>FeCl_3{\geq}SnCl_2{\gg}ZnCl_2{\geq}FeCl_2$, respectively. However, the addition of catalyst limited the reusability of DETA, hence was less useful from the viewpoint of cost effectiveness and waste management. The anion exchange capacity of the aminated PP-g-AA(PP-g-AA-Am) increased with increase in the degree of amination, but it reached maximum value at the degree of amination as about $50{\sim}60%$. The anion exchange capacity of PP-g-AA-Am was higher than those of commercial anion resins.

• Polymer(Korea)
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• v.38 no.6
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• pp.774-781
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• 2014

Acetylenic or phenylethynyl end-capped polyisoimide oligomers ($M_w$ 2500 g/mol, 5000 g/mol) based upon 4,4'-diamino diphenyl ether (4,4'-ODA)/4,4'-oxydiphthalic anhydride (ODPA) and 4,4'-ODA/3,3',4,4'-benzophenone tetracarboxylic acid dianhydride (BTDA) were synthesized by using 4-ethynylaniline (4-EA) or 4-phenylethynyl phthalic anhydride (4-PEPA) as an end capper. The incorporation of ethynyl groups were confirmed by FTIR spectroscopy. The isomerization temperature was influenced by molecular weight as well as the backbone structure of polyisoimides oligomers. Thus, polyisoimide oligomers with molecular weight of 2500 g/mol was found to be imidized at temperature $10^{\circ}C$ lower than that for the oligomers with molecular weight of 5000 g/mol. The crosslinking reaction of ethynyl groups occurred at a higher temperature than that for the isoimide/imide isomerization reaction. These two reactions were totally or partially overlapped on the DSC thermograms for the polyisoimide oligomer end-capped with 4-EA. Kinetics of thermal imidization and crosslinking reactions for the 4,4'-ODA/ODPA polyisoimide oligomers end-capped with 4-PEPA were investigated by performing dynamic DSC experiments at heating rate of $10^{\circ}C/min$. The activation energy and pre-exponential factors were 141 kJ/mol and $1.45{\times}10^{13}min^{-1}$ for the imidization reaction and 177 kJ/mol and $2.90{\times}10^{13}min^{-1}$ for the crosslinking reaction, respectively.

• Polymer(Korea)
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• v.33 no.1
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• pp.79-83
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• 2009

Thin electric insulation layers were coated on aluminum plates and aluminum condenser cases by plasma polymerization of HMDSO+$O_2$. Electric resistances of the films were higher than 1.0 M$\Omega$ if they are thicker than 0.5 ${\mu}m$ independently of the type of films but their surface morphologies and adhesion strengths were dependent on the process conditions. Deposition rate and adhesion strength of the films were dependent on $O_2$/HMDSO flow ratio and discharge power. The best result was obtained at $O_2$/HMDSO flow ratio of 4 and discharge power of 60 W. Adhesion strength could also be highly improved if aluminum was pre-treated in boiling water for 30 min through the formation of Al-O-Si bonding between the film and the aluminum surface. The coated films showed excellent chemical and thermal resistances.

• Journal of Korean Society of Environmental Engineers
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• v.29 no.1
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• pp.74-81
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• 2007

Using the new experimental method named "filtration-permeation", the average specific resistances which plays an important role in designing cake filtration apparatus and the development of cake filtration theory were measured in this study. By this new experimental method, two kinds of average specific resistances are measured. The one from the filtration is named 'filtration average specific resistance $\alpha_{avf}$, and the other from the permeation of particle eliminated water through the pre-formed cake is named 'permeation average specific resistance $\alpha_{avf}$. The "filtration-permeation" method is applied to three different kind of suspensions(i.e. particulate suspension, pre-flocculated suspension and macro-molecule suspension) to obtain filtration and permeation average specific resistances. A theoretical procedure of cake filtration is studied based on the values of permeation average specific resistance. With the study it was concluded that the influence of the sedimentation during particlulate filtration operation could not be ignored as commonly used. And the solid content of suspension, S, which also regarded usually as constant, changes during filtration of particles. It is also verified that the exact value of solid content of cake for floe filtration could not be obtained. These significant problems are all solved by our new "filtration-permeation" experimental method.

