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Development of Simple Solvent Treating Methods to Enhance the Efficiency of Small-Molecule Organic Solar Cells

  • Kim, Jin-Hyun;Heo, Il-Su;Gong, Hye-Jin;Yu, Yeon-Gyu;Yim, Sang-Gyu
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.276-276
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    • 2012
  • The interface morphology of organic active layers is known to play a crucial role in the performance of organic photovoltaic (OPV) cells. Especially, a controlled nanostructure with a large contact area between electron donor (D) and acceptor (A) layers is necessary to improve the power conversion efficiency (PCE) of the cells since the short exciton diffusion lengths in organic semiconductors limit the charge (hole and electron) separation before excitons recombination. In this work, we developed simple solvent treating methods to fabricate a nanostructured DA interface and applied them to enhance the PCE of ZnPc/C60 based small molecule OPV cells. Interestingly, it was observed that the solvent treatment on the donor layer prior to the deposition of the acceptor layer resulted in a significant decrease in PCE, which was due to an existence of undesirable voids at the DA interface. Instead, the solvent vapor treatment after the DA bilayer formation led to densely packed and well dispersed DA contacts. Consequently, 3-fold enhancement of PCE as compared to the untreated bilayer cell was accomplished.

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Photonic Crystal Effect of Nano-Patterned PEDOT:PSS Layer and Its Application to Absorption Enhancement of ZnPc Thin Films

  • Han, Ji-Young;Ryu, Il-Whan;Park, Da-Som;Kwon, Hye-Min;Yim, Sang-Gyu
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.252-252
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    • 2012
  • It is widely accepted that short exciton diffusion lengths of organic semiconductors with respect to the film thickness limit the charge (hole and electron) separation before excitons recombination in organic photovoltaic (OPV) cells. Therefore the efficient absorption of incident light within the thin active organic layer is of great importance to improve the power conversion efficiency (PCE) of the cells. In this work, we fabricated 2-dimensionally (2D) nano-patterned poly(3,4-ethylenedioxythiophene): poly(styrenesulfonate) (PEDOST:PSS) layers using capillary phenomenon and nano-imprinting technology at the scale of several hundred nanometers. This 2D nano-patterned PEDOT:PSS layer exerted photonic crystal effect such as redirection of light paths and variation of light intensity at specified wavelengths. It is also expected that the consequently alternated light pass lengths and intensities change the absorption properties of zinc phthalocyanine (ZnPc) thin films grown on top of the nano-patterned PEDOT:PSS layer. The influence of conductivity and thickness of the PEDOT:PSS layer on the absorption properties of ZnPc thin films were also investigated.

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Fabrication of 3-dimensional magnetic sensor by anisotropic etching in TMAH (TMAH에 의한 이방성 식각을 이용한 3차원 자기센서의 제작)

  • Jung, Woo-Chul;Nam, Tae-Chul
    • Journal of Sensor Science and Technology
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    • v.8 no.4
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    • pp.308-313
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    • 1999
  • This paper will present an anisotropic etching in TMAH technique used in the fabrication of three-dimensional magnetic field vector sensor based on angled Hall plate structure. This sensor design relies on simultaneously detecting all magnetic field vector components using Hall plates that are imbedded into the silicon [111] sloped-surface of bulk micromachined cavity by the anisotropic etching of [100] silicon. The fabricated Hall elements has relatively improved sensitivity compare to convensional Hall elements for three-dimensional magnetic field sensing. The product sensitivity of 547V/AT at the supply current of 1.0mA was achived. The corresponding limit in the detection of magnrtic field is 0.07G that calculated by measured power spectral density(PSD) in magnetic sensor output.

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Effects of Storage Duration on Physicochemical and Antioxidant Properties of Tomato (Lycopersicon esculentum Mill.)

