• Title/Summary/Keyword: Porosity.

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Relationship between Water Stable Aggregate and Macroporosity in Upland Soils Calculated by Fragmentation Fractal Dimension (파쇄프랙탈차원을 이용한 밭토양 내수성입단과 대공극률의 관계 평가)

  • Han, Kyung-Hwa;Cho, Hyun-Jun;Lee, Hyup-Sung;Hur, Seung-Oh;Ha, Sang-Keun
    • Korean Journal of Soil Science and Fertilizer
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    • v.42 no.1
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    • pp.58-64
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    • 2009
  • The objectives of this study were to investigate the aggregate fragmentation in wet-sieving and to evaluate the relationship between the aggregate fragmentation fractal dimension and macro-porosity of upland soils, using three different textural types of soils including Gopyeng series (Fine, Typic Hapludalfs), Gyuam series (Fine silty over coarse silty, Fluvaquentic Eutrudepts), and Jungdong series (Coarse loamy, Typic Udifluvents) located in Gyeonggi province. Undisturbed soil samples with five replicates were seasonally sampled and used for measuring water stable aggregate, macropores, and physico-chemical properties of soils. The aggregate stability in wet-sieving was digitalized as three types of fragmentation fractal dimension ($D_f$), geometric mean diameter (GMD), and mean weight diameter (MWD). $D_f$ had higher correlation with GMD than with MWD. Seasonal aggregate stability showed the highest values in summer, and decreased in the order of spring and autumn. The macroporosity had higher in topsoil, in autumn, and in ridge, than in plow pan layer, in summer, and in row, respectively. The relationship between $D_f$ and macroporosity, especially more than 99 m, showed high correlation only in soils with $D_f$ less than 3.1, which means more aggregated soils compared to soils with $D_f$ more than 3.1. Besides, in the soils with the fractal dimension less than 3.1, the power function relation between saturated hydraulic conductivity and macroporosity more than 99 m had relatively high determinant coefficient, and vice versa. Therefore, it could be thought that fragmentation fractal dimension is available for confirming macroporosity induced from aggregation.

Synthesis and Electrochemical Properties of Porous Li4Ti5O12 Anode Materials (기공구조로 제조된 Li4Ti5O12 음극활물질의 전기화학적 특성)

  • Seo, Jin-Seong;Na, Byung-Ki
    • Korean Chemical Engineering Research
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    • v.57 no.6
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    • pp.861-867
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    • 2019
  • $Li_4Ti_5O_{12}$ is a promising next-generation anode material for lithium-ion batteries due to excellent cycle life, low irreversible capacity, and little volume expansion during charge-discharge process. However, it has poor charge capacity at high current density due to its low electrical conductivity. To improve this weakness, porous $Li_4Ti_5O_{12}$ was synthesized by sol-gel method with P123 as chelating agent. The physical characteristics of as-prepared sample was investigated by XRD, SEM, and BET analysis, and electrochemical properties were characterized by cycle performance test, cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS). $Li_4Ti_5O_{12}$ synthesized by 0.01mol ratio of P123/Ti showed most unified particle size, high specific surface area, and relatively high porosity. EIS analysis showed that depressed semicircle size was remarkably reduced, which suggested resistance value in electrode was decreased. Capacity in rate performance showed 178 mAh/g at 0.2C, 170 mAh/g at 0.5C, 110 mA/h at 5C, and 90 mAh/g at 10C. Capacity retention also showed 99% after rate performance.

