• 제목/요약/키워드: Potassium hydroxide

검색결과 210건 처리시간 0.029초

The Effect of Potassium Hydroxide on the Porosity of Phenol Resin-based Activated Carbon Fiber

  • Jin, Hang-Kyo
    • Carbon letters
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    • 제7권3호
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    • pp.161-165
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    • 2006
  • Activated carbon fiber could be prepared at 973 K by catalytic activation using potassium hydroxide. Phenol resin fiber (Kynol) was impregnated with potassium hydroxide ethanol solution, carbonized and activated at 973 K, resulting in activated carbon fibers with different porosities. The potassium hydroxide accelerated the activation of the fiber catalytically to form narrow micropore preferentially in carbon dioxide atmosphere. The narrow micropore volume of 0.3~0.4 cc/g, total pore volume of 0.3~0.8 cc/g, mean pore width of 0.5~0.7 nm was obtained in the range of 20~50% burnoff.

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Enhancing Enzymatic Digestibility of Miscanthus sinensis using Steam Explosion Coupled with Chemicals

  • Jung, Ji Young;Yang, Jae-Kyung
    • Journal of the Korean Wood Science and Technology
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    • 제44권2호
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    • pp.218-230
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    • 2016
  • The effect of steam explosion coupled with alkali (1% sodium hydroxide, 1% potassium hydroxide and 15% sodium carbonate) or organosolv solvent (85% methanol, 70% ethanol and dioxane) on the production of sugar, changes in the chemical composition of M. sinensis were evaluated. The steam explosion coupled with 1% potassium hydroxide and dioxane were better as compared with other treatments based on the removals of acid insoluble lignin, and about 89.0% and 85.4%. Enzymatic hydrolysis of steam explosion with 1% potassium hydroxide and dioxane treated M. sinensis, gave a 98.0% and 96.5% of glucose conversion, respectively. These results suggested that pretreatment of M. sinensis with either potassium hydroxide or dioxane could be a promising pretreatment method for glucose production.

Camelina oil transesterification using mixed catalyst of tetra methyl amonium hydroxide and potassium hydroxide on the tubular reactor

  • Hyun, Young-Jin
    • 한국응용과학기술학회지
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    • 제28권2호
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    • pp.178-184
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    • 2011
  • The analysis of reaction kinetics provided that the reaction order was the $1^{st}$ of triglyceride and the rate constant was 0.067 $min^{-1}$. The transesterification of camelina oil using 0.6 wt% mixed catalyst which consists of 40 v/v% of potassium hydroxide (1 wt%) and 60 v/v% of tetra methyl ammonium hydroxide (0.8 wt%), was carried out at $65^{\circ}C$ on the tubular reactor packed with static mixer. The conversion was shown to be 95.5% at the 6:1 molar ratio of methanol to oil, flow rate of feed of 3.0 mL/min and 24 of element of static mixer. The volume of washing water emitted by 0.6 wt% mixed catalyst was the half of the volume emitted by 1 wt% potassium hydroxide.

염기용액을 이용한 태양전지용 실리콘 기판의 절삭손상층 식각 특성 (The Saw Damage Etching Characteristics of Silicon Wafer for Solar Cell with Alkaline Solutions)

  • 권순우;이종협;윤세왕;김동환
    • 신재생에너지
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    • 제5권1호
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    • pp.26-31
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    • 2009
  • The surface etching characteristics of single crystalline silicon wafer were investigated using potassium hydroxide (KOH) and tetramethylammonium hydroxide (TMAH). The saw damage layer was removed after 10min by KOH 45wt% solution at $80^{\circ}C$. The wafer etched at high temperature ($90^{\circ}C$) and in low concentration (4wt%) of TMAH solution showed an increased etch rate of silicon wafer and wavy patterns on the surface. Especially, pyramidal textures were formed in 4wt% TMAH solution without alcohol additives.

