• Title/Summary/Keyword: Porous fiber

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Porous Ceramic Fibers: Materials and Applications

  • Kim, Il-Du
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.10a
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    • pp.4-4
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    • 2011
  • Extensive research efforts are directed toward the development of highly sensitive gas sensors using novel nanostructured materials. Among the different strategies for producing sensor devices based on nanosized building blocks, polymeric fiber templating approach which is combined by chemical and physical synthesis routes was attracted much attention. This unique morphology increases the surface area and reduces the interfacial area between film and substrate. Consequently, the surface activity is markedly enhanced while deleterious interfacial effects between film and substrate are significantly reduced. Both effects are highly advantageous for gas sensing applications. In this presentation, facile synthesis of hollow and porous metal oxide nanostructures and their applications in chemical sensors will be discussed.

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Preparation of PVDF Hollow Fiber Membrane via TIPS (Thermally Induced Phase Separation) and Stretching (열유도 상분리와 연신공정을 이용한 PVDF 중공사막의 제조)

  • Park, Minsoo;Kim, Jinho;Jang, Moonseog;Kim, Sung Soo
    • Membrane Journal
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    • v.24 no.2
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    • pp.158-166
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    • 2014
  • In this research, microporous and bicontinuous poly vinylidene fluoride(PVDF) hollow fiber membranes were prepared via hybrid process of the thermally induced phase separation (TIPS) and stretching method. The mechanism of the membrane preparation is based on liquid-liquid phase separation. The final membranes have characteristic structures which have both bicontinuous and fibrillar morphology by applying the stretching method. They showed quite different structure when compared with the spherulitic or nodular structure from S/L TIPS and bicontinuous structure from L/L TIPS. At first, PVDF hollow fiber precursors were prepared via TIPS method using various kind of diluent mixtures. We used gamma-butyrolacton, dimethyl phthalate (DMP), diethyl phthalate (DEP), dibutyl phthalate (DBP) as diluents. We could make hollow fiber membranes which had porous outer surface or dense outer surface by controling the parameters such as cooling conditions, PVDF concentration and the ratio of diluent mixtures. Finally, these hollow fiber were stretched at room temperature and diluents were extracted by ethanol. Effects of the stretching ratio on the membrane morphology were investigated using scanning electron microscope (SEM), and its effects on water flux, porosity, pore size, roughness and tensile strength were examined.

Anatomical Features Affecting Safranine Solution Permeability in Anthocephalus chinensis (Lam.) Rich. ex Walp

  • Ahmed, Sheikh Ali;Chun, Su-Kyoung
    • Journal of the Korea Furniture Society
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    • v.18 no.4
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    • pp.261-267
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    • 2007
  • This report describes the wood anatomy and 1% safranine solution penetration depth in radial and longitudinal directions of Anthocephalus chinensis belonging to the family Rubiaceae native to Bangladesh. The wood of this species was mostly characterized by diffuse porous, vessel with simple perforation plate, vestured alternate intervessel pittings, relatively medium vessel elements and fiber, and nonseptate fiber with distinctly bordered pits at radial wall. The body ray cell was procumbent with 2 to over 4 rows of upright and square marginal cells. Sometimes, the rays with procumbent, square and upright cells were mixed. Latewood fiber was thin to thick walled while it was very thin walled in earlywood. Axial parenchyma was diffuse, vasicentric, 5-8 cells per parenchyma strand dominantly present. Liquid penetration depth was observed in radial and longitudinal directions at moisture level of 7.42%. Longitudinal penetration was found 6.3 times higher than radial penetration. The initial penetration rate of safranine solution was high, but gradually decreased during the course of time. Different anatomical features were found to be responsible for the variation of safranine solution penetration depth compared to Gmelina arborea.

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Preparation of Hydrophobic Porous PVDF Membrane and Application for Membrane Distillation (소수성 다공질 PVDF 중공사 분리막 제조 및 막증류 적용)

  • Min, Ji Hee;Park, Min Soo;Kim, Jinho
    • Membrane Journal
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    • v.24 no.3
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    • pp.240-248
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    • 2014
  • Porous PVDF hollow fiber membranes were prepared by hybrid process of TIPS(thermally induced phase separation) and stretching for membrane distillation. The tests were conducted to investigate that permeability of the membrane could be enhanced by reducing membrane wall thickness. During fiber spinning, dope discharge rate from nozzle was reduced and flow rate of bore fluid increased to make the wall thickness thinner. As dope discharge rate from nozzle was reduced and flow rate of bore fluid increased, the membrane wall thickness was reduced. As a result, air permeability, water permeability and vapor permeability of the membranes increased.

Preparation of Porous Carbon Fiber by Using MgO Powder and Its Characteristics of Catalysts for Fuel Cell (MgO를 이용한 다공성 탄소 섬유 제조 및 이를 이용한 연료전지용 촉매 특성)

  • Nam, Kidon;Kim, Sang-Kyung;Lim, Seongyop;Peck, Donghyun;Lee, Byoungrok;Jung, Doohwan
    • Korean Chemical Engineering Research
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    • v.46 no.6
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    • pp.1142-1147
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    • 2008
  • Nano-structured porous carbon fiber(PCF) for the catalyst supports of the direct methanol fuel cell (DMFC) were prepared from the mesophase pitch by using the nano-MgO powders. Specific surface area of the PCFs was $8{\sim}58m^2/g$ and surface pore structures had almost meso pore diameter of 10~20 nm which were depending on the amount of MgO spheres. Aqueous reduction method was used to load 60 wt% PtRu on the prepared PCF supports. The electro-oxidation activity and single cell performance of the 60 wt% Pt-Ru catalysts were measured by cyclic voltammetry and unit cell test. The performances of these catalysts increased by 5~10% compared with one of commercial catalyst.

A High Birefringent Polymer Terahertz Waveguide: Suspended Elliptical Core Fiber

  • Wang, Jingli;Chen, Heming;Shi, Weihua
    • Journal of the Optical Society of Korea
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    • v.18 no.5
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    • pp.453-458
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    • 2014
  • A novel high birefringent polymer terahertz (THz) fiber with a suspended elliptical core is proposed in this paper. The introduction of an elliptical core can enhance asymmetry to realize high mode birefringence, and a large porous outer cladding effectively isolates the core-guided mode from interacting with the surrounding environment. A full-vector finite element method(FEM) is used to analyze the characteristics of the THz fiber. Simulation results show that the suspended elliptical fiber exhibits high mode birefringence on a level of $10^{-2}$ over a wide frequency range, and an extremely large mode birefringence(${\approx}0.06226$) is obtained when ellipticity is 0.2. Moreover, a suspended hollow elliptical core fiber is also discussed for the purpose of lower loss, however high mode birefringence and low relative absorption loss can not coexist in such a kind of fiber.