• 제목/요약/키워드: Positional

검색결과 1,043건 처리시간 0.028초

The Positional Effect of Solute Functional Group among Positional Isomers of Phenylpropanol in Hydroxyl Group-Solvent Specific Interactions in Methanol/Water Mixed Solvents Monitored by HPLC

  • Cheong, Won-Jo;Ko, Joung-Ho;Kang, Gyoung-Won
    • Bulletin of the Korean Chemical Society
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    • 제26권8호
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    • pp.1246-1250
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    • 2005
  • We have evaluated the hydroxyl group-solvent specific interactions by using a Lichrosorb RP18 stationary phase and by measuring the retention data of carefully selected solutes in 50/50, 60/40, 70/30, 80/20, and 90/10(v/v%) methanol/water eluents at 25, 30, 35, 40, 45, and 50 ${^{\circ}C}$. The selected solutes are 3 positional isomers of phenylpropanol, that is, 1-phenyl-1-propanol, 1-phenyl-2-propanol, and 3-phenyl-1-propanol. There exist clear discrepancies in ${\Delta}H^o$ (solute transfer enthalpy from the mobile to the stationary phase) and $T{\Delta}S^o$ (solute transfer entropy) among positional isomers. The difference in ${\Delta}H^o$ and $T{\Delta}S^o$ between secondary alcohols (1-phenyl-1-propanol and 1-phenyl-2-propanol)is negligible compared to the difference between the primary alcohol (1-phenyl-3-propanol) and secondary alcohols. The $T{\Delta}S^o$ values of 3-phenyl-1-propanol are close to those of butylbenzene while the $T{\Delta}S^o$ values of secondary alcohols are close to those of propylbenzene. The difference in ${\Delta}{\Delta}H^o$ (specific solute-mobile phase interaction enthalpy) between the primary alcohol and the secondary alcohol decreases with increase of methanol content in the mobile phase. A unique observation is an extremum for 1-phenyl-3-propanol in the plot of $T{\Delta}{\Delta}S^o$ vs. methanol volume %. The positive sign of $T{\Delta}{\Delta}S^o$ of 3-phenyl-1-propanol implies that the entropy of 3-phenyl-1-propanol is greater than that of the hypothetical alkylbenzene (the same size and shape as phenylpropanol) in the mobile phase.

Validation and selection of GCPs obtained from ERS SAR and the SRTM DEM: Application to SPOT DEM Construction

  • Jung, Hyung-Sup;Hong, Sang-Hoon;Won, Joong-Sun
    • 대한원격탐사학회지
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    • 제24권5호
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    • pp.483-496
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    • 2008
  • Qualified ground control points (GCPs) are required to construct a digital elevation model (DEM) from a pushbroom stereo pair. An inverse geolocation algorithm for extracting GCPs from ERS SAR data and the SRTM DEM was recently developed. However, not all GCPs established by this method are accurate enough for direct application to the geometric correction of pushbroom images such as SPOT, IRS, etc, and thus a method for selecting and removing inaccurate points from the sets of GCPs is needed. In this study, we propose a method for evaluating GCP accuracy and winnowing sets of GCPs through orientation modeling of pushbroom image and validate performance of this method using SPOT stereo pair of Daejon City. It has been found that the statistical distribution of GCP positional errors is approximately Gaussian without bias, and that the residual errors estimated by orientation modeling have a linear relationship with the positional errors. Inaccurate GCPs have large positional errors and can be iteratively eliminated by thresholding the residual errors. Forty-one GCPs were initially extracted for the test, with mean the positional error values of 25.6m, 2.5m and -6.1m in the X-, Y- and Z-directions, respectively, and standard deviations of 62.4m, 37.6m and 15.0m. Twenty-one GCPs were eliminated by the proposed method, resulting in the standard deviations of the positional errors of the 20 final GCPs being reduced to 13.9m, 8.5m and 7.5m in the X-, Y- and Z-directions, respectively. Orientation modeling of the SPOT stereo pair was performed using the 20 GCPs, and the model was checked against 15 map-based points. The root mean square errors (RMSEs) of the model were 10.4m, 7.1m and 12.1m in X-, Y- and Z-directions, respectively. A SPOT DEM with a 20m ground resolution was successfully constructed using a automatic matching procedure.

