• Journal of the Korea institute for structural maintenance and inspection
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• v.23 no.7
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• pp.1-8
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• 2019

The primary purposes of this study are to understand a fundamental effects of electro-deposition on reinforcing steel in saturated Ca(OH)2 electrolyte, and evaluate the corrosion rates of rebars under cyclic 3wt.%NaCl immersion and dry corrosion environment. The three cement mortar specimens with cover thickness 5, 10 and 30mm, were prepared in the experiment. To monitor the corrosion rates of rebars in mortar, the three cement mortar specimens were exposed to 110 wet-drying cycles(8-hour-immersion in 3wt.%NaCl and 16-hour-drying in a room temperature) in the laboratory. During the wet-dry cycles, the polarization resistance, Rp, and solution resistance, Rs, were continuously measured. The instantaneous corrosion rates of rebars on the effect of electro-depositing with sat. Ca(OH)2 electrolyte were estimated from obtained R-1p and degrees of wetness were estimated from Rs values. From the experimental results, the corrosion rates of rebars were greatly accelerated by wet/dry cycles. During the mortars exposed to drying condition, the large increases in the corrosion rates were showed at all rebar surfaces in three mortar specimen, attributed from the accelerated reduction rates of dissolved oxygen in drying process. However, the corrosion rates on rebar surface electrochemically deposited with sat. Ca(OH)2 electrolyte showed the clear decreases, caused by calcium deposits in the porous rust layer.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.22 no.6
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• pp.305-311
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• 2012

In order to recycle the coal bottom ashes (denoted as BA) produced from a thermal power plant, the artificial aggregates (denoted as AAs) containing BA and red clay were manufactured, and the physical properties of AAs were studied as a function of particle size of BA and batch compositions. As-received BA had 38 wt% coarse particles of above 2 mm and many unburned carbon mass and porous slag particles were co-existed. So the two particle sizes of BA, the fine (< 100 ${\mu}m$) and coarse (< 2 mm), were prepared by milling and screening process. The AAs containing fine BA sintered at $1100{\sim}1200^{\circ}C$ had the higher bulk density and lower water absorption compared to the specimen made of coarse BA. The inside core of AAs manufactured by using coarse BA showed nonuniform and porous microstructure, while the AAs made of fine BA had a uniform and dense microstructure. In this research, the AAs containing BA and red clay with various bulk density (1.2~1.7) and water absorption (13~21 %) could be manufactured by controlling the particle size of BA and batch compositions, so the AAs of various physical properties could be applied to the wide fields such as construction/building materials in near future.

• Tunnel and Underground Space
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• v.13 no.6
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• pp.465-475
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• 2003

Groundwater inflow into the caverns constructed in fractured rock mass was simulated by numerical modeling, NAPSAC (DFN, discrete fracture network model) and NAMMU (CPM, continuous porous media model), a finite-element software package for groundwater flow in 3D fractured media developed by AEA Technology, UK. The input parameters for modeling were determined on surface fracture survey, core logging and single hole hydraulic test data. In order to predict the groundwater inflow more accurately, the anisotropic hydraulic conductivity was considered. The anisotropic hydraulic conductivities were calculated from the fracture network properties. With a minor adjustment during model calibration, the numerical modeling is able to reproduce reasonably groundwater inflows into cavern and the travel length and times to the ground surface along the flow paths in the normal, dry and rainy seasons.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.7 no.3
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• pp.111-119
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• 1987

Scale effects of stability, run-up, run-down and reflection of layered coastal structures are investigated through the experiments with 7 kinds of hydraulic scale models. The occurrence mechanism and the control method of scale effects are also discussed. As a result, it is found that the similarity of permeability of inner layers plays an important role in the occurrence of scale effects, which has been neglected in the most of conventional model tests. To assure the best scale effects for permeable coastal structures, control of Reynolds numbers of the porous media flow in each layer is recommended. It is also found that Reynolds numbers in revetment, filter, and core layer must be greater than $2{\times}10^4$, $3{\times}10^3$, and $1{\times}10^3$, respectively.

