• Title/Summary/Keyword: Pore network

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Pore Distribution of Porous Silicon layer by Anodization Process

  • Lee, Ki-Yong;Chung, Won-Yong;Kim, Do-Hyun
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1996.06a
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    • pp.494-496
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    • 1996
  • The purpose of this study is to investigate the effect of process conditions on pore distribution in porous silicon layer prepared by electrochemical reaction. Porous silicon layers formed on p-type silicon wafer show the network structure of fine porse whose diameters are less than 100${\AA}$. In n-type porous silicon, selective growth was found on the pore surface by wet etching process after PR patterning. And numerical method showed high current density on the pore tip. With this result we confirmed that pore formation has two steps. First step is the initial attack on the surface and second step is the directional growth on the pore tip.

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Pore Size Distribution and Chloride Diffusivity of Concrete Containing Ground Granulated Blast Furnace Slag

  • Moon Han-Young;Kim Hong-Sam;Choi Doo-Sun
    • Journal of the Korea Concrete Institute
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    • v.16 no.2 s.80
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    • pp.277-282
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    • 2004
  • In a hardened concrete, diffusion of oxygen, carbon dioxide, aggressive ions, and moisture from the environment to the concrete takes place through the pore network. It is well known that making dense cement matrix enhances the durability of concrete as well as all the characteristics including strength of concrete. In this paper,9 mix concretes with water to cementitious material ratio (40,45, and $50\%$) and replacement ratio of GGBFS (40 and $60\%$ of cement by weight) were studied on the micro-pore structure by mercury intrusion porosimetry and the accelerated chloride diffusion test by potential difference. From the results the average pore diameter and accelerated chloride diffusivity of concrete were ordered NPC > G4C > G6C. It is concluded that there is a good correlation between the average pore diameter and the chloride diffusivity, and the mineral admixtures has a filling effect, which increases the tortuosity of pore and makes large pores finer, on the pore structure of cement matrix due to the latent hydraulic reaction with hydrates of cement.

Porometric Study on the Gas Diffusion Layer in PEMFCs Using Method of Standard Porosimetry (MSP 기법을 적용한 고분자 전해질 연료전지 가스확산층의 포로시메트리 연구)

  • Lee, Yongtaek
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.25 no.2
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    • pp.64-69
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    • 2013
  • The structure of pore network of gas diffusion layers (GDLs) in PEMFCs plays a critical role in determining the transport phenomena of reaction gas as well as generated water. In addition, the interactive characteristics between water and surface of pore are no less important than the structural characteristics of pore network. In this study, porometric investigation is conducted for two kinds of GDL using method of standard porosimetry which enable to distinguish hydrophobic pores from hydrophilic pores of GDLs. The porosity of TGPH-120 decreases by 6% by adding 30 wt.% of PTFE, but the porosity of hydrophilic pores decreases by 12%. The relation of $p_c-S_{nw}$ varies with the addition of PTFE, especially at low $p_c$.

Computer Simulation on the Correlations between the Microwave Quality factor and the Pores inside the Dielectrics (마이크로파 유전체의 내부 기공과 마이크로파 품질계수의 상관관계에 대한 컴퓨터 시뮬레이션)

  • 박재환
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.16 no.4
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    • pp.311-316
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    • 2003
  • Effects of pores on the microwave properties in microwave dielectric ceramics were studied by a computer simulation. Scattering matrix S$\_$21/ obtained from the network analyzer was compared to the S$\_$21/ obtained from the simulation. From electric field distribution, the dominant resonant TE$\_$01$\delta$/ mode could be easily determined. The effects of the porosity and pore size inside the dielectrics on the microwave properties were investigated by the HFSS simulation. When the total pore volume remains constantly, the quality factor decreased as the pore size Increases. As the total pore volume of the dielectrics increased. quality factor decreased.

The Effect of MgO Content on the Preparation of Porous Hydroxyapaite Scaffolds by Polymer Sponge Method (폴리머 스펀지법을 이용한 다공성 수산화아파타이트 지지체 제조 시 MgO 첨가량에 따른 영향)

  • Jin, Hyeong-Ho;Min, Sang-Ho;Lee, Won-Ki;Park, Hong-Chae;Yoon, Seog-Young
    • Korean Journal of Materials Research
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    • v.16 no.11
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    • pp.715-718
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    • 2006
  • Porous hydroxyapatite (HAp) scaffolds have been prepared by using the slurry including HAp and magnesia based on the replication of polymer sponge substrate. The influence of MgO content in slurry on the pore morphology and size, density, porosity, and mechanical strength of porous HAp scaffolds was investigated. The obtained scaffolds with average pore sizes ranging 150 to 300 mm had open, relatively uniform, and interconnected porous structure regardless of MgO content. As the MgO content increased, the pore network frame of scaffolds became to be relatively stronger, even though the pore size was not much changed. The compressive strength of the scaffolds increased rapidly with the increase of MgO content because of increasing the pore wall thickness and density of the scaffolds. As a result, the porosity, density, and compressive strength of the porous HAp scaffolds prepared by the sponge method were significantly affected by the addition of MgO.

