• Title/Summary/Keyword: Porosity ceramics

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STUDY ON HEAT TRANSFER CHARACTERISTICS OF THE ONE SIDE-HEATED VERTICAL CHANNEL WITH INSERTED POROUS MATERIALS APPLIED AS A VESSEL COOLING SYSTEM

  • KURIYAMA, SHINJI;TAKEDA, TETSUAKI;FUNATANI, SHUMPEI
    • Nuclear Engineering and Technology
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    • v.47 no.5
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    • pp.534-545
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    • 2015
  • In the very high temperature reactor (VHTR), which is a next generation nuclear reactor system, ceramics are used as a fuel coating material and graphite is used as a core structural material. Even if a depressurization accident occurs and the reactor power goes up instantly, the temperature of the core will change only slowly. This is because the thermal capacity of the core is so high. Therefore, the VHTR system can passively remove the decay heat of the core by natural convection and radiation from the surface of the reactor pressure vessel. The objectives of this study are to investigate the heat transfer characteristics of natural convection of a one-side heated vertical channel with inserted porous materials of high porosity and also to develop the passive cooling system for the VHTR. An experiment was carried out using a one-side heated vertical rectangular channel. To obtain the heat transfer and fluid flow characteristics of the vertical channel with inserted porous material, we have also carried out a numerical analysis using a commercial Computational Fluid Dynamics (CFD) code. This paper describes the thermal performances of the one-side heated vertical rectangular channel with an inserted copper wire of high porosity.

Effect of Phenolic Resin According to Relative Humidity on Submerged Entry Nozzle with ZrO2-C System in Fabrication Process (ZrO2-C계 침지노즐 제조시 상대습도에 따른 바인더용 페놀수지의 영향)

  • Yoon, Sang-Hyeon;Kim, Jang-Hoon;Kim, Ju-Young;Lee, Hee-Soo;Koo, Young-Seok
    • Journal of the Korean Ceramic Society
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    • v.48 no.4
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    • pp.293-297
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    • 2011
  • The thermodynamic behavior of phenolic resin was investigated to verify the relation between the properties of porous ceramics with $ZrO_2$-C system for submerged entry nozzle and the characteristics of phenolic resin with various relative humidity. The green and the sintered density were decreased between 25% and 50% relative humidity, whereas they were gradually enhanced above 50% relative humidity. The highest value of apparent porosity was 20.1% and the minimum compressive strength was 69MPa in the specimen using the powder exposed to 50% relative humidity. As a result of thermal analysis for phenolic resin, the shift of endothermic peak to low temperature and the reduction of exothermic peak were observed, and the peaks corresponded to melting and curing of phenolic resin, respectively. The melting and the curing of phenolic resin generate the change of green density, and it can affect the properties of submerged entry nozzle.

Structural and Electrical Properties of (x)Ba$TiO_3$-(1-x)Sr$TiO_3$ Ceramics with Contents Sr$TiO_3$ (Sr$TiO_3$ 변화량에 따른 (x)Ba$TiO_3$-(1-x)Sr$TiO_3$ 세라믹스의 구조적, 전기적 특성)

  • 장동환;김충배;홍경진;이우기;정우성;김태성
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1998.11a
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    • pp.45-48
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    • 1998
  • A BaTiO$_3$ was annexed to SrTiO$_3$, (x)BaTiO$_3$-(1-x)SrTiO$_3$ (0.7$\leq$X$\leq$1) ceramics with stable dielectric and electrical properties in high voltage were manufactured. Structural, dielectric and electrical properties were surveyed with the contents of SrTiO$_3$. The open porosity and sintering density were excellent in 0.9BaTiO$_3$-0.1SrTiO$_3$, the grain size of 0.9BaTiO$_3$-0.1SrTiO$_3$ was maximum at 12.40[${\mu}{\textrm}{m}$]. Increasing SrTiO$_3$ mol ratio, the curie temperature was shifted low temperature and the supreme permittivity was increased. In line with increasing of supplied voltage, permitivity was decreased slightly.

