• Applied Chemistry for Engineering
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• v.20 no.5
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• pp.465-472
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• 2009

The technologies for improving the capacity of hydrogen storage were investigated and the recent data of hydrogen storage by using various porous carbon materials were summarized. As the media of hydrogen storage, activated carbon, carbon nanotube, expanded graphite and activated carbon fiber were mainly investigated. The hydrogen storage in the carbon materials increased with controlled pore size about 0.6~0.7 nm. In case of catalyst, transition metal and their metal oxide were mainly applied on the surface of carbon materials by doping. Activated carbon is relatively cheap because of its production on a large scale. Carbon nanotube has a space inside and outside of tube for hydrogen storage. In case of graphite, the distance between layers can be extended by intercalation of alkali metals providing the space for hydrogen adsorption. Activated carbon fiber has the high specific surface area and micro pore volume which are useful for hydrogen storage. Above consideration of research, porous carbon materials still can be one of the promising materials for reaching the DOE target of hydrogen storage.

• Horticultural Science & Technology
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• v.29 no.3
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• pp.201-210
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• 2011

This experiment was conducted to investigate physical and chemical characteristics by volume fractions of root media using peatmoss, perlite, and vermiculite, along with effects on the growth of pot chrysanthemums (Dendranthema ${\times}$ grandiflorum 'Vemini') in a C-channel mat irrigation system. To evaluate the physico-chemical properties of 20 root media, the bulk density, particle density, total pore space, pore space, ash content, organic matter, pH, and electrical conductivity were measured and data were analyzed using principal component analysis (PCA). PCA scores revealed that physico-chemical properties changed by the blending of peatmoss, perlite, and vermiculite. The 20 root media were divided into three main groups by hierarchical cluster analysis. At the end of the experiment, the pH and EC of the root media were measured from media divided into four layers. The pH of root media without plants showed a strong linear relationship and the pH of root media with plants increased exponentially. The change of EC in the root medium was indicated as a hyperbolic curve. Plant growth characteristics according to growth in the 20 root media were analyzed by PCA. It was found that the mixing ratios of the root media affected plant growth characteristics. Therefore, mixing ratio is an important factor for pot-plant production in a subirrigation system.

• Journal of the Korean Geosynthetics Society
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• v.9 no.3
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• pp.39-45
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• 2010

When the ground temperature drops below $0^{\circ}C$, wet soils expand due to the ice formation in their porous space. This results in frost heave which causes structural stability problems. Frost heave is attributed by several factors such as physical soil properties and heat transfer including pore water phase change. Due to the complex physical phenomena, reliable and verified multi-dimensional numerical models for frost heave problems are still in a research stage. This study presents an efficient and simple method of overcoming numerical problems associated with sudden jump of heat capacity due to the phase change from water to ice in the pore space. This paper proposes heat transfer equation and finite element method when the saturated soils or porous rocks are subjected to freezing. Numerical analyses using the proposed method agree well with the known closed form solution and the laboratory test results.

• Journal of Plant Biology
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• v.15 no.4
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• pp.1-12
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• 1972

To study on the annual height growth of Pinus densiflora within natural pine stands in central Korea, twenty two pure closed Pinus densiflora stands were selected subjectively in the west-central region of Korea. In each stand twenty trees were chosen randomly. For each tree, abotu ten to fifteen measurements of internodal lengths were made from leader top to trunk base. A total of one hundred thirty four soil samples was collected. Each soil sample was bulked with three subsamples. The ranges of the growth measurements per stand, per tree and per observation were 14.9-35.4cm, 9.0cm-54.4cm and 2.4cm-69.0cm respectively. The total mean value was 23.5cm. The Student-Newman-Keul's tests for the multiple comparison among the mean values of the height growth per stand were very highly significant. The resutls of the analysis of variance of the height growth data for the selected fifteen stands among the twenty two stands indicate that sampling efficiency might be increased to 744% if measurement of the growth were made on fifteen trees per stand from twenty stands instead of twenty trees per stand from fifteen stands. The annual height growths of Pinus densiflora and Pinus koraiensis for the period from 1960 to 1968 were 21.74$\pm$5.29cm (10) and 20.56$\pm$5.59cm (10) respectively. The total means of easily-soluble phosphorus, total nitrogen, loss on ignition and pH for the soil samples were 2.8 ppm, 0.09%, 5.4% and 4.7 respectively. The ranges of those amounts were 18.7-1.7ppm, 0.17-0.05%, 11.6%-3.1%, 3.9-5.1 respectively. The relationship of the annual height growth of P. densiflora to soil was studied in terms of standard partial multiple regression. Among soil properties such as non-capillary pore space, capillary pore space, maximum field capacity, loss on ignition, soil reaction, total nitrogen and easily-soluble phosphoros investigated, the easily soluble phosphorus in one analysis and loss on ignition and soil reaction in the other analysis seem to have significant positive influence on the annual height growth.