후반고리관 양성돌발두위현훈의 치료에서 재평가 시기에 대한 피로 현상의 영향 (Influence of Fatigability on the Timing of Reassessment in the Treatment of Posterior Canal Benign Paroxysmal Positional Vertigo)

  • 김창희;신정은;신용국;송미현;심대보
    • Korean Journal of Otorhinolaryngology-Head and Neck Surgery
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    • 제61권12호
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    • pp.658-662
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    • 2018
  • Background and Objectives The early assessment of treatment is not done for benign paroxysmal positional vertigo (BPPV) since the well-known phenomenon of fatigability after a repeated positional test can mimic successful treatment. The aim of this study is to evaluate the clinical implication of 'fatigability' after Epley maneuver and to identify the therapeutic efficacy of Epley maneuver in posterior canal BPPV (PC-BPPV). Subjects and Method This study was prospectively conducted by two dizziness clinics on 51 consecutive patients diagnosed with PC-BPPV. All patients included in the study received Epley maneuver treatment. The therapeutic results were reassessed immediately after a single trial of Epley maneuver. After 30 minutes, results were reassessed repeatedly to confirm the fatigability of diagnostic procedure immediately after treatment. If the treatment was not successful after 30 minutes, Epley maneuver was repeatedly performed until complete resolution. Results Immediately after the first maneuver, 45 of 51 (88.2%) patients had neither vertigo nor nystagmus during the positional test. All patients demonstrated complete resolution after receiving one to three Epley maneuvers on the day of diagnosis. 'Fatigability (false negative result)' was confirmed for only one case (1 of 6 patients, 16.7%), in which nystagmus was observed after 30 minutes but not identified immediately after the first Epley maneuver. Conclusion The therapeutic efficacy of Epley maneuver is very high in PC-BPPV. Considering the possibility of fatigability when reassessment is performed immediately after therapeutic maneuver, clinicians should avoid assessing the outcome immediately after treatment in patients with PC-BPPV.

한국어 음소결합확률 계산기 개발연구 (A Study of Development for Korean Phonotactic Probability Calculator)

  • 이찬종;이현복;최훈영
    • 한국음향학회지
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    • 제28권3호
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    • pp.239-244
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    • 2009
  • 본 연구는 현대 한국어 단어의 말소리가 결합하는 음소결합확률 (Phonotactic Probability)을 예측하는 계산기 엔진 개발에 관한 연구이다. 한국어 음소결합확률계산기 (이하, KPPC)는 첫째로, 한국어의 주어진 단어에서의 음소와 그 음소의 음소결합의 빈도를 예측하여 말소리가 단어내의 특정위치에서 특정 분절음이 나타나는 빈도 값, 두 음소간의 결합의 빈도값, 그리고 세 음소간의 결합의 빈도 출현률을 예측하여 계산한다. 둘째로 한국어의 주어진 단어에서 말소리 하나만 다르면서 실제로 존재할 수 있는 근접밀도 (neighborhood density)의 값을 계산한다. University of Kansas에서 개발된 음소결합계산기는 영어 20,000단어의 D/B를 대상으로 위치별 분절음빈도와 두 음소간의 음소결합률 빈도를 컴퓨터가 읽을 수 있는 발음기호를 통해서만 가능하다. 본 연구에서는 분절음빈도와 두 음소간의 빈도뿐만 아니라 세 음소간의 결합률 빈도와 근접밀도율을 예측할 수 있고 입력할 때 발음기호뿐만 아니라 단어를 입력하면 확률값을 얻을 수 있다. 이 엔진은 67,284단어의 한국어 표준발음을 D/B로 구축하여 고빈도 음소결합확률, 저빈도 음소결합확률, 고빈도 근접밀도, 저빈도 근접밀도의 값을 예측할 수 있다.