• Proceedings of the Materials Research Society of Korea Conference
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• 2003.03a
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• pp.137-137
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• 2003

Conducting PPy/PVA composite and pure PPy gas sensors were prepared by in-situ vaporstate polymerization method in a vaporization chamber under N2 condition, by exposing the pre-coated electrode with PVA/FeC13 to distilled pyrrole monomer. The various electrical sensing behaviors of both types of sensors were systematically investigated by a flow measuring system including mass flow controller (MFC) and bubbling bottle. The FT-Raman spectroscopy of vapor state polymerized PPy was identical to that of chemically polymerized PPy, confirming the same chemical structure. Both types of sensors had positive sensitivity when exposed to methanol gas. The sensitivity varied linearly with gas concentration in the range of 50ppm to 1059ppm. The detection limit of PPy/PVA sensor was believed to be as low as 10ppm. The sensitivity of PPy/PVA composite sensor was higher than that of pure PPy sensor. Both the response time and recovery time of PPy/PVA composite sensors were longer than those of pure PPy sensors. The thickness of the sensing film affected the sensitivity this way that the sensor having thinner film had higher sensitivity, indicating that the resistance of polymer film involved in the sensing behavior was bulk resistance rather than surface resistance. The reproducibility of PPy/PVA composite sensor was excellent during eight on-off cycles by switching between N2 and 3000ppm methanol gas. The sensitivity of PPy/PVA composite sensor was only maintained for two weeks, while the sensitivity of pure PPy sensor was maintained over two months.

• Transactions on Electrical and Electronic Materials
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• v.14 no.3
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• pp.133-138
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• 2013

Acrylonitrile-butadiene-styrene (ABS) plastic is a polymer material extensively used in electrical and electronic applications. Nickel (Ni) thin film was deposited on ABS by electroless plating, after its surface was treated and modified with atmospheric plasma generated by means of dielectric barrier discharges (DBDs) in air. The method in this study was developed as a pre-treatment for electroless plating using DBDs, and is a dry process featuring fewer processing steps and more environmentally friendliness than the chemical method. After ABS surfaces were modified, surface morphologies were observed using a scanning electron microscope (SEM) to check for any physical changes of the surfaces. Cross-sectional SEM images were taken to observe the binding characteristics between metallic films and ABS after metal plating. According to the SEM images, the depths of ABS by plasma are shallow compared to those modified by chemically treatment. The static contact angles were measured with deionized (DI) water droplets on the modified surfaces in order to observe for any changes in chemical activities and wettability. The surfaces modified by plasma showed smaller contact angles, and their modified states lasted longer than those modified by chemical etching. Adhesion strengths were measured using 3M tape (3M 810D standard) and by 90° peel-off tests. The peel-off test revealed the stronger adhesion of the Ni films on the plasma-modified surfaces than on the chemically modified surfaces. Thermal shock test was performed by changing the temperature drastically to see if any detachment of Ni film from ABS would occur due to the differences in thermal expansion coefficients between them. Only for the plasma-treated samples showed no separation of the Ni films from the ABS surfaces in tests. The adhesion strengths of metallic films on the ABS processed by the method developed in this study are better than those of the chemically processed films.

• Journal of Conservation Science
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• v.25 no.2
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• pp.171-178
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• 2009

When we considered the superior ability of the semi-water soluble urethane 1st transcription and final epoxy products, the stability for moving historic sites depend on physical properties and the peel off state of separation media. In this paper, we synthesised three type of water-borne epoxy solution without using a surfactant, and investigated the peel off state, physical properties, and the state between urethane surface and epoxy surface after exfoliation. The life time of water-borne separation media is over the 60 days. When it is used the 30% solution of water-borne separation media, it made good separation of urethane pre-products surface and epoxy final product surface and no color change. The separation tension pressure is about 15~50 kg/$cm^2$ and there is no surface whitewash phenomenon. We suggest that this water-borne epoxy will be best material as separation media of low viscosity type.