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A Study on Enhancement of MIR Transmittance of Hydrothermally Synthesized ZnS Nanoparticles with Sintering Pressure (수열합성된 황화아연 나노입자의 소결 압력에 따른 중적외선향상에 관한 연구)

  • Yeo, Seo-Yeong;Park, Buem-Keun;Paik, Jong-Hoo
    • Journal of Sensor Science and Technology
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    • v.29 no.1
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    • pp.63-67
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    • 2020
  • This study investigated the influence of various sintering pressures of ZnS nanoparticles prepared by hydrothermal synthesis performed at 220 ℃ for 20 h. The hydrothermally synthesized ZnS nanoparticles formed a cubic phase. The ZnS nanoparticles were sintered using a hot-press process at 850 ℃ for 2 h under pressures of 10, 20, 30, 40, 50, 60, and 70 MPa. The ZnS ceramics indicate the cubic phase is the major phase and the hexagonal phase is the minor phase. In the ZnS ceramics, as the sintering pressure increased, a decrement in the hexagonal phase was confirmed. When the sintering pressure equaled or exceeded 30 MPa, the transmittance and density improved with reductions in porosity and hexagonal phase. A sintering pressure of 60 MPa delivered the highest transmittance (69.7%).

Effect of Vacuum Heat Treatment on the Properties in Thermal Sprayed Ceramics Coating (세라믹스 용사 코팅 특성에 미치는 진공열처리의 영향)

  • Lee, J.I.;Ur, S.C.;Lee, Y.G.
    • Journal of the Korean Society for Heat Treatment
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    • v.13 no.2
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    • pp.98-102
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    • 2000
  • The effect of vacuum heat treatment in the thermal sprayed ceramics coating on a capstan by either high velocity oxygen fuel(HVOF) or plasma thermal spray process was investigated. The coating materials applied on the capstan were tungsten and chrome carbides. In order to characterize the interface between coating layer and bare materials, hardness, adhesion strength, X-ray diffraction(XRD) and microstructural analysis are conducted. The adhesion strength of the carbide coated materials by HVOF process is over 500MPa compared to those of plasma coating process is 230MPa. In case of the carbide coated materials by HVOF process, the adhesion strength is increased to 15MPa and the porosity is reduced under 5% by vacuum heat treatment for 5 hrs at $1000^{\circ}C$. The XRD results reveal that the increasement is believed due to the phase stabilization of metastable $Cr_3C_2$ phase to stable $Cr_{23}C_6$ phase.

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Fabrication of Porous Al2O3 Ceramics Using Thermoplastic Polymer (열가소성 고분자를 이용한 다공질 알루미나의 제조)

  • 이상진;김해두
    • Journal of the Korean Ceramic Society
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    • v.41 no.7
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    • pp.513-517
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    • 2004
  • Porous alumina ceramics with aligned plate-shaped pores were fabricated by using thermoplastic microsphere in order to show the anisotropy in thermal conductivity. The mixed powder of alumina and microsphere was pressed under 15 MPa till 20$0^{\circ}C$ to deform polymer into platelet-shape and sintered at 1,00$0^{\circ}C$ for 1 h. The sintered specimen with 10 wt% microsphere has 45.3% porosity and the bending strength of 44 MPa. The microstructural investigation confirmed the pore structure of platelet-shape, the thermal conductivities for vertical and parallel directions are 3.803 W/mK and 7.818 W/mK, respectively, the ratio between two directions exceeds 2.

Influence of the SPS heating rate on the optical and mechanical properties of Y2O3-MgO nanocomposites

  • Yong, Seok-Min;Choi, Doo Hyun;Lee, Kisu;Ko, Seok-Young;Cheong, Dong-Ik
    • Journal of Ceramic Processing Research
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    • v.20 no.1
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    • pp.59-62
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    • 2019
  • Y2O3-MgO nanocomposites are promising materials for hypersonic infrared windows and domes due to their excellent midIR transmittance and mechanical properties. In this work, influence of SPS heating rate on the microstructure, IR transmittance, and mechanical properties of Y2O3-MgO nanocomposites was investigated. It was found that the average grain size decreases with a decreasing heating rate, which can be attributed to high defect concentration by rapid heating and deformation during densification. Also, the residual porosity decreases with a decreasing heating rate, which is ascribed to the enhancement of grain boundary diffusion by a large grain-boundary area (a small grain size). Consequently, high transmittance and hardness were attained by the low heating rate. On the other hand, the mechanical strength showed little difference with the heating rate change, which is somewhat different from the general knowledge on ceramics and will be discussed in this letter.

