• 제목/요약/키워드: Pozzolanic Reaction

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콘크리트 내구성 향상을 위한 시멘트 재료의 수밀성 개선에 관한 연구 (A Study on the Watertightness Improvement of Cementitious Material for Durability Improvement of Concrete)

  • 강현주;송명신;정의담
    • 한국방재학회 논문집
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    • 제10권5호
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    • pp.17-25
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    • 2010
  • 콘크리트의 내구성능 향상을 위한 방안으로서 시멘트 재료의 수밀성능 증진에 대한 연구를 수행하였다. 보통 포틀랜드 시멘트 및 보통 포틀랜드 시멘트와 플라이애쉬의 혼합계 재료에 다양한 성능의 수밀성능 개선제를 혼합하여 수밀성 실험을 진행한 결과, 시멘트 재료의 수밀성능 향상은 시멘트 수화생성물인 CSH의 생성과 유기지방산에 의한 수화물과의 접촉각의 크기와 밀접한 관계가 있으며 수화초기에 활발하게 생성되는 CSH는 수밀성과 장기적인 흡수율 저감에 영향을 주는 것으로 나타났다. 또한 시멘트 재료의 작업성 개선을 위하여 플라이애쉬를 사용하는 경우, 구형 플라이애쉬의 작업성 증진에 의해 시멘트 재료의 조직이 치밀화 되고 포졸란 재료의 특성에 의한 CSH의 생성으로도 수밀성이 향상 되는 것으로 나타났다. 다양한 종류의 수밀성 재료를 혼합하여 흡수율 및 수화 생성물의 변화에 대해 실험한 결과, 콘크리트의 내구성 향상을 위해서는 어떠한 형태이든 시멘트 재료에 수밀성 혼화제의 혼합 사용이 바람직 한 것으로 판단된다.

고유동성 채움재 타설장비를 이용한 모형시험 (A Small Scale Test using the Coal Ash Placement Equipment)

  • 김주형;조삼덕;함태규;도종남;천병식
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2010년도 춘계 학술발표회
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    • pp.1452-1457
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    • 2010
  • 본 연구에서는 국내 회처리장에 매립되어 있는 매립회를 효율적으로 사용하기 위한 실내 모형시험장치인 CSP 시스템을 제작하여 매립회와 물 그리고 시멘트량을 조절하여 모형지반을 조성하고 이에 대한 강성변화를 평가하였다. 시멘트를 첨가한 모형지반이 시멘트를 첨가하지 않은 경우에 비해 빠른 속도로 경화가 진행되었으며 192시간 경과 후에는 경화속도가 급격히 감소하는 것으로 나타났다. 모형지반 조성시 전체 중량의 30~45% 사이의 물의 양 변화는 지반의 강성 변화에 큰 영향을 끼치지는 않는 것으로 나타났다. 추후에는 지반 조성 초기에 큰 지반강성의 크기를 얻을 수 있도록 시멘트량을 증가시키는 등의 다양한 영향인자에 대한 시험을 수행하여 고유동성 채움재 활용성을 정량적으로 평가하는 것이 필요할 것으로 판단된다.

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혼화재 종류 및 활성황토 대체율별 콘크리트의 공학적 특성에 관한 실험적 연구 (Experimental Study on the Properties of Concrete by the Kinds of Admixture and the Replacement Ratios of Activated Hwangtoh)

  • 최희용;김무한;김문한;황혜주;최성우
    • 콘크리트학회논문집
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    • 제13권2호
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    • pp.123-129
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    • 2001
  • 본 연구에서는 천연재료인 황토의 활용성을 넓히기 위해, 황토를 혼화재로 사용한 경우 혼화재 종류 및 황토 대체율에 따른 콘크리트의 기초물성을 비교.검토하였다. 연구 결과, 황토를 사용할 경우 유동성은 다소 저하하는 것으로 나타났으며, 혼화재를 대체하지 않은 콘크리트에 비해 공기량도 다소 저하하는 것으로 나타나, 고성능 감수제의 선택성 및 AE제의 사용에 의한 공기량 보정이 필요할 것으로 판단된다. 황토와 시멘트간의 포졸란반응에 의한 강도발현성상을 검토한 결과, 황토를 콘크리트용 혼화재로서 사용하기 위해서는 가열에 의한 활성화공정이 필요한 것으로 나타났으며, 활성황토를 콘크리트용 혼화재료로 사용할 경우 활발한 포졸란반응에 의해 압축 강도 발현이 플레인콘크리트보다 높게 나타나, 건설 신재료로서의 황토의 개발이 가능할 것으로 사료된다. 활성황토의 대체율에 따른 콘크리트의 특성은 대체율이 증가할수록 강도발현수준이 높게 나타났으나, 대체율 30%의 경우 무혼입에 비해 강도가 저하하는 것으로 나타나, 활성황토의 적정 대체율에 대한 보다 심도 있는 연구가 필요할 것으로 사료되며, 본 연구의 범위에서 활성황토의 적정 대체율의 범위는 10~20%내외에 존재할 것으로 사료된다.