• Proceedings of the Materials Research Society of Korea Conference
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• 2012.05a
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• pp.58.2-58.2
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• 2012

Heavy hydrocarbon reforming is a core technology for "Dirty energy smart". Heavy hydrocarbons are components of fossil fuels, biomass, coke oven gas and etc. Heavy hydrocarbon reforming converts the fuels into $H_2$-rich syngas. And then $H_2$-rich syngas is used for the production of electricity, synthetic fuels and petrochemicals. Energy can be used efficiently and obtained from various sources by using $H_2$-rich syngas from heavy hydrocarbon reforming. Especially, the key point of "Dirty energy smart" is using "dirty fuel" which is wasted in an inefficient way. New energy conversion laboratory of KAIST has been researched diesel reforming for solid oxide fuel cell (SOFC) as a part of "Dirty energy smart". Diesel is heavy hydrocarbon fuels which has higher carbon number than natural gas, kerosene and gasoline. Diesel reforming has difficulties due to the evaporation of fuels and coke formation. Nevertheless, diesel reforming technology is directly applied to "Dirty fuel" because diesel has the similar chemical properties with "Dirty fuel". On the other hand, SOFC has advantages on high efficiency and wasted heat recovery. Nippon oil Co. of Japan recently commercializes 700We class SOFC system using city gas. Considering the market situation, the development of diesel reformer has a great ripple effect. SOFC system can be applied to auxiliary power unit and distributed power generation. In addition, "Dirty energy smart" can be realized by applying diesel reforming technology to "Dirty fuel". As well as material developments, multidirectional approaches are required to reform heavy hydrocarbon fuels and use $H_2$-rich gas in SOFC. Gd doped ceria (CGO, $Ce_{1-x}Gd_xO_{2-y}$) has been researched for not only electrolyte materials but also catalysts supports. In addition, catalysts infiltrated electrode over porous $La_{0.8}Sr_{0.2}Ga_{0.8}Mg_{0.2}O_3-{\delta}$ and catalyst deposition at three phase boundary are being investigated to improve the performance of SOFC. On the other hand, nozzle for diesel atomization and post-reforming for light-hydrocarbons removal are examples of solving material problems in multidirectional approaches. Likewise, multidirectional approaches are necessary to realize "Dirty energy smart" like reforming "Dirty fuel" for SOFC.

• Bulletin of the Korean Chemical Society
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• v.31 no.12
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• pp.3593-3599
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• 2010

In an original effort, this lab attempted to employ polystyrene nanoparticles as a template for the synthesis of ordered and highly porous macroporous $SiO_2$ thin films, utilizing their high combustion temperature and narrow size distribution. However, polystyrene nanoparticle thin films were not obtained due to the low interaction between individual particles and between the particle and silicon substrate. However, polystyrene-polyacrylic acid (PS-AA) colloidal particles of a core-shell structure were synthesized by a one-pot miniemulsion polymerization approach, with hydrophilic polyacrylic acid tails on the particle surface that improved interaction between individual particles and between the particle and silicon substrate. The PS-AA thin films were spin-coated in the thickness ranges from monolayer to approximately $1.0\;{\mu}m$. Using the PS-AA thin films as sacrificial templates, macroporous $SiO_2$ thin films were successfully synthesized by vapor deposition or conventional solution sol-gel infiltration methods. Inspection with field emission scanning electron microscopy (FE-SEM) showed that the macroporous $SiO_2$ thin films consist of interconnected air balls (~100 nm). Typical macroporous $SiO_2$ thin films showed ultralow refractive indices ranging from 1.098 to 1.138 at 633 nm, according to the infiltration conditions, which were confirmed by spectroscopy ellipsometry (SE) measurements. This research shows how the synthetic control of the macromolecule such as hydrophilic polystyrene nanopaticles and silicate sol precursors innovates the optical properties and processabilities for actual applications.