The Prevalence and Characteristics of Positional Obstructive Sleep Apnea

  • Kim, Cheon-Sik;Lee, Yong-Seok;Cho, Cheon-Ung;Pae, Sang-Ho;Lee, Sang-Ahm
    • 대한임상검사과학회지
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    • 제44권2호
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    • pp.52-58
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    • 2012
  • Patients with obstructive sleep apnea (OSA) often have more aggravated symptoms in the supine position. We tried to investigate the clinical characteristics and the predictive factors for positional OSA. Polysomnographic data were reviewed for OSA patients (apnea hypopnea index, $AHI{\geq}5$) from April, 2008 to April, 2011 at the Asan Medical Center. Clinical data, comorbid medical condition data and questionnaires (SF-36, MFI-20, ESS, BDI, STAI) were assessed. All patients were classified into two groups: positional patients (PP) group and non-positional patients (NPP) group. PP was defined as a patient who had the AHI in the supine position was at least twice as high as that in the lateral position. The body position of patients was confirmed by sleep position sensor and video monitor. All patients had at least 30 minutes of positional and 30 minutes of non-positional sleep. We compared clinical, medical, polysomnographic data, and questionnaire results between two (PP and NPP) groups and investigated predictive factors for the PP group using binary logistic regression analysis. In total, 371 patients were investigated. 265 (71.4%) was categorized as PP group and 106 (28.5%) as NPP group. The mean age ($mean{\pm}SD$) was higher in the PP group ($52.4{\pm}9.8$) than in the NPP group ($49.5{\pm}11.9$) (p<0.05). Comparison of sleep parameters between the PP and the NPP group showed that the PP group had significantly lower BMI (PP: $26.1{\pm}3.2kg/m^2$; NPP: $27.8{\pm}4.3kg/m^2$, p<0.001), neck circumference (PP: $39.7{\pm}2.8cm$; NPP: $41.5{\pm}3.7cm$, p<0.001) and hypertension rate (PP: n=89/265 (33.5%); NPP: n=48/106 (45.2%), p=0.0240). In the PP group, the percentage of deep sleep (PP: $8.7{\pm}8.1%$; NPP: $5.6{\pm}7.0%$, P=0.001) and rapid eye movement (REM) (PP: $17.5{\pm}6.1%$; NPP: $14.0{\pm}6.9%$, p<0.001) were significantly higher whereas the percentage of light sleep (stage N1) was significantly lower than the NPP group (PP: $30.4{\pm}12.3$; NPP: $44.5{\pm}20.8%$, p<0.001). During the sleep, the AHI in the supine position (PP: $48.6{\pm}19.5$; NPP: $60.5{\pm}22.6$, p<0.001) and in the non-supine position (PP: $9.4{\pm}8.9$; NPP: $48.4{\pm}24.8$, p=<0.001) were significantly lower and the minimal arterial oxygen saturation in non-REM sleep was significantly higher in the PP group (PP: $80.3{\pm}7.6$; NPP: $75.1{\pm}9.9$, p=<0.001). There were no significant differences in all questionnaires including quality of life. The results of the binary logistic regression analysis showed that age, the amount of REM sleep(%) and AHI were significant predictive factors for positional OSA. The significant predictive factors for positional OSA were older age, higher percentage of REM and lower AHI. The questionnaire results were not significantly different between the two groups.