농업부산물의 혼화재료로써 사용가능성에 관한 연구 (The Research on Possibility as Mineral Admixture of Agriculture by-product)

  • 정의창
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2019년도 춘계 학술논문 발표대회
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    • pp.178-179
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    • 2019
  • The purpose of this study was to investigate the possibility as mineral admixture of agriculture by-product. XRD and XRF analysis were performed on rice straw ashes at various combustion temperatures to identify chemical compositions. Also to evaluate properties of pozzolanic reaction, pH change method was tested.

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Expansion Properties of Mortar Using Waste Glass and Industrial By-Products

  • Park, Seung-Bum;Lee, Bong-Chun
    • International Journal of Concrete Structures and Materials
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    • 제18권2E호
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    • pp.125-132
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    • 2006
  • Waste glass has been increasingly used in industrial applications. One shortcoming in the utilization of waste glass for concrete production is that it can cause the concrete to be weakened and cracked due to its expansion by alkali-silica reaction(ASR). This study analyzed the ASR expansion and strength properties of concrete in terms of waste glass color(amber and emerald-green), and industrial by-products(ground granulated blast-furnace slag, fly ash). Specifically, the role of industrial by-products content in reducing the ASR expansion caused by waste glass was analyzed in detail. In addition, the feasibility of using ground glass for its pozzolanic property was also analyzed. The research result revealed that the pessimum size for waste glass was $2.5{\sim}1.2mm$ regardless of the color of waste glass. Moreover, it was found that the smaller the waste glass is than the size of $2.5{\sim}1.2mm$, the less expansion of ASR was. Additionally, the use of waste glass in combination with industrial by-products had an effect of reducing the expansion and strength loss caused by ASR between the alkali in the cement paste and the silica in the waste glass. Finally, ground glass less than 0.075 mm was deemed to be applicable as a pozzolanic material.

A potential review on the influence of nanomaterials on the mechanical properties of high strength concrete

  • P. Jagadesh;Karthik Prabhu ;Moutassim Charai;Ibrahim Y. Hakeem;Emrah Madenci;Yasin Onuralp Ozkilic
    • Steel and Composite Structures
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    • 제48권6호
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    • pp.649-666
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    • 2023
  • In the current scenario, conventional concrete faces a substantial challenge in the modern era of the construction industry. Today's structures are massive, featuring innovative designs and strict time constraints. Conventional concrete does not provide the required compressive strength, tensile strength, flexural strength, toughness, and cracking resistance. As a result, most of engineers and professionals prefer to use ultra-high-performance concrete (UHPC), based on its wide advantages. Several advantages like mechanical and durability properties of UHPC provides dominant properties than the traditional concrete. Mix proportions of UHPC consists of higher powder content which provides maximum hydration and pozzolanic reaction, thereby contributing to the enhancement of the UHPC properties. Apart from that the nanomaterials provides the filler behavior, which will further improve the density. Enhanced density and mechanical properties lead to improved durability properties against water absorption and other typical chemicals. Nanomaterials are the most adopted materials for various applications, ranging in size from 0.1 nanometers to 100 nanometers. This article explores the effects of nanomaterial application in UHPC as a replacement for cementitious material or as an additive in the UHPC mix. The physical and durability properties modifications and improvements of UHPC, as well as negative effects, limitations, and shortcomings, are also analyzed.