Effects of Damage Evolution of Eutectic Si Particle and Microporosity to Tensile Property of Al-xSi Alloys (Al-xSi 합금의 인장특성에 미치는 공정 Si 입자의 파단과 미소기공율의 영향)

  • Lee, ChoongDo
    • Journal of Korea Foundry Society
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    • v.41 no.5
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    • pp.434-444
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    • 2021
  • This study investigated the overall dependence of the tensile properties of Al-Si alloys on the distribution aspect of a eutectic Si particle in terms of defect susceptibility to the effective void area fraction, referring to the sum of pre-existing microvoids and the damage evolution of the Si particle. The network morphology of as-cast Al-xSi (x=2,5,8,11) alloys was modified to a granular type via a T4 treatment, after which a computational topography (CT) analysis and scanning electron microscope (SEM) observations were utilized to evaluate the size and distribution of the microvoids. The CT and SEM analyses indicated that the main cracks grow along local regions that possess the highest porosity level. The local plastic deformation around the microvoids and the distribution aspect of the microvoids induced a practical difference between the iso-volumetric CT measurement and the SEM fractography outcomes. The results demonstrated that the overall dependence of the ultimate tensile strength (UTS) and elongation on the effective void area fraction is more sensitive to the variation of the area fraction of the Si particle in the network morphology than in the granular type; this is due to the sequential damage evolution of the neighboring Si particles in the eutectic Si colony.

Scientific Comparison Study on the Joseon Dynasty Palace Roof Tiles and Modern Handmade Roof Tiles

  • Ahn, Kyoung Suk;Lee, Min Hye;Kim, Ji Hye;Ha, Ji Hyang;Jang, Won Jin;Kim, Du Hyeon;Jeong, Ji Youn;Han, Min Su
    • Journal of Conservation Science
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    • v.37 no.1
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    • pp.63-76
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    • 2021
  • The purpose of this study is to scientifically analyze physicochemical characteristics of the roof tiles used for palaces in the Joseon Dynasty which stored in Changdeokgung material storage and Seooreung Jaesil and the modern handmade ones which made by N company to understand the differences between their manufacturing techniques. Through chromaticity, cross-sectional observation, component analysis, and crystal structure analysis, it was possible to confirm the physicochemical properties and fired properties of the roof tile. Roof tiles from the Joseon Dynasty have a wider colorimetric range and higher apparent porosity and water absorption, on average, than the modern roof tiles. The cross section of the Joseon Dynasty roof tiles shows that most clay minerals have not been vitrified, remaining in the form of atypical particles, while the modern roof tiles have denser clay materials. X-ray diffraction analysis identified low-temperature minerals such as micas in Joseon roof tiles but no peak of these minerals was observed in the modern roof tiles, implying that the modern ones are fired at higher temperature than the Joseon ones. Therefore, the modern roof tiles are fired at higher temperature and have higher density than the Joseon ones due to the use of pugmills. The general content of main ingredients was similar between the two. Additionally, the principal component analysis of trace elements in the Joseon roof tiles showed that most samples were from similar areas. It seems that the Joseon roof tiles were manufactured using soils supplied from a specific region at the same timeframe and their consistency in the content of principal components implies that they also have similar mix proportions of clay.

Flow Distribution in an Electrostatic Precipitator with a Perforated Plate (타공판에 따른 전기집진기 내의 유동분포)

  • Kim, Dong-uk;Jung, Sang-Hyun;Shim, Sung-Hoon;Kim, Jin Tae;Lee, Sang-Sup
    • Clean Technology
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    • v.25 no.2
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    • pp.147-152
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    • 2019
  • Electrostatic precipitator that shows a good performance for the removal of particulate matter is important for controlling emissions from industrial facilities and power plants. The efficiency of the electrostatic precipitator on the removal of particulate matter is highly affected by the flow pattern inside the electrostatic precipitator. A number of studies have been conducted to obtain uniform flow distribution inside electrostatic precipitators. An electrostatic precipitator (ESP) with a length of 3.5 m and a height of 0.875 m was designed and installed in this study. The ESP included an inlet duct, diffuser, body, and contractor. Three perforated plates were installed in the diffuser of the ESP. Five pitot tubes were installed vertically and used to measure flow distribution in the cross section of the ESP body. Root mean square deviation value (RMS%) was used to examine the flow distribution inside the ESP when the perforated plates were installed in the diffuser. Flow distribution was also investigated in relation to the porosity of the perforated plate. The results showed that the perforated plates improved greatly the flow distribution inside the electrostatic precipitator. In addition, the most uniform flow distribution was found with 40%, 50%, and 50% porous perforated plates located from the inlet of the diffuser.