• 한국신재생에너지학회:학술대회논문집
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• 2006.06a
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• pp.407-409
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• 2006

Geochemical analyses carried out on samples collected from cores on and near the southern smit of Hydrate Ridge have advanced understanding by providing a clear contrast of the two major modes of marine gas hydrate occurrence. High concentrations (15%-40% of pore space) of gas hydrate occurring at shallow depths (0-40 mbsf) on and near the southern summit are fed by gas migrating from depths of as much as 2km within the accretionary prism. This gas carries a characteristic minor component of C2-C5 thermogenic hydrocarbons that enable tracing of migration pathways and may stabilize the occurrence of some structure II gas hydrate. A structure II wet gas hydrate that is stable to greater depths and temperatures than structure I methane hydrate may account for the deeper, faint second bottom simulating reflection (BSR2) that occurs on the seaward side of the ridge. The wet gas is migrating In an ash/turbidite layer that intersects the base of gas hydrate stability on the seaward side of and directly beneath the southern summit of Hydrate Ridge. The high gas saturation (>65%) of the pore space within this layer could create a two-phase (gas + solid) system that would enable free gas to move vertically upward through the gas hydrate stability zone. Away from the summit of the ridge there is no apparent influx of the gas seeping from depth and sediments are characterized by the normal sequence of early diagenetic processes involving anaerobic oxidation of sedimentary organic matter, initially linked to the reduction of sulfate and later continued by means of carbonate reduction leading to the formation of microbial methane.

• Horticultural Science & Technology
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• v.19 no.2
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• pp.179-185
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• 2001

Throughout the world, physical and chemical analyses of horticultural substrates are carried out in many different ways at the different laboratories. In Europe, standardization in properties and analytical methods of horticultural substrates has been a topic over the last decades. As a result, the CEN methods as European standard methods for the physical and chemical analyses were introduced and the final draft was reported in 1999 by CEN(Committee for European Standardization). Dry matter and moisture content are analyzed after drying samples at $103^{\circ}C$. Laboratory compacted bulk density is analyzed by determining the weight of sample compacted in the test cylinder with constant volume. Dry bulk density, particle density, total pore space, water volume, air volume and volume shrinkage are determined by saturating, draining and drying the sample using double rings and a sand suction table. pH and EC are analyzed by 1:5(sample:distilled water) extraction method on the basis of volume. Organic matter and ash content are determined after drying and combusting the samples. Now, CEN methods are being regarded almost as European standard methods. Further study needs to be carried out for universal applicability of the CEN methods to all the substrates.

• Journal of Korean Tunnelling and Underground Space Association
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• v.11 no.3
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• pp.243-254
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• 2009

Tunnel problems relate to pore water pressure generally occur due to the restriction of groundwater flow into the tunnel which is generally caused by the deterioration of drainage systems. Previous studies have identified the problem as combined mechanical and hydraulic interaction occasions. In this study, detrimental effects of pore water pressure on the lining were investigated using the finite element method considering deterioration of the drainage system. Particularly, double-lined linings with drain-holes are considered. Deterioration of drainage system is represented as blockages of drain-holes. It is identified that the secondary lining ran be influenced by the deterioration of drainage system. It is shown that a tunnel with all drain-holes blocked moved upward, and unbalanced drain-hole blocking may result in torsional behavior of the tunnel which causes significant damages to the secondary linings.

• Tunnel and Underground Space
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• v.25 no.5
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• pp.435-449
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• 2015

Physical and microstructural properties of Pungchon and Maggol limestone were investigated quantitatively during 50 cycles of artificial freezing and thawing test. There were decrease in dry weight and P,S-wave velocity, and increase in absorption rate in both rock types. Porosity, pore volume, equivalent diameter, throat thickness and pore orientation were analyzed using X-ray computed tomography images. Porosity increased, and initiation and expansion of pores were investigated as weathering progresses. Physical and microstructural variation in Maggol limestone was larger than that of Pungchon limestone because Maggol limestone has more pores and microcracks at initial state. As this study analyzes physical and microstructural properties of rock specimens comprehensively, it can be applied to further rock weathering study and can be used as fundamental data of construction and resource development in cold regions.

• Clean Technology
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• v.13 no.2
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• pp.127-133
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• 2007

Celite with enormous pore space inside can hold small molecules and can be well blended with polyethylene (PE) to make a Celite-PE film. Two types of Celite-PE film were prepared, one with Celite surface-treated with surfactant to reduce the hydrophilicity and another with plain Celite. The anti-rust chemical such as dicyclohexylamine, dicyclohexylamine nitrite, or diisopropylamine was allowed to permeate into celite pore in the film, and slowly evaporated to protect the packaged steel material from the rust for a long period of time. The chemical concentration in the different packaging film bags was analyzed by a gas chromatography for a month, and the anti-rust effect on iron labware was compared for a six month period. The Celite film was superior to PE film in anti-rust effect and the long-term anti-rust chemical evaporation.

• Tunnel and Underground Space
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• v.26 no.3
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• pp.181-191
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• 2016

In geological storage of $CO_2$, the behavior of $CO_2$ is influenced by pore network of rock. In this study, the drilling cores from Pohang Basin were analyzed quantitatively using three-dimensional images acquired by X-ray micro computed tomography. The porosities of sandstone specimens around 740 m-depth (T1), 780 m-depth (T2) and 810 m-depth (T3) which were target strata were 25.22%, 23.97%, 6.28%, respectively. Equivalent diameter, volume, area, local thickness of pores inside the sandstone specimens were analyzed. As a result, the microstructural properties of T1 and T2 specimens were more suitable for geological storage of $CO_2$ than those of T3 specimens. The result of the study can be used as input data of the site for decision of injection condition, flow simulation and so on.