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두위 현훈에 대한 괄법(刮法) 복합치료 효과 (Effect of Scratching Method Complex Therapy on the Patients with Positional Vertigo)

  • 김경태;송호섭
    • Journal of Acupuncture Research
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    • 제29권4호
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    • pp.1-6
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    • 2012
  • Objectives : This study was done for reporting the effect of scratching method on patients with positional vertigo. Methods : We investigated 22 cases of patients with dizziness, and devided patients into two groups : We treated one group by complex oriental medical treatment with scratching method therapy, and did the other group by complex oriental medical treatment without scratching method therapy. Korean version of dizziness handicap inventory at baseline and final were used for evaluating the effect of the treatment. Results : 1. In scratching method group and non-scratching method group, compared with baseline, at final, Korean version of dizziness handicap inventory was significantly decreased. 2. At final, scratching method group showed significant decrease on Korean version of dizziness handicap inventory compared with non-scratching method group. Conclusions : Scratching method showed significant improvement in dizziness.

공작기계용 리니어모터의 운동성능 평가에 관한 연구 (A Study on Performance of Linear Motor for Machine Tools)

  • 최헌종;강은구;정일용;이석우
    • 한국공작기계학회:학술대회논문집
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    • 한국공작기계학회 2002년도 춘계학술대회 논문집
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    • pp.215-220
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    • 2002
  • Recently, linear motor has been developed for linear motion of machine tools. Linear motor is useful to design the linear motion, high speed and high accuracy, because of the simple system not required the additional mechanical part such as coupling and ballscrew. This paper tested performance of linear motor relevant to motioning and positioning table such as F.R.F., step response and positional accuracy Linear motion system using linear motor requires the effective cooling system because it cause to decrease the positional error and to protect the motor coil. Therefore the positional error measurement was made to evaluate the effect of the temperature variation.

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Development of a hazard map creation support system with community participation type using positional information

  • Mori, Seina;Okazaki, Yasuhisa;Wakuya, Hiroshi;Mishima, Nobuo;Hayashida, Yukuo;Min, Byung-Won
    • 한국콘텐츠학회:학술대회논문집
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    • 한국콘텐츠학회 2015년도 춘계 종합학술대회 논문집
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    • pp.11-12
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    • 2015
  • This paper describes development of a system that can create a hazard map by residents in order to prepare for disaster in daily life. This system make a hazard map by displaying the community-based disaster information on the map. Residents register information about the spot (a disaster type, a risk level, a photo, comments, positional information) that can be dangerous in case disaster. We think that residents can share information while having fan and increase disaster prevention consciousness by resident participation activities.

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자세변화에 따른 현훈(眩暈)을 주소증으로 한 태음인(太陰人)환자 치험 3례 (Three Cases of Taeumin Patients Suffering from Positional Vertigo)

  • 이정환;서은희;하진호;초재승;구덕모
    • 사상체질의학회지
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    • 제19권1호
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    • pp.193-202
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    • 2007
  • 1. Objectives These cases are to report that Taeumin patients suffering from positional vertigo treated by Constitutional medications. 2. Methods These patients were treated by Taeumin's Constitutional medications and acupuncture treatment according to the result of Sasang Constitutional diagnosis. We used Visual analogue scale(VAS) for the assessment of vertigo. 3. Results & Conclusions Three patients have been suffering from Positional Vertigo were treated by Taeumin's Constitutional medications(especially Taeumjowi-tang and Jowisungcheng-tang) and showed positive responses about their problems.

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웨이블릿 계수와 Dynamic Positional Warping을 통한 EOG기반의 사용자 독립적 시선인식 (EOG-based User-independent Gaze Recognition using Wavelet Coefficients and Dynamic Positional Warping)

  • 장원두;임창환
    • 한국멀티미디어학회논문지
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    • 제21권9호
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    • pp.1119-1130
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    • 2018
  • Writing letters or patterns on a virtual space by moving a person's gaze is called "eye writing," which is a promising tool for various human-computer interface applications. This paper investigates the use of conventional eye writing recognition algorithms for the purpose of user-independent recognition of eye-written characters. Two algorithms are presented to build the user-independent system: eye-written region extraction using wavelet coefficients and template generation. The experimental results of the proposed system demonstrated that with dynamic positional warping, an F1 score of 79.61% was achieved for 12 eye-written patterns, thereby indicating the possibility of user-independent use of eye writing.