• Journal of the Korean Geotechnical Society
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• v.38 no.3
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• pp.27-34
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• 2022

Since water flow in the ground depends on the pore structure composed of soil grains, equations to predict the hydraulic properties based on the grain size have low accuracy. This paper presents a methodology to compute constriction-pore size distribution by Silveria's method and estimate saturated and unsaturated hydraulic properties of soils. Well-graded soil shows a uni-modal pore size distribution, and poor-graded soil does a bimodal distribution. Among theoretical models for saturated hydraulic conductivity using pore size distribution, Marshall model is well-matched with experimental results. Model formulas for soil-water characteristic curves and unsaturated hydraulic conductivity using the pore size distribution are proposed for hydraulic analysis of unsaturated soil. Continuous research is needed to select a model suitable to estimate hydraulic properties by applying the developed model formulas to various soils.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.26 no.5A
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• pp.927-934
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• 2006

According to the high demand of concrete structures with high performance, various studies have examined on the high performance concrete, especially high strength concrete. Various admixtures are required to produce high strength concrete and silica fume has been the most popular admixture. Recently, however, metakaolin, which is similar to silica fume in properties but cheaper, has been introduced to high strength concrete. This study conducted XRD and SEM analyses on a cement paste specimens to clarify metakaolin's performance in pozzolan. Additionally, a concrete specimens were fabricated to analyze its pore structure using Mercury Intrusion Porosimetry and its correlation to the compressive strength. In result, it was found that the average diameter of pore reduced and compressive strength increased as more metakaolin content was added. In addition, a regression analysis of $10nm{\sim}10{\mu}m$ pore and compression strength revealed that these two factors had a high correlation of about 0.93 and 10~15% of metakaolin replacement was most appropriate.

• Korean Journal of Mineralogy and Petrology
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• v.34 no.4
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• pp.209-218
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• 2021

Studies of pore structure in shale gas reservoirs are essential to increase recovery rates, which is in the spotlight concerning unconventional resources. In this study, the distribution of pores in shale gas reservoir sample were observed using Scanning Electron Microscope Particle Analysis (SELPA), which is appropriate to analyze the distribution of particle or shape for sample in large area. A sample from the A-068 borehole drilled in the Liard Basin was analyzed; calcite is the main mineral. The pore size ranges from tens of nanometers to hundreds of micrometers and the contribution of each pore size to overall sample porosity was determined using SELPA. The distribution of pores was determined by observing the surface in the same area at magnifications of ×1000, ×3000 and ×5000. Pores less than 100 nm were observed at high magnifications and confirm that small-scale pore distribution can be analyzed and identified rapidly using SELPA. The method introduced in this study will be useful to understand pore structures in unconventional reservoirs.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2017.05a
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• pp.162-163
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• 2017

This study investigated the properties of lightweight foamed concrete by using synthetic foaming agent and artificial lightweight aggregate. The effects of artificial lightweight sizes on the compressive strength, density and pore structure of the concrete were investigated. The samples were assessed by MIP analysis and simultaneous SEM was used to study their pore distribution. This study showed the improvement of important properties of lightweight foamed concrete. Lower pore distribution and correspondingly higher compressive strength values were reached. This is for the purpose of providing basic data for the use of lightweight foamed concrete through improvement on the problem such as unstability, falling in fluidity and the strength of existed foaming agent.

• Korean Journal of Soil Science and Fertilizer
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• v.43 no.4
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• pp.415-423
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• 2010

Pore network models are useful tools to investigate soil pore geometry. These models provide quantitative information of pore geometry from 3D images. This study presents a pore network model to quantify pore structure and hydraulic characteristics. The objectives of this work were to apply the pore network model to characterize pore structure from large images to quantify pore structure, calculate water retention and hydraulic conductivity properties from a three dimensional soil image, and to combine measured hydraulic properties from experiments with calculated hydraulic properties from image. Soil samples were taken from a site located at the Baltimore science center, which is located inside of the city. Undisturbed columns were taken from the site and scanned with a computer tomographer at resolutions of 22 ${\mu}m$. Pore networks were extracted by medial-axis transformation and were used to measure pore geometry from one of the scanned samples. Water retention and unsaturated hydraulic conductivity values were calculated from the soil image. Properties of soil bulk density, water retention and unsaturated hydraulic conductivity were measured from three replicates of scanned soil samples. 3D image analysis provided accurate detailed pore properties such as individual pore volumes, pore length, and tortuosity of all pores. These data made possible to calculate accurate estimations of water retention and hydraulic conductivity. Combination of the calculated and measured hydraulic properties gave more accurate information on pore sizes over wider range than measured or calculated data alone. We could conclude that the hydraulic property computed from soil images and laboratory measurements can describe a full structure of intra- and inter-aggregate pores in soil.