• Steel and Composite Structures
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• v.36 no.1
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• pp.1-16
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• 2020

In steel-concrete composite beams, to improve the cracking resistance of the concrete slab in the hogging moment region, a new type of connector in the interface, named uplift-restricted and slip-permitted screw-type (URSP-S) connector has been proposed. This paper focuses on the behavior of steel-concrete composite beams with URSP-S connectors. A total of three beam specimens including a simply supported beam with URSP-S connectors and two continuous composite beams with different connectors arrangements were designed and tested. More specifically, one continuous composite beam was equipped with URSP-S connectors in negative moment region and traditional shear studs in other regions. For comparison, the other one was designed with only traditional shear studs. The failure modes, crack evolution process, ultimate capacities, strain responses at different locations as well as the interface slip of the three tested specimens were measured and evaluated in-depth. Based on the experimental study, the research findings indicate that the larger slip deformation is allowed while using URSP-S connectors. Meanwhile, the tensile stress reduces and the cracking resistance of the concrete slab improves accordingly. In addition, the overall stiffness and strength of the composite beam become slightly lower than those of the composite beam using traditional shear studs. Moreover, the arrangement suggestion of URSP-S connectors in the composite beam is discussed in this paper for its practical design and application.

• Korean Journal of Metals and Materials
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• v.49 no.8
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• pp.596-600
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• 2011

Thermal degradation behavior of a $WO_3-TiO_2$ monolithic catalyst was investigated in terms of structural, morphological, and physico-chemical analyses. The catalyst with 4 wt.% $WO_3$ contents were prepared by a wet-impregnation method, and a durability test of the catalysts were performed in a temperature range between $400^{\circ}C$ and $800^{\circ}C$ for 3 h. An increase of thermal stress decreased the specific surface area, which was caused by grain growth and agglomeration of the catalyst particles. The phase transition from anatase to rutile occurred at around $800^{\circ}C$ and a decrease in the Brønsted acid sites was confirmed by structural analysis and physico-chemical analysis. A change in Brønsted acidity can affect to the catalytic efficiency; therefore, the thermal degradation behavior of the $WO_3-TiO_2$ catalyst could be explained by the transition to a stable rutile phase of $TiO_2$ and the decrease of specific surface area in the SCR catalyst.

• Composites Research
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• v.33 no.6
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• pp.408-414
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• 2020

The present engineering sector focused on the sandwich composites and almost covered all engineering fields because of decent mechanical properties with a lightweight structure. It mainly consists of high strength fiber skin and porous structure core like corrugated, honeycomb, balsa wood, and foams which is playing a pivotal role in weight reduction. Recently researchers attention grabbed by Natural fiber sandwich composites due to biodegradability, renewable, low-cost, and environmentally friendly. However special focus is highly needed towards the flammability behavior of natural fibers used as reinforcement for composites. Herein, for the first time, the flame retardant natural fiber sandwich composite was fabricated by using flame retardant treated bamboo fabric and vinyl ester via the VARTM process. The impact of flame retardant treated bamboo fabric on mechanical and flame retardant properties were studied. The results concluded that the fabricated bamboo sandwich composites show structurally lightweight with significant mechanical strength and feasibility with respect to the flame.

• Structural Engineering and Mechanics
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• v.85 no.3
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• pp.289-304
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• 2023

The main objective of this paper is to study the effect of porosity on the buckling behavior of thick functionally graded sandwich plate resting on various boundary conditions under different in-plane loads. The formulation is made for a newly developed sandwich plate using a functional gradient material based on a modified power law function of symmetric and asymmetric configuration. Four different porosity distribution are considered and varied in accordance with material propriety variation in the thickness direction of the face sheets of sandwich plate, metal foam also is considered in this study on the second model of sandwich which containing metal foam core and FGM face sheets. New quasi-3D high shear deformation theory is used here for this investigate; the present kinematic model introduces only six variables with stretching effect by adopting a new indeterminate integral variable in the displacement field. The stability equations are obtained by Hamilton's principle then solved by generalized solution. The effect of Pasternak and Winkler elastic foundations also including here. the present model validated with those found in the open literature, then the impact of different parameters: porosities index, foam cells distribution, boundary conditions, elastic foundation, power law index, ratio aspect, side-to-thickness ratio and different in-plane axial loads on the variation of the buckling behavior are demonstrated.