  • Tilahun, Shimeles;Park, Do Su;Taye, Adanech Melaku;Jeong, Cheon Soon
    • Horticultural Science & Technology
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    • v.35 no.1
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    • pp.88-97
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    • 2017
  • This study explored the physicochemical and nutritional changes associated with storage duration of fresh tomatoes. Fruits of the 'TY Megaton' and 'Yureka' tomato cultivars were harvested at the pink stage and stored at $12^{\circ}C$ for 20 days. During storage, firmness, weight loss, skin color (Hunter L, a, b, a / b values), soluble solids content (SSC), titratable acidity (TA), pH, antioxidant contents (lycopene, ascorbic acid, and total phenolics) and antioxidant activity were evaluated. Firmness was above the minimum marketable limit and fresh weight loss was below maximum acceptable weight loss after 3 weeks of storage, and no deleterious effect on antioxidant contents or activities were observed. Significant differences in SSC, TA, and pH were seen between varieties, but not between fruits stored for different durations. In both varieties, Hunter a values increased more than five-fold after 8 days of storage; this correlated with a more than four-fold accumulation of lycopene after two weeks of storage. The antioxidant activity of tomatoes was highest at the beginning of the storage period, likely because of the effective DPPH - reducing power of ascorbic acid and total phenolics. Antioxidant activity increased after 12 days of storage because of increasing lycopene content. Hence, this study indicates that pink - stage tomatoes may be stored at $12^{\circ}C$ for up to 3 weeks without affecting marketability or nutritional value.

Impact of dental fear on oral health related quality of life in teenagers (청소년들의 치과 공포감이 구강건강 삶의 질에 미치는 영향)

  • Lee, Hye-Kyung
    • Journal of Korean society of Dental Hygiene
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    • v.16 no.5
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    • pp.759-766
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    • 2016
  • Objectives: The purpose of the study was to investigate the impact of dental fear on the oral health related quality of life in teenagers. Methods: A self-reported questionnaire by Likert 5 point scale was completed by 900 high school students in J area from March 10 to April 20, 2014. The questionnaire consisted of general characteristics of the subjects, dental fear survey, and oral health related quality of life. Data were analyzed by t-test and One-way ANOVA using SPSS 12.0 program. Results: Oral symptoms had no significant differences in mother's education and family economic status. Emotional well-being factors had no significant difference in age, religion, school performance, and family economic strength. Dental fear was closely related to emotional well-being, Oral symptoms, social stabilities, functional limit and mental stabilities. Explanation power of the model was 29.1%. Conclusions: It is very important to explain the dental fear procedure to teenagrers before dental surgery and this will enhance the oral health related quality of life in teenagers.

RASE Acquisition Algorithm of Ultra Wideband System for Car Positioning and Traffic Light Control (차량 위치추적기반 교통신호등 제어용 UWB 시스템의 Acquisition 알고리즘 연구)

  • Hwang, In-Kwan;Park, Yun-Jin
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.30 no.10C
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    • pp.992-998
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    • 2005
  • In this paper, An Ultra Fast Acquisition Algorithm of low transmission rate ultra-wideband(UWB) systems for car positioning and traffic light controling is proposed. Since the acquisition algorithms for CDMA system are not fast enough to access the low transmission rate UWB systems, the new ultra fast acquisition scheme which can be implemented with low cost and simplified circuit is required. The proposed algorithm adopted the Recurrent Sequential Estimation scheme and trinomial M-sequence. Therefore, The proposed scheme can reduce the average acquisition time in $1\~3{\mu}sec$ with simple circuit, even for the UWB systems which use long pseudo-noise(PN) sequence and transmit low power below the FCC EIRP emission limits. The simulation results for the average acquisition time of the proposed scheme are compared with the ones of the existing acquisition schemes.

