• Applied Chemistry for Engineering
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• v.32 no.4
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• pp.431-441
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• 2021

In this study, PEBAX/GO-PEI and PEBAX/ZIF-8@GO-PEI composite membranes were prepared by varying the contents of GO and ZIF-8@GO in PEBAX, and also the gas permeation characteristics of N₂ and CO₂ was studied. Overall, the N₂ and CO₂ permeability of the PEBAX/GO-PEI composite membrane decreased as the GO content increased, and the CO₂/N₂ selectivity slightly increased. In the case of PEBAX/ZIF-8@GO-PEI composite membrane, the permeability of N₂ decreased, but CO₂ increased to 1 wt% of ZIF-8@GO and then decreased in the content thereafter. The CO₂/N₂ selectivity at 1 wt% of ZIF-8@GO was 92.3, showing the highest selectivity. This is thought to be due to the greatest effect of GO and ZIF-8 with good affinity for CO₂ alongside the effect of porosity ZIF-8 while improving compatibility with PEBAX and dispersing evenly. In addition, PEBAX/ZIF-8@GO-PEI composite membrane improved both CO₂ permeability and CO₂/N₂ selectivity than those of the PEBAX-PEI and PEBAX/GO-PEI membranes, except for ZIF-8@GO 5 wt%. The result was close to the Robeson upper bound.

• Journal of the Korean GEO-environmental Society
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• v.12 no.7
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• pp.57-65
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• 2011

Numerical simulations by three-dimensional Particle Flow Code($PFC^{3D}$, Itasca) considering distinct element method (DEM) were carried out for prediction of triaxial compression test with sand material. The effect of scale conditions for numerical model and distinct material on final prediction results was analyzed by numerical models under various scale conditions, and following observations were made from the numerical experiments. It is very useful to model the initial material condition without any porosity conversion from 2-D to 3-D DEM. Numerical experiments have shown that in all cases considered, 3D distinct element modeling could provide good agreement on stress-strain behavior, volume change and strength properties with laboratory testing results. It was important thing to assess reasonable scale ratio of numerical model and distinct elements for saving calculation time and securing calculation efficiency under condition with accuracy and appropriateness as numerical laboratory. As results of DEM simulations under various scale conditions, most of results show that shear strength properties as cohesion and internal friction angle are similar in condition of $D_{mod}/D_{gmax}$ < 10. It shows that 3-D distinct element method could be used as efficient tool to assess strength properties by numerical laboratory technique.

• Journal of Korean Society of Forest Science
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• v.100 no.3
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• pp.476-482
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• 2011

As part of studies on the reduction of forest trails degradation caused by high users density, this study was carried out to investigate soil physical properties of forest trails of Gyeongnam Domain in Mt. Jiri, Southeast Korea. Since the forest were opened for leisure trailing in 2008, the average soil erosion amounts per a square meter on the forest trails were $0.0015m^3$ from Inweol to Gumgeo, $0.0018m^3$ from Dongang to Suchol, and $0.0027m^3$ from Suchol to Chungam for 3 years. But, from Chungam to Agyang, the erosion was almost not occurred because it was recently opened. The soil hardness in 5 cm depth was significantly higher than in 10 cm depth. It indicates that intensive soil compaction by users has mainly affected in 5 cm soil depth until now on. In three forest trails compacted intensively, the porosity of 0-7.5 cm soil layer was down to 1.4-1.5 times compared to that in 2008. In additions, the bulk density was up to 1.6-3.1 times compared to the controls, which were not opened to users. As a result, the degradation caused by high users density would keep occurring on the three forest trails unless any counterplans are considered for the degradation reduction. At the moment, users distribution to other forest trails and long-term sabbatical years would be the most effective counterplans to keep from users gravitation on the three forest trails.

