• Title/Summary/Keyword: Pore water

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Preparation of Porous Cordierite by Using Water-Vapour Treatment (수증기처리공정에 의한 다공성 코디어라이트의 제조)

  • 문교태;서신석;노재성;조득희;김동표
    • Journal of the Korean Ceramic Society
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    • v.34 no.9
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    • pp.986-992
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    • 1997
  • Cordierite ceramic was prepared by sol-gel method. It was analyzed by Infrared spectroscopy and X-ray diffraction patterns that the ceramic was chemically mixed in molecular level and transformed to $\alpha$-cordierite at 125$0^{\circ}C$. Water vapour treatments for aging and drying process were conducted to get porous cordierite with thermally stable pore structure. It resulted in 220-410 $m^2$/g BET surface area and mesoporous structure with mean pore diameter, 40$\AA$. Compared to naturally dried ceramic, the ceramic showed superior thermal stability of surface area up to $700^{\circ}C$. Surfaces of porous cordierite ceramics were observed by SEM.

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Migration of calcium hydroxide compounds in construction waste soil

  • Shin, Eunchul;Kang, Jeongku
    • Advances in environmental research
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    • v.4 no.3
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    • pp.183-196
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    • 2015
  • Migration of leachate generated through embankment of construction waste soil (CWS) in low-lying areas was studied through physical and chemical analysis. A leachate solution containing soluble cations from CWS was found to have a pH above 9.0. To determine the distribution coefficients in the alkali solution, column and migration tests were conducted in the laboratory. The physical and chemical properties of CWS satisfied environmental soil criteria; however, the pH was high. The effective diffusion coefficients for CWS ions fell within the range of $0.725-3.3{\times}10^{-6}cm^2/s$. Properties of pore water and the amount of undissolved gas in pore water influenced advection-diffusion behavior. Contaminants migrating from CWS exhibited time-dependent concentration profiles and an advective component of transport. Thus, the transport equations for CWS contaminant concentrations satisfied the differential equations in accordance with Fick's 2nd law. Therefore, the migration of the contaminant plume when the landfilling CWS reaches water table can be predicted based on pH using the effective diffusion coefficient determined in a laboratory test.

Safety Evaluations of Reservoir Embankment by Instrument System (계측시스템에 의한 저수지 제체의 안정성 평가)

  • Kim, Mi-Hyun;Lee, Dal-Won
    • Journal of The Korean Society of Agricultural Engineers
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    • v.51 no.6
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    • pp.33-43
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    • 2009
  • This study analyzed data on the pore water pressure, the ground water level, the horizontal displacement and the resistivity monitoring from instrument system, which is established to evaluate the safety in reservoirs. The pore water pressure in the embankment ranged from $0.035{\sim}1.116kg/cm^2$. The seepage that piping showed, as well as the leakage from the reservoirs are acceptable for the safety management of the reservoir. The maximum horizontal displacement and direction analyzed from the measured inclinometer data gives us very effective information to evaluate the safety in reservoirs. The resistivity monitoring technique, which is obtained on the reservoir crest, is an efficient tool to detect leakage zone. The safety index (SI) was predicted by the resistivity monitoring, and was evaluated to have a safety level of 0.8-1.0 at all reservoirs. Safety evaluations of reservoir through instrument systems are effective when studying the embankment, when the results of the instrument system have been analyzed compositively.

Safety Evaluations of Reservoir Embankment by Instrument System (계측시스템에 의한 저수지 제체의 안정성 평가)

  • Lee, Dal-Won;Kim, Mi-Hyun
    • Proceedings of the Korean Geotechical Society Conference
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    • 2010.03a
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    • pp.840-851
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    • 2010
  • This study analyzed data on the pore water pressure, the ground water level, the horizontal displacement and the resistivity monitoring from instrument system, which is established to evaluate the safety in reservoirs. The pore water pressure in the embankment ranged from $0.035{\sim}1.116kg/cm^2$. The seepage that piping showed, as well as the leakage from the reservoirs are acceptable for the safety management of the reservoir. The maximum horizontal displacement and direction analyzed from the measured inclinometer data gives us very effective information to evaluate the safety in reservoirs. The resistivity monitoring technique, which is obtained on the reservoir crest, is an efficient tool to detect leakage zone. The safety index(SI) was predicted by the resistivity monitoring, and was evaluated to have a safety level of 0.8-1.0 at all reservoirs. Safety evaluations of reservoir through instrument systems are effective when studying the embankment, when the results of the instrument system have been analyzed compositively.

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A simplified directly determination of soil-water retention curve variables

  • Niu, Geng;Shao, Longtan;Guo, Xiaoxia
    • Geomechanics and Engineering
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    • v.23 no.5
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    • pp.431-439
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    • 2020
  • Soil-water retention curve (SWRC) contains key information for the application of unsaturated soil mechanics principles to engineering practice. The SWRC variables are commonly used to describe the hydro-mechanics of soils. Generally, these parameters are determined using the graphical method which can be time consuming. The SWRC is highly dependent on the pore size distribution (PSD). Theoretically, the PSD obtained by mercury intrusion porosimetry test can be used to determine some SWRC variables. Moreover, the relationship between SWRC and shrinkage curve has been investigated. A new method to determine total SWRC variables directly without curve-fitting procedure is proposed. Substituting the variables into linear SWRC equations construct SWRC. A good agreement was obtained between predicted and measured SWRCs, indicating the validity of the proposed method for unimodal SWRC.

