• Title/Summary/Keyword: Post curing

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Effect of Modification of SeO2/Acrylamide Ratios on Diffraction Efficiencies in PVA/AA Photopolymer Films

  • Kim, Dae-Heum;Lim, Ji-Yun;Nam, Seung-Woong;Chung, Dae-Won
    • Journal of the Optical Society of Korea
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    • v.11 no.4
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    • pp.183-191
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    • 2007
  • The highest diffraction efficiency(DE) value after illumination and post-curing of photopolymer films were obtained at the $SeO_2$/Acrylamide(AA) Ratios of AA 3.0 g, $SeO_2$ 1.0g and the DE's were stable values of over 90%. By the addition of $SeO_2$, the maximum DE at the initial stage of illumination was reached at 300 seconds, which suggests $SeO_2$ slows down the photopolymerization of AA, which enhances the maximum DE value by giving more migration time. DE variation curve for the optimum composition during extended-time illumination of 9,000 seconds resembles a sine curve due to the combination of the monomer diffusion and the photopolymerization, and the photopolymer film expanded by about 8% after photopolymerization due to monomer migration.

Evaluation of Mechanical Properties of Carbon Fabrics Composite with Thermal Shock (열 충격에 따른 탄소 직물 복합재료의 역학적 특성 평가)

  • Kim, Jae-Hong;Lee, Jung-Ho;Jung, Kyung-Ho;Kang, Tae-Jin
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2005.11a
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    • pp.79-82
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    • 2005
  • In this study, mechanical properties of carbon fabrics composite under the thermal shock cycling were evaluated. Due to the interactions between fiber and polymer matrix, it is reasonable to conclude that both thermal cycles of thermal shock result in improvement of interlaminar shear strength(ILSS) for the longer conditioning time duration. The rise in ILSS may be attributed to the improved adhesion by cryogenic compressive stress and also by the post-curing strengthening effect. However, the flexural and tensile strength were decreased with increasing conditioning time of thermal cycle.

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Techniques and Characteristics of Indirect Restorations

  • Cho, Kyung-Mo
    • Proceedings of the KACD Conference
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    • 2001.11a
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    • pp.593-593
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    • 2001
  • Esthetic restoration techniques can be categorized into "Direct techniques" consist only of intraoral procedures and "Indirect techniques" include intraoral as well as extraoral laboratory steps. Those made extraorally exhibit generally enhanced esthetic potential and anatomy and better hardness and wear resistance, indirect esthetic restorations numerously applied in contemporary dentistry. Indirect restorative materials can be divided into two categories; composite resin-based materials and ceramic-based materials. These materials shows various were resistance, modulus of elasticity, repair postenital, chemical stability, and different laboratory procedures. In this session, benefit of indirect techinques, case selection of this kind of restorations, and material characteristics and fabrication produre of those materials will ber reviewed; Targis, Sculpture, Belleglass, and Post-curing of restorative composite resins in resin-based materials; Dicor, Empress, Cerec, Celay, and conventional firing porcelain in ceramic based materials.

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The Application of Computer Simulation, Industrial CT and DLS RP for the rapid development of casting pilot models (신속한 주물 시제품 개발을 위한 전산모사 기술과 산업용 단층촬영기 및 쾌속표형기의 적용)

  • Yoo S.M.;Lim C.H.;Cho I.S.;Choi J.K.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2006.05a
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    • pp.195-196
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    • 2006
  • Direct laser sintering (DLS) technology for the resign coated sand is one of attractive technologies to produce molds and cores for the foundry industry rapidly and cost effectively. The objective of this case study is to develop casting pilot models using computer simulation technology, DLS RP machine and industrial computed tomography. The proposed casting design was verified by the Z-Cast software in the fields of fluid flow and solidification during the casting process. Casting parts with aluminum alloy using the post-curing treated sand moulds and cores are accurate to dimension and defect free.

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Reinforcement of Polychloroprene by means of Silia and Glass Fiber (Silica와 Glass Fiber에 의한 Polychloroprene의 보강(補强))

  • Yoo, Chong-Sun;Paik, Nam-Chul
    • Elastomers and Composites
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    • v.23 no.3
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    • pp.223-229
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    • 1988
  • The effect of triazine thiol derivative on the physical properties of silica-polychloroprene(CR) composites and glass fiber(MGF)-CR composites was investigated. Optimum cure time of the MGF composites filled with 2-dibuthylamino-4, 6-dithiol-s-triazine(DBT) was the fastest one, while maximum torque was the best in case of the silica composites filled with s-triazine-2,4,6-trithiol(TAT) on the Oscillating Disk Rheometer(ODR) test. Stress-strain curves of the composites showed that the physical properties such as 100% modulus, 300% modulus, tensile strength of the silica composites filled with DBT was very satisfactory and the silica composites filled with TAT was higher density of crosslinking than other crosslinked elastomer. In aging properties, elastomer filled DBT and TAT were progress post-curing reaction with increasing of aging time and it have been improved the tensile strength and crosslinking density.

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Comparative Study on the Failure of Polymer/Roughened Metal Interfaces under Mode-I Loading I: Experimental Result (인장하중하에서의 고분자/거친금속 계면의 파손에 대한 비교연구 I: 실험결과)

  • Lee Ho-Young;Kim Sung-Ryong
    • Korean Journal of Materials Research
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    • v.15 no.1
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    • pp.1-5
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    • 2005
  • Copper-based leadframe sheets were immersed in two kinds of hot alkaline solutions to form brown-oxide or black-oxide layer on the surface. The oxide-coated leadframe sheets were molded with epoxy molding compound (EMC). After post mold curing, the oxide-coated EMC-leadframe joints were machined to form sandwiched double-cantilever beam (SDCB) specimens. The SDCB specimens were used to measure the fracture toughness of the EMC/leadframe interfaces under quasi-Mode I loading conditions. Fracture surfaces were analyzed by various equipment to investigate failure path. The present paper deals with the failure path, and the cause of the failure path formation with an adhesion model will be treated in the succeeding paper.