• Applied Chemistry for Engineering
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• v.22 no.3
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• pp.277-285
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• 2011

Polysulfone (PSf) membranes were prepared via the phase inversion process. Polyvinylpyrrolidone (PVP) was added as a nonsolvent additive in the casting solution containing a mixture of PSf and n-methylpyrrolidone. The added PVP played a role of enhancing liquid-liquid phase separation of the casting solution, and significantly reduced the solution fluidity. When prepared via the diffusion-induced process using water as a precipitation nonsolvent, the solidified membranes revealed a typical asymmetric structure irrespective of the addition of PVP. With 5 wt% PVP content, the finger-like cavities were more developed in the membrane sublayer compared to that of the membranes prepared without PVP. In contrast, with more than 10 wt% of PVP, the formation of finger-like cavities was suppressed, and the thickness of polymer nodule layer was increased. The surface porosity was also increased with the PSf content in the casting solution. The water permeability curve as a function of PVP addition revealed the inflection point. The maximum water permeability for 12 wt% PSf membrane was obtained with 5 wt% PVP content, and that for 18 wt% PSf membrane with 15 wt% PVP.

• Applied Chemistry for Engineering
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• v.22 no.5
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• pp.501-507
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• 2011

To develop environmental-friendly insulating composite materials, natural cellulose and porous ceramic balls were used as core materials and activated Hwangtoh was used as a binder. Various specimens were prepared with different water/binder ratios and core material/binder ratios. The physical properties of these specimens were then investigated through compressive strengths, flexural strengths, absorption test, hot water resistance test, pore analysis, thermal conductivity, and observation of micro-structures using scanning electron microscope. Results showed that the maximum compressive strength varied appreciably with the water/binder ratios and core material/binder ratios, but the flexural strength increased with the core material/binder ratios regardless of water/binder ratios. The compressive strength and the flexural strength measured after the hot water resistance test decreased remarkably compared to those measured before test. The pore analysis measured after the hot water resistance test showed that total pore volume, porosity and average pore diameter decreased, while bulk density increased by the acceleration of hydration reaction of binder in the hot water. The thermal conductivity decreased gradually with an increase of core material/binder ratios. It can be evaluated that the composite insulation materials having good insulating properties and mechanical strengths can be used in the field.

• Korean Journal of Metals and Materials
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• v.46 no.6
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• pp.351-356
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• 2008

Thermally sprayed tungsten carbide-based powder coatings are being widely used for a variety of wear resistance applications. The coating deposited by high velocity processes such as high velocity oxy-fuel (HVOF) thermal spraying is known to provide improved wear resistant property. In this study, optimal coating process (OCP) is obtained by the study of coating properties such as surface hardness, porosity, surface roughness and microstructure of 9 coatings prepared by Taguchi program for 3 levels of four spray parameters. The Friction and wear behaviors of HVOF WC-CoCr coating prepared by OCP, electrolytic hard chrome (EHC) plating and Inconel718 (In718) are investigated by reciprocating sliding wear test at $25^{\circ}C$, $450^{\circ}C$. Friction coefficients (FC) of all of the 3 samples are decreased as increasing sliding surface temperature from $25^{\circ}C$ to $450^{\circ}C$. FC of WC-CoCr decreases as increasing the surface temperature from $0.33{\pm}0.02$ at $25^{\circ}C$ to $0.26{\pm}0.02$ at $450^{\circ}C$, showing the lowest FC among the 3 samples. Wear trace (WT) and wear depth (WD) of WC-CoCr are smaller than those of EHC and In718 both at $25^{\circ}C$ and $450^{\circ}C$. These show that WC-CoCr is highly recommendable for protective coating on In718 and other metal components.

• Conservation Science in Museum
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• v.25
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• pp.63-84
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• 2021

In order to investigate the diverse physicochemical changes that occurred in traditional Korean pottery during its production, including before and after firing, this study produced six replicas of a celadon maebyeong inlaid with cloud-and-crane designs, respectively corresponding to the process of shaping, carving, inlaying designs, first firing, glazing and second firing, respectively. It then conducted a scientific study of these six replicas and analyzed their images through high-resolution three-dimensional transmission imaging. The materials used for the replicas show different mineral phases and even colors depending on the components of each material. For example, black inlay with a high content of iron oxide (Fe₂O₃) shows dark colors and white inlay with a high alumina (Al₂O₃) content appears white. Physicochemical properties such as chromaticity and magnetic susceptibility and major components of the replicas were confirmed by the differences in the density in the computed tomography (CT) images. The characteristics of fired products such as fine structure, absorption ratio, apparent porosity, and other characteristics of the major mineral components were identified by the presence of pores and the formation of cracks inside the replicas in the image analysis.