Study on the control of marine biofouling developed on the surface of porous ceramics (세라믹 다공체 표면에 발생하는 해양 생물 오손 억제에 관한 연구)

  • Kang, Jimin;Kang, Seunggu;Kim, YooTack
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.25 no.5
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    • pp.218-224
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    • 2015
  • Recently, removing methods of red tide has been attempted by filtering the organisms using the ceramic porous bodies. However, the marine biofouling could be developed on the surfaces of porous ceramic body after use for more than one month, and it might decrease the function of the specimen. In this paper, a method of inhibiting marine biofouling by changing the physical properties or surface-modification of ceramic porous body was studied. After experiment with six different ceramic porous bodies, it was found that the specimen of lower porosity and water absorption showed the least amount of biofouling. In addition, by increasing the surface roughness with silica particles bonded to the surface of specimen, the amount of biofouling caused by large marine life such as barnacle and mussel could be decreased. On the other hand, when the surface of specimen was coated and fused by glass powder, the amount of biofouling was rather increased. This might be due to eluted inorganic ions from the glass which can promote the growth of the microorganism. In conclusion, the environmental-friendly methods to reduce the amount of marine biofouling, such as controlling the physical properties and the surface roughness of the porous ceramics, can be possible without the use of dangerous substances. So it is expected for the results obtained to be applicable to a marine structure.

Correlation between Microstructure and Mechanical Properties of the Additive Manufactured H13 Tool Steel (적층 제조된 H13 공구강의 미세조직과 기계적 특성간의 상관관계)

  • An, Woojin;Park, Junhyeok;Lee, Jungsub;Choe, Jungho;Jung, Im Doo;Yu, Ji-Hun;Kim, Sangshik;Sung, Hyokyung
    • Korean Journal of Materials Research
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    • v.28 no.11
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    • pp.663-670
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    • 2018
  • H13 tool steels are widely used as metallic mold materials due to their high hardness and thermal stability. Recently, many studies are undertaken to satisfy the demands for manufacturing the complex shape of the mold using a 3D printing technique. It is reported that the mechanical properties of 3D printed materials are lower than those of commercial forged alloys owing to micropores. In this study, we investigate the effect of microstructures and defects on mechanical properties in the 3D printed H13 tool steels. H13 tool steel is fabricated using a selective laser melting(SLM) process with a scan speed of 200 mm/s and a layer thickness of $25{\mu}m$. Microstructures are observed and porosities are measured by optical and scanning electron microscopy in the X-, Y-, and Z-directions with various the build heights. Tiny keyhole type pores are observed with a porosity of 0.4 %, which shows the lowest porosity in the center region. The measured Vickers hardness is around 550 HV and the yield and tensile strength are 1400 and 1700 MPa, respectively. The tensile properties are predicted using two empirical equations through the measured values of the Vickers hardness. The prediction of tensile strength has high accuracy with the experimental data of the 3D printed H13 tool steel. The effects of porosities and unmelted powders on mechanical properties are also elucidated by the metallic fractography analysis to understand tensile and fracture behavior.

Fabrication and Mechanical Properties of High-strength Porous Supports for High Temperature Oxygen Transport Membrane (고온 산소분리막용 고강도 다공성 지지체 제조 및 기계적 특성 연구)

  • Park, Geum Sook;Seong, Young-Hoon;Yu, Ji Haeng;Woo, Sang Kuk;Han, Moon Hee
    • Journal of the Korean Ceramic Society
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    • v.50 no.6
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    • pp.423-428
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    • 2013
  • Porous YSZ ceramics are fabricated using 3 mol% yittria-stabilized zirconia (3YSZ) and NiO with different particlesizes (0.6 and 7 ${\mu}m$). Nickel oxide (NiO) is added to the YSZ powder as a pore former with different amounts(40, 50, and 60 vol%) and at different sintering temperatures (1350 and $1400^{\circ}C$) are applied in order to evaluate the temperature effects on the pore and mechanical properties. Heat treatment is conducted after sintering at $700^{\circ}C$ in $H_2$ for the NiO reduction process; then, Ni is removed using a $HNO_3$ etchant solution. According to the NiO contentand sintering temperatures, 41-67% porous YSZ ceramic is obtained and the flexural strength increases, while the porosity decreases with an increasing sintering temperature. The optimum flexural strength ($136.5{\pm}13.4MPa$) and porosity (47%) for oxygen transport porous YSZ membrane can be obtained with 40 vol% of 7 ${\mu}m$ NiO particle at a sintering temperature of $1350^{\circ}C$.