• Bulletin of the Korean Chemical Society
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• v.29 no.10
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• pp.2051-2053
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• 2008

• Proceedings of the Korean Vacuum Society Conference
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• 2010.02a
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• pp.39-39
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• 2010

There have been many efforts to utilize the outstanding properties of graphene for macroscopic applications such as transparent conducting films useful for flexible/stretchable electronics. However, the lack of efficient synthesis, transfer, and doping methods limited the scale and the quality needed for the practical production of graphene films. In this presentation, we introduce ultra-large scale (~30 inch) synthesis and roll-to-roll transfer of graphene films showing excellent electrical and physical properties suitable for practical applications. Considering the outstanding scalability/processibility of roll-to-roll and CVD methods and the extraordinary flexibility/conductivity of graphene films, we expect the commercial production and application electrodes replacing the use of ITO can be realized in near future.

• Bulletin of the Korean Chemical Society
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• v.32 no.spc8
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• pp.3022-3030
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• 2011

Since the discovery of the fact that compounds bearing a vinylic fluoride moiety often exhibit remarkable biological activities such as enzyme inhibitors, many synthetic methods for fluorine-substituted vinylic compounds have been developed. The synthesis of selectively fluorinated building blocks, such as arylsubstituted fluoro-alkenes, also has become an area of interest in recent years. Herein we describe a novel and practical method for the synthesis of 1,1-difluoro- and 1-fluoroalkenes starting from easily accessible trifluoroacetophenone derivatives. Various 1,1-difluoro- and 1-fluoroalkenes were prepared by the reaction of the corresponding tosyl hydrazones that were derived from trifluoroacetophenone derivatives by treating with alkyl or aryllithium reagents via addition-elimination and single electron transfer (SET) mechanism.

• Archives of Pharmacal Research
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• v.23 no.6
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• pp.564-567
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• 2000

The use of amino acid derivatives as building blocks in peptide synthesis is increasingly being recognized as a potential route for the development of pharmaceutical agents. Side chain protection of polyfunctional amino acids such as Ser, Thr, Tyr is viewed as being particularly important. Although these derivatives are commercially listed, they are expensive and not widely available. We describe here a practical large-scale synthesis of t-butyl introduced D-serine, one of the building blocks of zoladex, a peptide drug.

• Bulletin of the Korean Chemical Society
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• v.35 no.6
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• pp.1692-1696
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• 2014

A practical and efficient one-pot synthesis of 1,3,5-trisubstituted pyrazoles from ${\alpha},{\beta}$-enones and arylhydrazine hydrochlorides has been developed. The pyrazoles were formed via a tandem formation of the corresponding pyrazolines and an acid-catalyzed aerobic oxidation process.

• Bulletin of the Korean Chemical Society
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• v.22 no.10
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• pp.1167-1168
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• 2001

• Bulletin of the Korean Chemical Society
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• v.7 no.2
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• pp.157-158
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• 1986

• International Journal of Aeronautical and Space Sciences
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• v.7 no.1
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• pp.129-136
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• 2006

A new guidance synthesis for anti-ship missiles to control impact angle and impact time is proposed in this paper. The flight vehicle is assumed as a 1st order lag system to consider more practical system. The proposed guidance synthesis enhances the survivability of anti-ship missiles because multiple anti-ship missiles with the proposed synthesis can hit the target simultaneously. The control input to satisfy constraints of zero miss distance and impact angle, and the feedforward bias control input to control impact time constitute the guidance law. The former is from trajectory shaping guidance, the latter is from neural network. And particle swarm optimization method is introduced to furnish reference input and output for learning in neural network. The performance of the proposed synthesis in the accuracy of impact time and angle is validated by numerical examples.

• Journal of the Korean Chemical Society
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• v.53 no.4
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• pp.415-421
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• 2009

A convenient and practical synthesis of 1, 8-dioxo-octahydroxanthene derivatives using various aldehydes, 5, 5-dimethyl-1, 3-cyclohexanedione in water was successfully carried out in the presence of polyethylene glycol (PEG) as a catalyst. Simple work-up, clean products, high yields and water as a green solvent are the attractive features of this methodology.

• Proceedings of the Materials Research Society of Korea Conference
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• 2010.05a
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• pp.3.2-3.2
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• 2010

There have been many efforts to utilize the outstanding properties of graphene for macroscopic applications such as transparent conducting films useful for flexible/stretchable electronics. However, the lack of efficient synthesis, transfer, and doping methods limited the scale and the quality needed for the practical production of graphene films. In this presentation, we introduce ultra-large scale (~30 inch) synthesis, roll-to-roll transfer, and chemical doping of graphene films showing excellent electrical and physical properties suitable for practical applications. Considering the outstanding scalability/processibility of roll-to-roll and CVD methods and the extraordinary flexibility/conductivity of graphene films, we expect the commercial production and application electrodes replacing the use of ITO can be realized in near future.