Comparative Study on the Failure of Polymer/Roughened Metal Interfaces under Mode-I Loading II: Adhesion Model (인장하중하에서의 고분자/거친금속 계면의 파손에 대한 비교연구 II: 접착모델)

  • Lee Ho-Young;Kim Sung-Ryong
    • Korean Journal of Materials Research
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    • v.15 no.1
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    • pp.6-13
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    • 2005
  • Copper based leadframe sheets were immersed in two kinds of hot alkaline solutions to form brown-oxide or blackoxide layer on the surface. The oxide-coated leadframe sheets were molded with epoxy molding compound (EMC). After post mold curing, the oxide-coated EMC-leadframe joints were machined to form sandwiched double-cantilever beam (SDCB) specimens. The SDCB specimens were used to measure the fracture toughness of the EMC/leadframe interfaces under quasi-Mode I loading conditions. After fracture toughness testing, the fracture surface were analyzed by various equipment to investigate failure path. An adhesion model was suggested to explain the failure path formation. The adhesion model is based on the strengthening mechanism of fiber-reinforced composite. The present paper deals with the introduction of the adhesion model. The explanation of the failure path with the proposed adhesion model was introduced in the companion paper.

EVALUATION OF NONDESTRUCTIVE TESTS ANALYSIS TO ESTIMATE INPLACE STRENGTH OF CONCRETE

  • Parviz Ghoddousi;Mohsen Tadayon;Pedram H. Mojarad
    • International conference on construction engineering and project management
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    • 2005.10a
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    • pp.672-680
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    • 2005
  • There are a lot of reasons to use In-place tests. Construction schedules often require that operations such as form removal, post-tensioning, termination of curing, and removal of reshores be carried out as early as possible. To enable these operations to proceed safely as soon as possible requires the use of reliable in-place tests to estimate the in-place strength. In-place test results are not reliable for engineering judgment. These results should be interpreted and correlated to standard compressive strength, based on the test method. In this paper some of these test procedures and their limitations are discussed. In this study we will go on for Rebound number, Pullout, Ultrasonic pulse velocity, and Cast-in-place cylinder methods which are most useful methods in the Asia.

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A Study of Relations of Chain Lengths and Properties for Bifunctional linear DGEBF/Linear Amino (EDA, HMDA) Cure Systems (선형 이관능성 DGEBF/선형아민(EDA, HMDA) 경화계의 경화제 사슬길이와 물성과의 관계에 대한 연구)

  • Myung In-Ho;Lee Jae-Rock
    • Composites Research
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    • v.17 no.6
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    • pp.37-43
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    • 2004
  • To determine the effect of chain length and chemical structure of linear amine curing agents on thermal and mechanical properties, a standard bifunctional linear DGEBF epoxy resin was cured with EDA and HMDA having amine group at the both ends of main chain in a stoichiometrically equivalent ratio in condition of preliminary and post cure. From this work, the effect of linear amine curing agents on the thermal and mechanical properties is significantly influenced by numbers of carbon atoms of main chain. In contrast, the results show that the DCEBF/EDA system having two carbons had higher values in the thermal stability, density, shrinkage (%), grass transition temperature, tensile modulus and strength, flexural modulus and strength than the DGEBF/HMDA system having six carbons, whereas the DGEBF/EDA cure system had relatively low values in maximum ekothermic temperature, maximum conversion of epoxide, thermal expansion coefficient than the DGEBF/HDMA cure system. These findings indicate that the packing capability (rigid property) in the EDA structure affects the thermal and mechanical properties predominantly. It shows that flexural fracture properties have a close relation to flexural modulus and strength.

A Study on the Preocessing of high Runctional Composites and the Evaluation of Its Characteristics (고기능성 복합재료의 제조와 그 특성평가에 관한 연구)

  • 김윤해
    • Journal of Advanced Marine Engineering and Technology
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    • v.22 no.2
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    • pp.139-145
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    • 1998
  • Filament winding method is widely used for composite fabrications using low viscosity liquid for-mation and processing asymmetrical structures of pressure vessel pipe rocket motor case etc. The filament winding method is affected by several parameters such as pot life of process time viscosi-ty of resin filament winding temperature and schedules curing condition and post curing condi-tion of resin. To develope high functional composite materials the rotation(5, 15, 20, 30rpm) of the winding machine was controlled by D.C motor. And the wiper to give proper tension was equipped between strand and resin bath. The resin is hooked by the design wiper. The adequate cure schedule was found by DSC. NOL ring test is carried out to investigate the basic physical properties such as design technology. The void contents in filament winding is generally higher than that of the prepreg laminated plate. These high contents of void can make a crack in resin in spite of low deformation. These problem was solved by giving tension in processing. To improve the characteristics of fiber volume fraction void contents resin/fiber bonding the winding speedc is changed under constant tension. It was found that resin impregnation was not different from in fiber contents void contents at the range of 0.5~1kg tension but it was found that resin was not impregnated at the above of 1.5kg tension. In burst test a pure PE liner was failed at a nozzle part under the $14kg/\textrm{cm}^2$ pressure but a pressure vessel of CNG was failed at a cylinder part under the $200kg/\textrm{cm}^2$ pressure.

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