• Title/Summary/Keyword: Pore structures

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Lateral Earth Pressure Caused by Action on Earth Retaining Wall in Clay Foundation Ground with Consideration of Construction Speed (지중 구조물에 작용하는 측방토압에 대한 성토 재하 속도의 영향)

  • Im Eun-Sang;Lee Kang-Il
    • Journal of the Korean Geotechnical Society
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    • v.20 no.7
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    • pp.57-68
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    • 2004
  • When an embankment is constructed on soft clay ground, the lateral displacement generally called as lateral flow is generated in the foundation ground. It strongly affects stabilities of structures, such as foundation piles and underground pipes, in and on the foundation ground. The lateral earth pressure induced by the lateral flow is influenced by the magnitude and construction speed of embankment, the geometric conditions and geotechnical characteristics of the embankment, and the foundation ground, and so on. Accurate methods for estimating the lateral earth pressure have not ever been established because the lateral flow of a foundation ground shows very complicated behavior, which is caused by the interaction of shear deformation and volumetric deformation. In this paper, a series of model tests were carried out in order to clarify effects of construction speed of an embankment on the lateral earth pressure in a foundation ground were design. It was found that the magnitude and the distribution of the lateral earth pressure and its change with time are dependent on the construction speed of the embankment. It was found that a mechanism for the lateral earth pressure was generated by excess pore water pressure due to negative dilatancy induced by shear deformation under the different conditions of construction speeds of embankments.

Service Life Assessment and Restrain Methods of Carbonation Attack on PC Outer Wall of LNG Storage Tanks (탄산염해에 대한 LNG 저장탱크 PC 외부벽체의 수명평가 및 억제방안)

  • Lee, Seung-Rim;Song, Il-Hyun;Kim, Han Sang
    • Journal of the Korean Institute of Gas
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    • v.18 no.2
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    • pp.73-80
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    • 2014
  • The objective of this paper is to assess the service life and retrain methods of specimens, which were subjected to carbonation attack, obtained from mix proportion of Sam-cheok LNG storage tank under construction. As the results, accelerated-carbonation penetration depths of 7, 28, 56 ages indicated 4.45, 9.19, 13.37mm, and even considering for cover depths of steel of LNG storage tank under real operation, it was enough. In addition, with carbonation velocity coefficient calculated by carbonation penetration depths, the service life to design cover depth(70, 80, 90, 100mm) of PC outer tank of LNG storage tank was 779, 1017, 1287, 1589 years and 466, 609, 771, 951 years, respectively, considering the $CO_2$ concentration in air which account for the 0.03% and 0.05%. Also, the restrain methods to carbonation attack were feasible through controlling the factors affecting the changes of hydration products such as $Ca(OH)_2$, ion composition in pore solution and matter mobility of organization structures within hardened concrete.

The Effects of Silica Sol and Modified Latex on the Concrete Surface Protection Cement Mortar for Improvement of Durability of Concrete (콘크리트 내구성 향상을 위한 표면 보호용 시멘트 모르타르에서 실리카 및 개질 라텍스의 영향)

  • Kim, Yong-Hoon;Jeaong, Cheol-Soo;Song, Myong-Shin;Lee, Woong-Geol
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.12
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    • pp.715-722
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    • 2019
  • The durability of concrete structures deteriorates due to the corrosion of rebars and concrete deterioration by harmful ions (CO32-, Cl-, SO42-) penetrating and diffusing from the outside into concrete. Therefore, the use of surface-protection finishing mortar is very important for preventing or delaying the deterioration of concrete. In this study, the possibility of the prevention of deterioration or delay of deterioration of concrete was investigated using natural latex modified with silica sol and calcium ions for cement mortar, which can be used to repair the mortar of deteriorated concrete or for finishing the mortar of concrete. As a result, fine calcium silicate hydrate was formed in the pores of the cement material due to the calcium ions and silica sol components contained in the modified latex component that reduce the pore distribution of the cement mortar, thereby reducing the penetration and diffusion of harmful ions (CO32-, Cl-, and SO42-). Furthermore, the latex component was found to be present in the pores of the cement to improve the alkali resistance and carbonation resistance.

Investigation of Degradation Mechanism of High Alumina Refractory in a Coal Gasifier (석탄 가스화기에서의 고알루미나 내화물의 손상 기구 규명)

  • Kim, Yuna;Lee, Jae Goo;Oh, Myongsook S.
    • Applied Chemistry for Engineering
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    • v.20 no.6
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    • pp.638-645
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    • 2009
  • High alumina refractory used in a coal gasifier was analyzed and the degradation mechanism by molten slag was investigated. The depth of refractory severely damaged by slag varied between 12~40 mm, including the adhered slag layer. The sample also showed the cracks formed in parallel to the slag/refractory interface. The degree of degradation varied with the micro-structures in the refractory. Fused alumina grains showed the uneven boundary and pore formation just along the edges, while the tablet alumina showed the slag penetrated between sintered alumina around which the formation of Al-Fe phase was observed. Calcium aluminate cements were not observed at the high temperature zone near the slag/refractory interface, probably due to dissolution into molten slag. Around large grains of alumina, rod shape alumina, which appeared to be recrystallized during cooling, were observed, and large pores were also formed around those grains. Therefore, in high alumina refractories, hot molten slag dissolves the bonding phase and rod-shape alumina phase is recrystallized upon cooling. During this process, cracks are developed due to structural change, and the degradation occurs by physical causes such as structural spalling.

