• Title/Summary/Keyword: Porous Ti

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Synthesis of TCO-less Solar Cell using Metal Mesh Type Electrode and its Photovoltaic Characteristics (금속 메쉬 전극을 이용한 TCO-less 광전변환소자 제작 및 광전변환 특성)

  • Park, Min-Woo;Sung, Youl-Moon
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.25 no.2
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    • pp.126-130
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    • 2011
  • Transparent conductive oxide (TCO) is an important part in the construction of dye-sensitized solar cells (DSCs) because of its low sheet resistance, sufficient light transparent ability and high photoelectrical response as a porous photo-electrode material of DSCs. However, the use of TCO for the two DSC electrodes can result in significant cost increase for the less effective DSCs compared to Si based solar cell. Therefore, the replacement of TCO is required for the commercial production of DSCs. In this study, TCO electrodes are replaced by stainless steel mesh. The 3.44[%] efficiency of the prepared TCO-less DSCs sample was obtained.

A Study on the ZnO Supported Silica Gel (ZnO가 담지된 실리카 겔 연구)

  • Kim, S.Y.;Kim, M.Y.;Ju, C.S.
    • Journal of Power System Engineering
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    • v.15 no.4
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    • pp.75-78
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    • 2011
  • There are various types of materials used in electronic industry, such as electrode material, conductor, insulator, anode, cathode and semiconductor. Electrode material type is Cu, Ti, ZnO and so on. Especially if we use mixed ZnO in soil cement or silica gel, we can have advantages in ice road to prevent freezing. We have great impact if we use supported in inorganic substances like silica gel. In this paper we have studied that ZnO supported silica gel and its properties. Zinc acetate dissolved in distilled water were loaded on the silica gel by the reaction with ammonia at $80^{\circ}C$. And we investigated particle structures of ZnO by scanning electron microscopy(SEM) and X-ray diffraction(XRD).

A Study on the Humidity Sensitive Characteristics of Perovskite-type Oxides Containing Alkaline Earth Ions (알칼리토족 이온을 함유한 페로브스카이트형 산화물의 감습특성에 관한 연구)

  • Yuk, J.H.;Lee, N.H.;Kang, D.H.;Han, S.O.;Park, K.H.;Lee, D.C.
    • Proceedings of the KIEE Conference
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    • 1992.07b
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    • pp.737-739
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    • 1992
  • The microstructure and humidity sensitive characteristics of $V_2O_5$ doped $CaTiO_3$ were studied. Sensing elements were prepared in bulk form. This element exhibits a porous structure. The grain grows and electrical conductivity increases as doping amount of $V_2O_5$ increases. The change of impedance and capacitance under different r.h is remarkable, and the conduction carriers of this element were ions.

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Ordered CdS nanorods- organic hybrid solar cells

  • Kang, Yoon-Mook;Kim, Dong-Hwan
    • New & Renewable Energy
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    • v.1 no.1 s.1
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    • pp.32-36
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    • 2005
  • We studied the optoelectronic properties of hybrid solar cells formed by mixing cadmium sulfide [CdS] nanorods with a conjugated polymer, poly-2-methoxy, 5-[2'-ethy[hexyloxy]-1,4-p-phenylenevinylene[MEH-PPV]. CdS nanorods were grown vertically on Ti substrates by electrochemical deposition through a porous alumina template. Absorption spectrum of the composite layer was the same as the superposition of the absorption spectrum of each individual layer. The photoluminescence signal from MEH-PPV film was reduced as a result of the mixing. The energy conversion efficiency of MEH-PPV improved from $0.0012\%$ to about $0.60\%$ when combined with the vertically aligned CdS nanorods.

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Preperation of catalyst having high activity on oxygen reduction (저온형 연료전지용 산소의 고활성 환원 촉매 제조)

  • 김영우;김형진;이주성
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 1992.11a
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    • pp.39-40
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    • 1992
  • This paper dealt with the manufacturing of binary alloy catalyst and showed simple electrochemical method for determing catalytic activity of oxygen reduction in acid or alkaline electrolyte. The catalyst was prepared by impregnating transition metal salts on platinum or silver particles adsorbed before on carbon paper substrate. The electrochemical characteristics of the catalysts was investigated with carbon paper electrode or PTFE-boned porous electrode and then cathodic current densities and tafel slopes were compared. As a result, of all binary catalysts utilized in this work, Pt-Fe, Pt-Mo showed better oxygen reduction activity than pure platinum catalyst in acid electrolyte and Ag-Fe, Ag-Pt, and Ag-Ni-Bi-Ti catalyst did than pure silver catalyst in alkaline electrolyte. The current density of Pt-Fe electrode in acid electrolyte was one and half times higher than that of Pt electrode(~500mA/$\textrm{cm}^2$ at 0.7VvsNHE).