Analysis the Use of Concrete Fine Aggregates of Coal Gasification Slag (콘크리트용 잔골재로서 석탄가스화 용융슬래그(CGS)의 활용성 분석)

  • Park, Kyung-Taek;Han, Min-Cheol;Hyun, Seung-Yong
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.2
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    • pp.101-108
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    • 2019
  • This study is analysis of the utilization as a concrete fine aggregate on CGS, a by-product of Integrated coal gasification combined cycle(IGCC). That is, in KS F 2527 "Concrete aggregate," properties of 1~12times to CGS were evaluated, focusing on quality items corresponding to natural aggregate sand(NS) and melted slag aggregate sand(MS). As a result, the distribution of grain shape, safety and expansion were all satisfied with KS standards by physical properties, but the quality was unstable at 7~12times of water absorption ratio and absolute dry density. The particle size distribution was unstable due to asymmetry distribution of coarse particles, and particles were too thick for 7~12times. The passing ratio of 0.08mm sieve was also out of the KS standard at part factor of 7~12times, but chloride content, clay contents, coal and lignite were all satisfactory. Meanwhile, chemical composition was satisfactory except for $SO_3$ in 1~6times, and content and amount of harmful substances were all within the specified value except for F in 7~12times. As a result of SEM analysis, the surface quality and porosity were 7~12times more than 1~6times, and it was the quality was degraded. Therefore, it is necessary to reduce the quality deviation by using separate measures in order to utilize it as concrete aggregate in the future, and if it is premixed with fine quality aggregate, it will contribute positively to solve aggregate supply shortage and utilize circulation resources.

Effects of the Physicochemical Properties of Lignocellulosic Artificial Soil Containing Bacillus subtilis on the Growth of Lespedeza cyrtobotrya (Bacillus subtilis가 함유된 목질계 인공토양의 물리·화학적 특성이 참싸리 생육에 미치는 영향)

  • Kim, Ji-Su;Jung, Ji young;Ha, Si Young;Yang, Jae-Kyung
    • Journal of the Korean Wood Science and Technology
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    • v.47 no.4
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    • pp.393-407
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    • 2019
  • In this study, we prepared lignocellulosic artificial soil that contains Bacillus subtilis (peat moss/perlite/ steam-exploded oak wood/microbial culture = 3:1:3:3, w/w/w/w) for use in the restoration of damaged soil areas. The prepared lignocellulosic artificial soil was mixed with soil at ratios of 0%, 25%, 50%, 75%, and 100%. These mixed soils were then applied to fields, and the resultant physicochemical properties and their effects on the plant growth of Lespedeza cyrtobotrya were observed. The mixture of the prepared artificial soils (mixed at ratios of 25%-100%) with soil had a bulk densities of <$0.04g/cm^3$, porosities of >85%, pH values between 4.3 and 4.7, electrical conductivities of <0.5 dS/m, C/N ratios between 15.0 and 26.5, organic matter content between 23.6% and 43.2%, and bacterial densities between $157{\times}10^6$ and $624{\times}10^6CFU/g$. In addition, the prepared artificial soils mixed with soil at ratios of 25%-50% exhibited higher plant growth rates for L. cyrtobotrya compared with the control. Overall, we identified positive correlations between the plant growth of L. cyrtobotrya and soil bulk density, porosity, water-holding capacity, C/N ratio, organic matter, and bacterial densities.