Feasibility Study of the Combustible Gab Control System Following a LOCA (냉각재 상실사고시 가연성 가스제거 계통의 타당성 조사)

  • Hyung Won Lee;Chang Sun Kang
    • Nuclear Engineering and Technology
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    • v.16 no.4
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    • pp.217-223
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    • 1984
  • The feasibility of not employing recombiners rather using the postaccident Purge system alone to control hydrogen concentration in the containment following a LOCA, is analyzed in this paper. For this study, the hydrogen concentration in the containment, hydrogen removal through the purge system, and additional off-site dose due to hydrogen purge were calculated. The economic justification of a hydrogen recombiner system (2 recombiners) was also investigated by using the cost benefit concept. As a result, the purge system is sufficient to maintain the hydrogen concentration at a safe level without hydrogen recombiners, and it meets the dose limit requirements set forth in 10 CFR part 100. A hydrogen recombiner system would be justified based on cost-benefit concept for common use in a site with 4 units or more.

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Behavior of the Residual Stress on the Surfaces of 12Cr Steels Generated by Flame Hardening Process (화염경화 표면처리 공정에 의한 12Cr 강의 잔류응력 거동)

  • 이민구;김광호;김경호;김흥회
    • Journal of Surface Science and Engineering
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    • v.37 no.4
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    • pp.226-233
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    • 2004
  • The residual stresses on the surfaces of low carbon 12Cr steels used as a nuclear steam turbine blade material have been studied by controlling the flame hardening surface treatments. The temperature cycles on the surfaces of 12Cr steel were controlled precisely as a function of both the surface temperature and cooling rate. The final residual stress state generated by flame hardening was dominated by two opposite competitive contributions; one is tensile stress due to phase transformation and the other is compressive stress due to thermal contraction on cooling. The optimum processing temperatures required for the desirable residual stress and hardness were in the range of $850^{\circ}C$ to $960^{\circ}C$ on the basis of the specification of GE power engineering. It was also observed that the high residual tensile stress generated by flame hardening induced the cracks on the surfaces, especially across the prior austenite grain boundaries, and the material failure virtually, which might limit practical use of the surface engineered parts by flame hardening.

Active Structural Acoustical Control of a Smart Structure using Uniform Force Actuator and Array of Accelerometers (균일힘 액추에이터와 가속도계 배열을 이용한 지능구조물의 능동구조 음향제어)

  • ;Stephen J Elliott;Paolo Gardonio
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2003.05a
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    • pp.368-373
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    • 2003
  • This paper presents a study of low frequencies volume velocity vibration control of a smart panel in order to reduce sound transmission. A distributed piezoelectric quadratically shaped polyvinylidene fluoride (PVDF) polymer film is used as a uniform force actuator and an array of 4$\times$4 accelerometer is used as a volume velocity sensor for the implementation of a single-input single-output con rot system. The theoretical and experimental study of sensor-actuator frequency response function sho vs that this sensor-actuator arrangement provides a required strictly positive real frequency response function below about 900Hz. Direct velocity feedback could therefore be implemented with a limited gain which gives reductions of about 15㏈ in vibration level and about 8 ㏈ in acoustic power level at the (1, 1) mode of the smart Panel. It has been also shown that the shaping error of PVDF actuator could limit he stability and performance of the control system.

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Inertia Latch Design for Micro Optical Disk Drives (초소형 광디스크 드라이브용 관성 래치 설계)

  • 김경호;김유성;이승엽;유승헌;김수경
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2003.05a
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    • pp.1157-1164
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    • 2003
  • Dynamic Load/unload (L/UL) mechanism is an alternative to the contact start stop (CSS) technology which eliminates stiction and wear failure modes associated with CSS. Other benefits of L/UL include increased areal density due to smooth disk surfaces, thinner overcoats, and lower head flying height Improved shock resistance due to elimination of head slap, and reduced power consumption. Inertia latch mechanism becomes important for mobile disk drives because of non operating shock performance. Various types of latch designs have been introduced in hard disk drives to limit a rotary actuator from sudden uncontrolled motion. In this paper, a single spring inertia latch is introduced for a small form optical disk drive, which uses a rotary actuator for moving an optical pick-up. A new small inertia latch with single spring is designed to ensure both feasible and small size. The shock performance of the new inertia latch is experimentally verified.

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