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Influence of KOH Solution on the Passivation of Al2O3 Grown by Atomic Layer Depostion on Silicon Solar Cell

  • 조영준;장효식
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제45회 하계 정기학술대회 초록집
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    • pp.299.2-299.2
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    • 2013
  • We investigated the potassium remaining on a crystalline silicon solar cell after potassium hydroxide (KOH) etching and its effect on the lifetime of the solar cell. KOH etching is generally used to remove the saw damage caused by cutting a Si ingot; it can also be used to etch the rear side of a textured crystalline silicon solar cell before atomic layer-deposited Al2O3 growth. However, the potassium remaining after KOH etching is known to be detrimental to the efficiency of Si solar cells. In this study, we etched a crystalline silicon solar cell in three ways in order to determine the effect of the potassium remnant on the efficiency of Si solar cells. After KOH etching, KOH and tetramethylammonium hydroxide (TMAH) were used to etch the rear side of a crystalline silicon solar cell. To passivate the rear side, an Al2O3 layer was deposited by atomic layer deposition (ALD). After ALD Al2O3 growth on the KOH-etched Si surface, we measured the lifetime of the solar cell by quasi steady-state photoconductance (QSSPC, Sinton WCT-120) to analyze how effectively the Al2O3 layer passivated the interface of the Al2O3 layer and the Si surface. Secondary ion mass spectroscopy (SIMS) was also used to measure how much potassium remained on the surface of the Si wafer and at the interface of the Al2O3 layer and the Si surface after KOH etching and wet cleaning.

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Ettringite의 생성에 미치는 pH의 영향 (The Effect of pH on the Ettringite Formation)

  • 이의학;정찬일;송명신;이경희
    • 한국세라믹학회지
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    • 제39권7호
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    • pp.699-703
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    • 2002
  • Ettringite의 생성에 미치는 pH의 영향을 알아보기 위하여 ettringite 합성시 boric acid, hydrochloric acid, nitric acid 및 potassium hydroxide를 첨가하여 pH를 변화시켰다. 이때 XRD, SEM 분석을 통해 ettringite의 생성에 미치는 영향성을 검토하였다. 시험결과 pH10 이하에서는 석고와 aluminate gel이 안정화되어 ettringite 생성이 저해됨을 알수있었다

Optimization of Two-stage Pretreatment from Soybean Hull for Efficient Glucose Recovery

  • Jung, Ji-Young;Choi, Myung-Suk;Yang, Jae-Kyung
    • Journal of the Korean Wood Science and Technology
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    • 제40권2호
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    • pp.78-90
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    • 2012
  • Soybean hull is an attractive feedstock for glucose production. To increase the glucose conversion in acid hydrolysis, a pretreatment method combined steam explosion with alkali pretreatment for soybean hull was studied. For first step pretreatment, steam explosion conditions (log Ro 2.45) were optimized to obtain maximum solid recovery and cellulose content. In the second step pretreatment, the conditions for potassium hydroxide pretreatment of steam exploded soybean hull were optimized by using RSM (response surface methodology). The optimum conditions for minimum lignin content were determined to be 0.6% potassium hydroxide concentration, $70^{\circ}C$ reaction temperature and 198 min reaction time. The predicted lignin content was 2.2% at the optimum conditions. Experimental verification of the optimum conditions gave the lignin content in similar value with the estimated value of the model. Finally, glucose conversion of pretreated soybean hull using acid hydrolysis resulted in $97.1{\pm}0.4%$. This research of two-step pretreatment was a promising method for increasing the glucose conversion in the cellulose-to-glucose process.

고상법에 의한 Leucite 합성 (Leucite Synthesis from Solid-State Sintering)

  • 윤동섭;이병하
    • 한국세라믹학회지
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    • 제42권4호
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    • pp.282-286
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    • 2005
  • 인공치과재료인 도재에 백류석(Leucite)결정을 이용해 왔는데, 이는 치과재료에 함께 사용하는 금속재질의 열팽창계수가 크기 때문에 이에 맞추기 위한 것이다. 산업적으로는 카리 장석으로부터 부조화 용융으로 leucite 결정을 합성하여 이용하고 있으며 이는 $1150^{\circ}C$ 이상에서 생성된다. 본 연구는 치과 재료에 사용하는 leucite를 보다 낮은 온도에서 조화 용융으로 합성하기 위한 것이다. 이를 위하여 카리 장석을 주원료로, 그 이외에 탄산칼륨, 수산화알루미늄을 사용하여 화학 양론적인 조성으로 고상합성법을 이용하여 leucite 합성 실험을 하였다. 그 결과 leucite를 조화 용융으로 $950^{\circ}C$부터 고상법으로 합성되었다.