Engineering properties of expansive clayey soil stabilized with lime and perlite

  • Calik, Umit;Sadoglu, Erol
    • Geomechanics and Engineering
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    • 제6권4호
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    • pp.403-418
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    • 2014
  • There are around 6700 millions tons of perlite reserves in the world. Although perlite possesses pozzolanic properties, it has not been so far used in soil stabilization. In this study, stabilization with perlite and lime of an expansive clayey soil containing smectite group clay minerals such as montmorillonite and nontronite was investigated experimentally. For this purpose, test mixtures were prepared with 8% of lime (optimum lime ratio of the soil) and without lime by adding 0%, 10%, 20%, 30%, 40% and 50% of perlite. Geotechnical properties such as compaction, Atterberg limits, swelling, unconfined compressive strength of the mixtures and changes of these properties depending on perlite ratio and time were determined. The test results show that stabilization of the soil with combination of perlite and lime improves the geotechnical properties better than those of perlite or lime alone. This experimental study unveils that the mixture containing 30% perlite and 8% lime is the optimum solution in stabilization of the soil with respect to strength.

Improved Durability Performances in Cement Mortar with Rice Husk Ash

  • Saraswathy, Velu;Karthick, Subbiah;Kwon, Seung-Jun
    • 한국건설순환자원학회논문집
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    • 제2권1호
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    • pp.66-73
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    • 2014
  • Currently many researches have been performed for enhancing durability of concrete. Rice husk ash has several advantages like early strength of concrete and dense pore structure. A calcium silicate hydrate (CSH) gel around the cement particles due to pozzolanic reaction of rice husk can increase the strength of concrete against cracking. Very limitedly a systematic and detailed investigation on the corrosion performance of rice husk ash and silica fume blended concrete is performed. A realistic approach has been made through compressive strength, bond strength, and split tensile strength etc. Corrosion performance was also evaluated rapid chloride ion penetration test (RCPT) and impressed voltage test, and the results were discussed in the paper.

콘크리트 시험체 시험법을 통한 고강도 콘크리트의 알칼리골재 반응성 (The Possibility of Alkali-Aggregate Reaction of High Strength Concrete by Concrete Bar Test)

  • 권영진;김무한
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 1996년도 봄 학술발표회 논문집
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    • pp.137-140
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    • 1996
  • The deterioration of concrete due to alkali-aggregate reaction is dependent on the total alkali content per unit volume of concrete. It was reported that the expansion of high alkali concrete with the reactive aggregate increased easily due to high alkali of concrete with the reactive aggregate increased easily. And it has been confirmed that the addition of pozzolanic material prevents the concrete with reactive aggregate from deterioration caused by alkali-aggregate reaction. It is the aim of this study to provide the fundamental data on the possibility of alkali-aggregate reaction of high strength concrete and its preventing and repair technic.

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시멘트 클린커 광물의 수화에 미치는 해수성분의 영향 (I)SO42- 및 Cl-이온에 의한 영향 (The Effect of Seawater on Hydration of Clinker Minerals (I) Effects of SO42- and Cl- ions)

  • 신도철;송태웅;한기성;최상흘
    • 한국세라믹학회지
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    • 제24권1호
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    • pp.77-85
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    • 1987
  • Hardened cement paste is mainly affected by corrosion of sulphate and chlorine ions in sea water. In this investigation, many specimens were made with the cement clinker minerals such as C3S, C3A, C4AF and their mixture according to cement composition added various blending materials. After the specimens were immersed in 4% MgSO4 and MgCl2 solutions, the product of reaction, the microstructure of specimen and Ca+2 ion leached in the solution were studied. The formation of Ca(OH)2 in the specimen of C3S is reduced relatively by adding pozzolanic admixtures. The chlorine ion is easily diffuse into the C3S specimen and produced CaCl2 compound, and it makes the specimen porous by leaching out itself into the solution. The specimen of C3A, C4AF are broken down by expanding reaction of ettringite and gypsum compound produced in the MgSO4 solution. At a later period, the ettringite is transformed into gypsum and 5MgO.2Al2O3·15H2O. The C3A in the MgCl2 solution combines chlorine ion to form Friedel's salt and prevents the diffusion reaction of chlorine ion into the specimen. Granulated slag shows inferior effect on the resistance of the specimen in MgSO4 solution by forming ettringite and gypsum, but good result in MgCl2 solution. Pozzolanic materials, on the whole, offer noticable effect on the resistance of the specimen in both solutions.

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