Electrochemical Performances of Acid-Treated and Pyrolyzed Cokes According to Acid Treatment Time (산처리 시간별 산화 코크스와 열분해 코크스의 전기화학적 거동)

  • Kim, Ick-Jun;Yang, Sunhye;Jeon, Min-Je;Moon, Seong-In;Kim, Hyun-Soo
    • Applied Chemistry for Engineering
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    • v.19 no.4
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    • pp.407-412
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    • 2008
  • As an activation procedure, in this study, the oxidation treatment of needle cokes with a dilute nitric acid and sodium chlorate $(NaClO_3)$, combined with heat treatment, was attempted. The structures of acid-treated and pyrolyzed coke were examined with XRD, FESEM, elemental analyzer, BET, and Raman spectroscopy. The behavior of double layer capacitance was investigated with the analysis of charge and discharge. The structure of needle coke treated with acid was revealed to a single phase of (001) diffraction peak after 24 h. On the other hand, thecoke oxidized by heat treatment was reduced to a graphite structure of (002) at $300^{\circ}C$. The distorted graphene layer structure, derived from the process of oxidation and reduction of the inter-layer, makes the pores by the electric field activation at the first charge, and generates the double layer capacitance from the second charge. The cell using pyrolyzed coke with 24 h acid treatment and $300^{\circ}C$ heat treatment exhibited the maximum capacitance per weight and volume of 33 F/g and 30 F/mL at the two-electrode system in the potential range of 0~2.5 V.

Cyclic Simple Shear Test Based Design Liquefaction Resistance Curve of Granular Soil (반복단순전단시험에 기반한 조립토의 설계 액상화 저항 곡선 개발)

  • Saeed-ullah, Jan Mandokhail;Park, Duhee;Kim, Hansup;Park, Ki-Chun
    • Journal of the Korean Geotechnical Society
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    • v.32 no.6
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    • pp.49-59
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    • 2016
  • We develop liquefaction resistance curves, which represent the correlation between cyclic resistance ratio (CRR) and number of cycles (N) to estimate the build-up of residual excess pore pressure from simple shear tests performed for this study and also from published literature. The liquefaction curve is calculated from two models. The comparisons show that one of the models is not reliable because it underestimates CRR. The scatter of the data is shown to be significantly reduced when CRR is normalized to the resistance ratio at N = 15 ($CRR_{N=15}$). Use of the normalization is particularly useful because CRR can be easily estimated from field tests. From normalization, we propose mean, upper, and lower curves. The corresponding design equation and its parameters are also proposed. We believe that the proposed curves can be used for effective stress site response analyses and evaluation of the seismic performance of port structures.

The Influence of Nano Synthesized Polymer Paint on Durability of Concrete (나노합성 무기질 폴리머계 표면처리제가 콘크리트의 내구성에 미치는 영향)

  • Beak, Jong-Myeong;Park, Youg-Keol
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.20 no.1
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    • pp.56-63
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    • 2016
  • This experiment was compared and analyzed between the original surface paint through chloride penetration, neutralization, freeze-thaw and chemical corrosion resistance measuring internal structure and volume of voids in order to evaluate the effect of increase in durability of the newly modeled nano synthesized polymer paint painted on concrete surface which results improvement on air permeability to increase the durability of concrete structures. The test result of measuring volume of void and inner structure, concrete, spreaded with nano synthesized polymer paint, showed decreasing trend of pore volume in the range of less than $0.1{\mu}m$ and more than $0.3{\mu}m$. Also, using an electron microscope inside showed tightness of hydration texture. Chloride penetration depth of concrete, painted with nano synthesized polymer paint, was decreased more than 92% compared to non-painted concrete and 70% with water-based epoxy painted concrete. Especially, chemical corrosion resistance test set with aqueous solution of 5% sulfuric acid, non-painted concrete and water-based epoxy painted concrete showed weight loss of 4% after dipping for 12 days. On the other hand, concrete painted with nano synthesized polymer paint showed 1.7% weight loss under the same condition. Also, it showed great result of appearance under the criteria of Tsivilis et al.