Application of Geophysical Methods for Developing Saline Groundwater from an Coastal Aquifer (해안지역 염지하수 개발을 위한 물리탐사 적용 사례)

  • Lim, Sung Keun;Song, Sung-Ho;Kim, Soo Hong
    • Geophysics and Geophysical Exploration
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    • v.21 no.4
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    • pp.255-261
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    • 2018
  • The purpose of this study was to obtain a large amount of saline groundwater around coastal aquaculture farms. Thus, we have proposed a method for evaluating the potential amount of saline groundwater resources through the combined analysis of geophysical methods. Refraction seismic survey and electrical resistivity survey were conducted in the vicinity of fish farm at Hadong, Gyeongnam Province. As the result, the velocity of layer in the range of 900 ~ 2,400 m/s was found to be saltwater aquifer with high water content. Geological drilling investigation and analysis of soil samples also showed that the soil at study area was the same as the texture of sandy loam layer in agricultural radial collector wells installed by KRC (Korea Rural Community Corporation). Futhermore, the study area turned out to be quite possible to develop saline groundwater from the coastal shallow aquifer. Therefore, parallel analysis of refraction seismic surveys and electrical resistivity surveys at coastal area are expected to be very useful for the detection of the aquifer composed of sand and gravel layers with high porosity in sandy sedimentary layers along the coastal area.

The Study on Filling Factor of Radiation Shielding Lead-free Sheet Via Screen Printing Method (스크린 프린팅 공법을 통한 방사선 무연 차폐 시트에 관한 연구)

  • Kang, Sang-Sik;Jeong, Ah-Rim;Lee, Su-Min;Yang, Seung-Woo;Kim, Kyo-Tae;Heo, Ye-Ji;Park, Ji-Koon
    • Journal of the Korean Society of Radiology
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    • v.12 no.6
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    • pp.713-718
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    • 2018
  • In many previous studies, monte carlo simulation is used to produce lead-free shielding sheet, and the possibility of radiation shielding capability and weight reduction is presented. But it is difficult to simulation for binder and micro-pores because of In fact it does not provide sufficient information necessary for the commercialization process. Therefore, in this paper, the results of radiation shielding capability corresponding to filling factor was presented by using the screen printing method to provide information on gel-paste required for the commercialization process. In this study, the geometric setup for evaluate of radiation shielding ability was designed to comply with IEC 61331-1:2014 and KS A 4025. In addition, radiation irradiation conditions were 100 kVp filtered with 2.0 mmAl total filtration was applied according to KS A 4021 standard. In this study, Pb $1270{\mu}m$, $BaSO_4$ $3035{\mu}m$, $Bi_2O_3$ $1849{\mu}m$ and $WO_3$ $2631{\mu}m$ were analyzed based on ten value layer. Additionally, the filling factor was analyzed as $BaSO_4$ 38.6%, $Bi_2O_3$ 27.1%, $WO_3$ 30.15%. However, in the case of applying low-temperature high-pressure molding in the future, it is expected that the radiation shielding capability can be sufficiently improved by reducing the porosity while increasing the filling factor.

Fundamental Research on Reactivity of Silica Source in the Rapidly Cured Inorganic Micro-Defect-Free(MiDF) Concrete (촉진 양생한 무기계 MiDF 콘크리트에서 실리카질 원료의 반응성에 관한 기초 연구)

  • Choi, Hong-Beom;Kim, Jin-Man
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.2
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    • pp.166-173
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    • 2019
  • In this paper, the reaction properties of silica source in the accelerated curing conditions using autoclave and the fundamental properties of inorganic Micro Defect Free(MiDF) concrete using silica source are studied. Studies show that Si ions elution rate from silica source in autoclave curing is higher in amorphous source. In tap water conditions, solids which is source after autoclaved curing show a higher mass reduction in amorphous materials, which is attributed to the higher elution rate of ion. In $Ca(OH)_2$ solution conditions, amorphous materials show higher mass increase, due to increase in C-S-H minerals. From experiment for influence on the properties of MiDF concrete by using nano silica materials, the specimen with silica fume shows an increase in compressive strength and a decrease in absorption depending on replacement rate up to 5.5%, while nano silica with amorphous phase and high-fineness shows a decrease in compressive strength and decrease in the water absorption. The specimen with nano silica increases the pore below 10,000nm, but reduces pore between 10,000 and 100,000nm. The above results show that the porosity and absorption rate of MiDF concrete can be reduced by using amorphous nano-size silica. However, to reduce the pore of 50 to 10,000nm, better dispersion of nano material in the cement matrix will be necessary. We will focus on the this item in the next research.