• Proceedings of the Korean Geotechical Society Conference
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• 2006.03a
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• pp.970-979
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• 2006

Construction of underground structure requires higher standard of planning and design specifications than in surface construction. However, high construction cost and difficult working environment limit design level and construction quality. One of the most sensitive factors to be considered are infiltration and external pore-water pressures. Development of pore-water pressure may accelerate leakage and cause deterioration of the lining. In this paper, the development of pore-water pressure and its potential effect on the linings are investigated using physical model tests. A simple physical equipment model with well-defined hydraulic boundary conditions was devised. The deterioration procedure was simulated by controlling both the permeability of filters and flowrate. Development of pore-water pressure was monitored on the lining using pore pressure measurement cells. Test results identified the mechanim of pore-water pressure development on the tunnel lining which is the effect of deterioration of drainage system. The laboratory tests were simulated using coupled numerical method, and shown that the deterioration mechanism can be reproduced using coupled numerical modelling method.

• Bulletin of the Korean Chemical Society
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• v.33 no.5
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• pp.1699-1702
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• 2012

$TiO_2$ nanostructures with various morphologies like cubes, spheres, hexahedral pillars and spherical tubes were synthesized by microwave-assisted hydrothermal process. Each structure was obtained by changing the relative concentrations of titanium tetraisoproxide (TTIP), tetrabutylammonium hydroxide (TBAH) and ethanol. Scanning electron microscopy (SEM), transmission electoron microscopy (TEM), X-ray diffraction and Brunauer-Emmett-Teller (BET) surface area analysis were used to characterize the synthesized $TiO_2$ nanostructures. From these results, it has been proved that $TiO_2$ structure could be controlled to have specific morphology, size, surface area, pore volume and pore size distribution.

• Journal of Powder Materials
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• v.22 no.2
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• pp.129-133
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• 2015

Porous W with controlled pore structure was fabricated by thermal decomposition and hydrogen reduction process of PMMA beads and $WO_3$ powder compacts. The PMMA sizes of 8 and $50{\mu}m$ were used as pore forming agent for fabricating the porous W. The $WO_3$ powder compacts with 20 and 70 vol% PMMA were prepared by uniaxial pressing and sintered for 2 h at $1200^{\circ}C$ in hydrogen atmosphere. TGA analysis revealed that the PMMA was decomposed at about $400^{\circ}C$ and $WO_3$ was reduced to metallic W at $800^{\circ}C$. Large pores in the sintered specimens were formed by thermal decomposition of spherical PMMA, and their size was increased with increase in PMMA size and the amount of PMMA addition. Also the pore shape was changed from spherical to irregular form with increasing PMMA contents due to the agglomeration of PMMA in the powder mixing process.

• Proceedings of the KAIS Fall Conference
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• 2011.05a
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• pp.147-150
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• 2011

A copper-based metal organic framework (MOF) named Cu-BTC, also known as HKUST-1, was successfully synthesized by using a solvothermal method. The properties of the Cu-BTC sample were characterized with Powder X-ray diffraction (XRD) for phase structure, Thermogravimetric analysis (TGA) for thermal stability, Scanning electron microscopy (SEM) for crystal structure, and Nitrogen adsorption-desorption for pore textural structure. The analysis results displayed that the Cu-BTC sample exhibited a good crystal structure with uniform size of octahedral particles. The BET data revealed a high surface area of $1457 \;m^2g^{-1}$ and a pore volume of $0.60\; cm^3g^{-1}$. The Cu-BTCs ample was also studied for $CO_2$ adsorption and exhibited a maximum $CO_2$ adsorption capacity of 170 mg/g of the sorbent (3.8 mol/kg) at $25^{\circ}C$.

• Proceedings of the Korean Nuclear Society Conference
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• 2002.05a
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• pp.232.1-232
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• 2002