Sustained Release of Proteins Using Small Intestinal Submucosa Modified PLGA Scaffold (SIS로 개질된 PLGA 담체에서의 단백질의 서방화)

  • Ko, Youn-Kyung;Choi, Myung-Kyu;Kim, Soon-Hee;Kim, Geun-Ah;Lee, Hai-Bang;Rhee, John-M.;Khang, Gil-Son
    • Polymer(Korea)
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    • v.32 no.3
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    • pp.199-205
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    • 2008
  • In this study, we fabricated poly (lactide-co-glycolide) (PLGA) scaffold modified with small intestinal submucosa (SIS) as a drug delivery matrix of bioactive molecules. SIS derived from the submucosa layer of porcine intestine has been widely used as biomaterial because of low immune response. PLGA scaffold was prepared by the method of solvent casting/salt leaching. Novel composite scaffolds of SIS/PLGA were manufactured by simple immersion method of PLGA scaffold in SIS solution under vacuum. SEM observation shows that PLGA and SIS/PLGA scaffolds have interconnective and open pores. Especially, SIS/PLGA scaffold showed that micro-sponge of SIS with interconnected pore structures were formed in the pores of PLGA scaffold. In order to assay release profile of proteins, we manufactured FITC conjugated BSA loaded PLGA and SIS/PLGA scaffold. And the release amount was identified by fluorescence intensity using the fluorescence spectrophotometer. The initial burst of BSA containing SIS/PLGA scaffolds was lower than that of PLGA scaffolds resulting in constant release. And release of BSA in SIS/PLGA scaffold was fast and incremental because of the increased content of BSA. In conclusion, we confirmed that penetrated SIS solution prevented the initial burst of BSA and PLGA modified with SIS scaffold is useful as protein carriers with controlled release pattern.

Studies on the Fine Structures of Mouse Oocyte Whose Maturation has been suppressed in Vitro by Dibutyryl Cyclic AMP (Dibutyryl Cyclic AMP에 의해 成熟이 抑制된 Mouse 卵子의 微細構造에 관한 硏究)

  • 崔林淳
    • The Korean Journal of Zoology
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    • v.18 no.2
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    • pp.87-101
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    • 1975
  • Electron microscopic studies on the ultrastructure of the mouse oocyte were made to investigate the inhibition of germinal vesicle breakdown by dibutyryl cAMP. The nuclear membrane of the dibutyryl cAMP-treated oocyte is characterized by a decreased degree of folding, maintains the normal double membrane structure, and shows an increased occurrence of the nuclear pore. It is suggested that these may be related to the suppression of the maturation of oocytes at the germinal vesicle. Mitochondria in the control cell were shown to be spread evenly throughout the cytoplasm and structurally underdeveloped or transitionary having little cristae development. On the contrary, mitochondria in the treated oocyte were found to be localized mainly around the nucleus and to show a greater extent of cristae development. The oocyte treated with dibutyryl cAMP appears to have fewer and structurally simpler lysosomes as compared to the control. The Golgi complex in the control oocyte exhibits the typical granular and lamellar structure, whereas that in the treated cell is poorly developed. Many multivesicular bodies, tonofilaments, and free ribosomes were observed in the control as well as in treated cells. The microvilli become structurally irregular, and a development of the perivitelline space is apparent in the treated oocyte. It is concluded that there is no basic difference in the ultrastructure between the oocytes treated with dibutyryl cAMP for 24 hours in the medium and those collected directly from the follicle. However, the finding that dibutyryl cAMP induces a development of more pores along the nuclear membrane strongly suggests the possibility that this compound inhibits the maturation of oocytes by influencing the permeability of the nuclear membrane.

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Pollen Characteristics of Flower Type and Cross Compatibility with Table Grape in Vitis amurensis Rupr. (왕머루의 화형에 따른 화분특성 및 포도의 교배화합성)

  • Park, Young-Sik;Kim, In-Jong;Jeong, Byeong-Chan;Heo, Jae-Yoon;Park, Sung-Min
    • Korean Journal of Medicinal Crop Science
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    • v.13 no.6
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    • pp.234-240
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    • 2005
  • This study was conducted to identify cross compatibility with table grape and pollen characteristics by flower type in Vitis amurensis Rupr. (GW-22, GW-45, GW-56, GW-200, GW-202 and GW-300) collected in Gangwon area. Flower structure, germinability and morphology of pollen, and cross compatibility with table grape were examined. Flowers of GW-22 and GW-56 had an aborted gynoecium and five erect fdaments, and all of them was male. The percentage of pollen germination of GW-22 and GW-56 on the agar medium was 27.6-29.8%. Flowers of GW-45, GW-200, GW-202 and GW-300 had well-developed pistils and five stamens with curled filaments. The percentage of pollen germination of female plant on the agar medium was 0%. Pollen grail)s from GW-22 and GW-56 (male flower) have symmetrically distributed three furrows on their surface and each furrow contains a germ pore at the equatorial level (Tricolporated). GW-45, GW-200, GW202, and GW-300 (Female flower) produced pollen grains with no germinative structures (acolporated). In self-pollina-tion of female flowers, berries of clusters were no berry and no seed. Therefore, flower structure in V. amurensis proved to be that of other dioecious Vitis species. In cross combination of female and male flower of V. amurensis made normal seeds. In cross combination of table grape and V. amurensis of male flower made normal seeds. But, in cross combination of female flower of V. amurensis did not make seeds. Therefore, V. amurensis was cross compatible with vitis spp, and V. amurensis varieties may contribute to breeding studies of Vitis spp.