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Development of Porous Sorbents for Removal of Hydrogen Sulfide from Hot Coal Gas -I. Additive Effect of Sorbents for the Removal of Hydrogen Sulfide- (고온석탄 가스에서 황화물의 제거하기 위한 다공성 흡착제의 개발-1. 황화수소가스 흡착제의 첨가물 효과-)

  • 이재복;류경옥
    • Journal of Environmental Health Sciences
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    • v.14 no.1
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    • pp.1-9
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    • 1988
  • 석탄유도가스에 포함된 황화수소를 제거시킬 흡착제를 개발하기 위하여 알칼리 토금속, 천이원소 및 아연의 이온반경보다 이온반경이 작은 금속산화물을 산화아연에 첨가시켜 다공성 흡착제를 제조하였다. 600$\circ$C에서 이들 첨가시료를 2.09vol.% 황화수소와 질소가스 혼합기체로 반응시켜 초기속도를 측정하고, 같은 온도에서 사용된 흡착제를 공기로 재생시켰다. 사용된 금속산화물 첨가 흡착제중에서 CaO, TiO$_2$, $Fe_2O_3$, CuO, $Ga_2O_3$ 및 Si$_2$O가 ZnO 흡착제의 초기속도를 증가시켜 첨가제로 사용할 수 있음을 보였다.

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Development of Porous Sorbents for Removal of Hydrogen Sulfide from Hot Coal Gas -II. Kinetics of Suffidation on Zinc Oxide - (고온석탄가스에서 황화물을 제거하기 위한 다공성 흡착제의 개발 -II. 산화아연의 황화반응에 관한 연구-)

  • 서인식;이재복;류경옥
    • Journal of Environmental Health Sciences
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    • v.14 no.1
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    • pp.11-22
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    • 1988
  • Calcium oxide, lithium oxide and titanium oxide were investigated as additives of zinc oxide for the removal of hydrogen sulfide at high temperature. This experiment was performed in the range of 1.0-2.0 vol.% H$_2$S concentration at 623-873 K reaction temperature, using a thermogravimetric analyzer. A pore blocking model was found to fit the reaction rate and the kinetics data were sucessfully expressed by this model. The reactions between additive sorbents and hydrogen sulfide were first order with respect to hydrogen sulfide concentration in a gaseous mixture with nitrogen. Among the used sorbents, ZnO-CaO 0.5 at.% and ZnO-TiO$_2$ 2.0 at.% sorbents had the best additive effects on the sulfidation reaction between additive sorbents and hydrogen sulfide, whereas the ZnO-Li$_2$O sorbents were ineffective.

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Effect of Space Velocity on the DeNOx Performance in Diesel SCR After-Treatment System (디젤 SCR 후처리장치 내 공간속도가 NOx 저감에 미치는 영향)

  • Wang, Tae-Joong;Baek, Seung-Wook;Kang, Dae-Hwan;Kil, Jung-Ki;Yeo, Gwon-Koo
    • 한국연소학회:학술대회논문집
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    • 2006.04a
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    • pp.49-54
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    • 2006
  • The present study conducted a numerical modeling on the diesel SCR (selective catalytic reduction) system using ammonia as a reductant over vanadium-based catalysts $(V_2O_5-WO_3/TiO_2)$. Transient modeling for ammonia adsorption/desorption on the catalyst surface was firstly carried out, and then the SCR reaction was modeled considering for it. In the current catalytic reaction model, we extended the pure chemical kinetic model based on laboratory-scale powdered-phase catalyst experiments to the chemico-physical one applicable to realistic commercial SCR reactors. To simulate multi-dimensional heat and mass transfer phenomena, the SCR reactor was modeled in two dimensional, axisymmetric domain using porous medium approach. Also, since diesel engines operate in transient mode, the present study employed an unsteady model. In addition, throughout simulations using the developed code, effects of space velocity on the DeNOx performance were investigated.

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Effective Refractive Index of Dye-Sensitized Solar Cell Using Transmittance and Reflectance Measurements (투과 및 반사율 측정을 이용한 염료감응태양전지의 유효 굴절률 모델링)

  • Kim, Hyeong Seok;Lee, Joocheol;Shin, Myunghun
    • Current Photovoltaic Research
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    • v.3 no.3
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    • pp.91-96
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    • 2015
  • Optical modeling and characterization of transparent dye-sensitized solar cells (DSC) are presented to design and estimate DSC devices numerically. In order to model the inhomogeneous active layer of DSC, the porous structure of titanium oxide ($TiO_2$) and dye mixture, we prepared films consisting of layer by layer of the DSC's basic materials sequentially, and characterized the optical parameters of the films with the effective refractive index, which was extracted from the transmittance and reflectance measurements in ultra violet to near infra-red range. By using the effective refractive index, we made the optical model for DSC, and demonstrated that the optical model based on effective refractive index can be used to design and evaluate the performance of transparent-type DSC modules.

Effects of Electrolyte Concentration and Relative Cathode Electrode Area Sizes in Titania Film Formation by Micro-Arc Oxidation

  • Lee, Yong-K.;Lee, Kang-Soo
    • Corrosion Science and Technology
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    • v.9 no.4
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    • pp.171-174
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    • 2010
  • MAO (micro-arc oxidation) is an eco-friendly convenient and effective technology to deposit high-quality oxide coatings on the surfaces of Ti, Al, Mg and their alloys. The roles of the electrolyte concentration and relative cathode electrode area sizes in the grown oxide film during titanium MAO were investigated. The higher the concentration of the electrolyte, the lower the $R_{total}A$ value. The oxide film produced by the lower concentration of the electrolyte is thinner and less uniform than the film by the higher concentration, which is thick and porous. The cathode area size must be bigger than the anode area size in order to minimize the voltage drop across the cathode. The ratio of the cathode area size to the anode area size must be bigger than 8. Otherwise, the cathode will be another source for voltage drop, which is detrimental to and slows down the oxide growth.