An Analysis on Remediation of Soil Contaminted with Cobalt by Solvent Flushing

  • Kim, Gyenam;Kyungsuk Suh;Huijun Won;Joonbo Shim;Wonzin Oh
    • Nuclear Engineering and Technology
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    • v.32 no.4
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    • pp.342-349
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    • 2000
  • A soil whose texture is silt loam was collected for the study from an area around a nuclear facility in Korea. The equilibrium sorption coefficient between Co$^{2+}$in water and the soil was 1.51/kg, on the other hand, that between Co$^{2+}$ in EDTA and the soil was 0.21/kg. The values calculated by the developed nonequilibrium sorption code corresponded to the experimental values better than those calculated by the existing equilibrium sorption code. When an EDTA solution was used as a solvent to decontaminate Co$^{2+}$ in the soil column, the relative Co$^{2+}$ concentrations of the effluent were higher at 2~10 pore volumes than those of the case using water. The soil in the column was decontaminated by 95.5% of the total amount of Co$^{2+}$ after being flushed with EDTA solution of 20 pore volumes.e volumes.

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The Prediction of Moisture Distribution in Concrete (콘크리트 내부의 수분분포 예측에 관한 연구)

  • 김진근;이칠성
    • Proceedings of the Korea Concrete Institute Conference
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    • 1996.04a
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    • pp.123-128
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    • 1996
  • Water in concrete has an effect on properties of concrete very much, such as shrinkage, creep, fire resistance, durability, freezing and thawing resistance. Therefore predicting the moisture distribution in concrete is very important. And since the diffusion process of water in concrete is strongly dependent on the temperature and pore humidity, the process is highly nonlinear phenomena. In this study, a finite element program which was capable of simulating the moisture distribution in concrete was developed, and differential drying shrinkage due to the water diffusion process was measured at the different positions of concrete. This F.E.M. program is shown that the analytical results of this study are in good agreement with experimental data. Shrinkage strain caused by moisture distribution was increased with the decrease of pore relative humidity.

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Effects of Carbonation on the Microstructure of Cement Materials: Influence of Measuring Methods and of Types of Cement

  • Pham, Son Tung;Prince, William
    • International Journal of Concrete Structures and Materials
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    • v.8 no.4
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    • pp.327-333
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    • 2014
  • The objective of this work was to examine the influence of carbonation on the microstructure of cement materials. Different materials, which were CEM I mortar and paste, CEM II mortar and paste, were carbonated at $20^{\circ}C$, 65 % relative humidity and 20 % of $CO_2$ concentration. The specific surface area and pore size distribution were determined from two methods: nitrogen adsorption and water adsorption. The results showed that: (1) nitrogen adsorption and water adsorption do not cover the same porous domains and thus, we observed conflicts in the results obtained by these two techniques; (2) the CEM II based materials seemed to be more sensible to a creation of mesoporosity after carbonation than the CEM I based materials. The results of this study also helped to explain why observations in the literature diverge greatly on the influence of carbonation on specific surface area.

Effects of Stearic Acid on the Watertightness Properties of the Cementitious Materials (시멘트 재료의 수밀성에 대한 스테아르산의 영향)

  • Na, Seung-Hun;Kang, Hyun-Ju;Song, Myong-Shin
    • Journal of the Korean Ceramic Society
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    • v.46 no.4
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    • pp.365-371
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    • 2009
  • It is well known that the properties of concrete such as the compressive strength, water permeability, water tightness and durability are affected by micro-structure in hardened cement paste. Especially, for durability of concrete, watertightness of cementitious materials is the most critical property among various properties. Recently, many types of materials as organic and/or inorganic materials are used for watertightness of concrete. In this study, The effect of Stearic Acid at $0.5\;wt%{\sim}3.0\;wt%$ adding ratios on the hydration and watertightness property of cement were investigated. And we also discussed the changing of microstructure in hardened cement paste by addition of Stearic Acid. Cement paste with Stearic Acid showed improvement of watertightness by reducing of cement total pore volume and decomposition of Stearic Acid.

An Analysis on the Deformation of Clayey Foundation Using Elasto-Viscoplastic Model (${\cdot}$粘塑性構成式을 使用한 粘性土地盤의 變形解析)

  • Lee, Moon-Soo
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.34 no.2
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    • pp.60-72
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    • 1992
  • This study aims at predicting the behavior of saturated soft clayey foundation subjected to earth structure loads such as tidal dike, embankment etc. by using Biot's consolidation equation coupled with elasto-viscoplastic constitutive model. To validate the computer program developed b author, a case study was performed for the site of Kwang-yang steel works improved by sand drain, where since the beginning of the works, field measurements(settlement, lateral displacement and excess pore water pressure) had been accurately achieved. Comparisons between numerical results and observation values were carried out. The main results obtained are summarized as follows : 1. Settlement and lateral displacement between numerical and observation values show satisfactory accordance. 2. As for the exess pre water pressure, numerical results appear to be larger than observation values, which may be due to the existence of sand seams which were not found during soil investigation. 3. Useful data available for failure prediction of soft foundation can be secured by examining lateral displacement, settlement, exess pore water pressure and stress paths.

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