Fabrication and Response Characteristics of Multi-walled Carbon Nanotube Film Humidity Sensor (다중벽 탄소나노튜브 습도센서의 제작과 응답특성)

  • Park, Chan-Won
    • Journal of Industrial Technology
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    • v.34
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    • pp.39-43
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    • 2014
  • This paper represents a highly porous MWCNT film electrode with interconnected open pores and demonstrated the possibility of using an MWCNT network film as the top electrode for polyimide capacitive humidity sensors. Polyimide humidity sensors with MWCNT electrodes exhibited about 6 times faster response than equivalent Cr electrode sensors. This result may be due to their percolated pore structures, which make water molecules accessible to all polyimide surfaces. The much faster response times of MWCNT electrode sensors is attributed to the percolated pore network, which allows more water molecules to be accessible to polyimide surfaces.

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Processing of Porous Ceramics with a Cellular Structure Using Polymer Beads

  • Ha, Jung-Soo;Kim, Chang-Sam
    • Journal of the Korean Ceramic Society
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    • v.40 no.12
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    • pp.1159-1164
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    • 2003
  • Two processing routes (i.e., the gel casting and polymer preform routes) using polymer beads were studied to fabricate porous ceramics with a cellular structure. The gel casting route, comprising the gel casting of a ceramic slurry mixed with polymer beads, was found to be inadequate to produce porous ceramic bodies with a interconnected pore structure, due to complete coating of the slurry on the polymer beads, which left just isolated pores in the final sintered bodies. The polymer preform route, involving the infiltration of a polymer beads preform with the ceramic slurry, successfully produced porous ceramics with a highly interconnected network of spherical pores. The pore size of 250-300 $\mu\textrm{m}$ was demonstrated and the porosity ranged from 82 to 86%. This process is advantageous to control the pore size because it is determined by the sizes of polymer beads used. Another feature is the avoidance of hollow skeleton, giving a high strength.

CNN Model for Prediction of Tensile Strength based on Pore Distribution Characteristics in Cement Paste (시멘트풀의 공극분포특성에 기반한 인장강도 예측 CNN 모델)

  • Sung-Wook Hong;Tong-Seok Han
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.36 no.5
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    • pp.339-346
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    • 2023
  • The uncertainties of microstructural features affect the properties of materials. Numerous pores that are randomly distributed in materials make it difficult to predict the properties of the materials. The distribution of pores in cementitious materials has a great influence on their mechanical properties. Existing studies focus on analyzing the statistical relationship between pore distribution and material responses, and the correlation between them is not yet fully determined. In this study, the mechanical response of cementitious materials is predicted through an image-based data approach using a convolutional neural network (CNN), and the correlation between pore distribution and material response is analyzed. The dataset for machine learning consists of high-resolution micro-CT images and the properties (tensile strength) of cementitious materials. The microstructures are characterized, and the mechanical properties are evaluated through 2D direct tension simulations using the phase-field fracture model. The attributes of input images are analyzed to identify the spot with the greatest influence on the prediction of material response through CNN. The correlation between pore distribution characteristics and material response is analyzed by comparing the active regions during the CNN process and the pore distribution.

A Numerical Study on Hydraulic Behavior in a Fractured Rock Medium with Hydromechanical Interaction (수리역학적 상호작용을 고려한 균열암반매질에서의 수리학적 거동에 대한 수치적 연구)

  • Jeong, Woochang;Park, Youngjin
    • Journal of the Korean GEO-environmental Society
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    • v.10 no.2
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    • pp.61-68
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    • 2009
  • This paper presents the numerical investigation for the hydraulic behavior of a fractured rock mass with a hydromechanical interaction which may be considered during the in-situ hydraulic injection test. These experiments consist in a series of flow meter injection tests for fractures existing along an open hole section installed in a borehole, and experimental results are applied for testing a numerical model developed to the analysis and prediction of such hydromechanical interactions. Field experimental results show that conductive fractures form a dynamic and interdependent network, that individual fractures cannot be adequately modeled as independent systems, that new fluid intaking zones generate when pore pressure exceeds the minimum principal stress magnitude in that borehole, and that pore pressures much larger than this minimum stress can be further supported by the circulated fractures. In this study, these characteristics are investigated numerically how to influence the morphology of the natural fracture network in a rock mass by using a discrete fracture ntework model.

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An Analysis of Pore Network of Drilling Core from Pohang Basin for Geological Storage of CO2 (이산화탄소 지중저장을 위한 포항분지 시추코어의 공극구조 분석)

  • Park, Jihwan;Park, Hyeong-Dong
    • Tunnel and Underground Space
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    • v.26 no.3
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    • pp.181-191
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    • 2016
  • In geological storage of $CO_2$, the behavior of $CO_2$ is influenced by pore network of rock. In this study, the drilling cores from Pohang Basin were analyzed quantitatively using three-dimensional images acquired by X-ray micro computed tomography. The porosities of sandstone specimens around 740 m-depth (T1), 780 m-depth (T2) and 810 m-depth (T3) which were target strata were 25.22%, 23.97%, 6.28%, respectively. Equivalent diameter, volume, area, local thickness of pores inside the sandstone specimens were analyzed. As a result, the microstructural properties of T1 and T2 specimens were more suitable for geological storage of $CO_2$ than those of T3 specimens. The result of the study can be used as input data of the site for decision of injection condition, flow simulation and so on.