• Journal of the Korean Recycled Construction Resources Institute
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• v.8 no.4
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• pp.506-513
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• 2020

In this study, the mechanical properties, absorption, and reduction performance of NOx in the mortar containing mineral admixture like zeolite and active hwangtoh were evaluated. Zeolite and active hwangtoh were used as binder, and zeolite and active hwangtoh were substituted for cement. The substitution ratio of two types of mineral admixtures was considered as 20 and 30% respectively. As a result of evaluating the compressive strength and flexural strength of each mortar specimen, the highest strength in the plain mixture was evaluated. As the substitution ratio of zeolite and active hwangtoh increased, the compressive and flexural strength decreased. In addition, the difference of compressive and flexural strength between active hwangtoh and zeolite mixing was evaluated to be insignificant. To evaluate the absorption rate, the mixture was designed to lower the W/B ratio of the existing mixture and set the substitution ratio of active hwangtoh and zeolite at 25%. The highest absorption ratio in the mortar with zeolite was evaluated, and the difference in absorption ratio between the remaining two mortar mixtures was small. The assessment of reduction performance of NOx considering the application of photocatalyst showed a clearly decreasing reduction behavior, even if they were the same mortar mixture. Zeolite and active hwangtoh also showed a higher NOx reduction than the Plain mixture, because of their porosity properties. In the case of active hwangtoh, the absorption ratio was lower than that of zeolite mixture, but the reduction of NOx performance was better than the result of zeolite mixture.

• Journal of Korean Tunnelling and Underground Space Association
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• v.24 no.5
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• pp.395-409
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• 2022

To overcome the limitation of conventional rock excavation methods, the excavation with abrasive waterjet has been actively developed. The abrasive waterjet excavation method has the effect of reducing blasting vibration and enhancing the excavation efficiency by forming a continuous free surface on the rock. However, the waterjet cutting performance varies with rock fracturing characteristics. Thus, it is necessary to analyze the cutting performance for various rocks in order to effectively utilize the waterjet excavation. In this study, cutting experiments with the high pressure waterjet system were performed for basalt and granite specimens. Water pressure, standoff distance, and traverse speed were determined as effective parameters for the abrasive waterjet cutting. The cutting depth and width of basalt specimens were analyzed to compare with granite results. The averaged cutting depth of basalt was shown in 41% deeper than granite; in addition, the averaged cutting width of basalt was formed by 18.5% narrower than granite. The results of this study are expected to be useful basic data for applying rock excavation site with low strength and high porosity such as basalt.

• Journal of the Korean Recycled Construction Resources Institute
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• v.10 no.3
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• pp.195-203
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• 2022

In this paper, the effects of the bottom ash aggregate sizes and compaction levels on the thermal conductivity of porous concrete were investigated. In this experimental study, bottom ash was used as aggregates after identifying the aggregate characteristics. SA mixtures included hybrid aggregates, and DA contained only one particle size. The water-binder ratio was fixed at 0.30, and the compaction levels were applied to the concrete specimens at 0.5, 1.5, and 3.0 MPa. Unit weight, total void ratio, and thermal conductivity were measured and analyzed. As the compaction level increased, the unit weight and thermal conductivity increased in the SA mixtures, but the total void ratio decreased. In addition, the thermal conductivity of the specimens under oven-dried condition were lower than that of the specimens under air-dried condition. The correlation between the unit weight, total porosity, and thermal conductivity of porous concrete was analyzed. The thermal conductivity-unit weight correlation was proportional, while the thermal conductivity-total void ratio correlation was inversely proportional.