• Title/Summary/Keyword: Pore distribution

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Preparation of High-purity Porous Alumina Carrier for Gas Sensor (가스센서용 고순도 다공질 알루미나 담체의 제조)

  • 이창우;현성호;함영민
    • Fire Science and Engineering
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    • v.11 no.3
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    • pp.15-23
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    • 1997
  • In this study, the alumina for gas sensor was prepared by anodic oxidation. It was stable thermally and chemically, and pore diameter and pore distribution was uniform. And the shape of pore was cylinderical. The aluminum plate was carried out by the thermal oxidation, chemical polishing and electropolishing pretreatment. The pore diameter, pore size distribution, pore density and thickness of alumina was observed with the change of reaction temperature, electrolyte concentration and current density. As a results, It was able to use for carrier because alumina which was prepared by anodic oxidationhas uniform pore size distribution.

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Studies on the Pore of Coating Layer and Printability(II) -Effects of Pigment Shape on Pore of Coating Layer- (도공층의 공극과 인쇄적성에 관한 연구(제2보) -안료의 입자형태가 미치는 영향-)

  • 김창근;이용규
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.33 no.1
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    • pp.53-61
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    • 2001
  • This study was carried out to evaluate the effect of coating pigments on the printability by investigating the pore structure of casting layer such as the number, size and distribution of pores and the pore rate. The coating structure was mainly determined by the interaction between pigment and binder. It means that the structure of pores was chiefly affected by the shape and size distribution of pigments and their packing rate. The physical properties of pore have close relationships with ink set-off, the speed of ink penetration and printing gloss. The results suggested that the rate and number of pores were greatly affected by the particle size distribution and shape of pigments. The rate of pore increased with the reduction of particle size distribution of pigments. Calcite was effective to improve greatly the printability of coated paper.

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Pore Structure and Reflectivity of Light of Paper

  • Won, Jong-Myoung
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.38 no.3 s.116
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    • pp.7-12
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    • 2006
  • The pore structure of paper was modified by the application of the blending of pulp, refining, and filler particle size and ash content. It was conformed that the reflectivity of paper can be modified by the combination of the above parameters. It was also found that the change of reflectivity of paper was greatly dependent on the pore structure, such as average pore size, pore size distribution and porosity. The average pore size was decreased with addition of HwBKP, but the smallest average pore size was obtained from the addition of 80% HwBKP Refining of pulp decreased both average pore size and the reflectivity of paper. The pore size distribution of filled paper can be varied by the combination of filler particle size and ash content

Estimating Hydraulic Properties of Soil from Constriction-pore Size Distribution (수축공극크기분포를 이용한 지반의 수리학적 물성치 산정)

  • Shin, Hosung
    • Journal of the Korean Geotechnical Society
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    • v.38 no.3
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    • pp.27-34
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    • 2022
  • Since water flow in the ground depends on the pore structure composed of soil grains, equations to predict the hydraulic properties based on the grain size have low accuracy. This paper presents a methodology to compute constriction-pore size distribution by Silveria's method and estimate saturated and unsaturated hydraulic properties of soils. Well-graded soil shows a uni-modal pore size distribution, and poor-graded soil does a bimodal distribution. Among theoretical models for saturated hydraulic conductivity using pore size distribution, Marshall model is well-matched with experimental results. Model formulas for soil-water characteristic curves and unsaturated hydraulic conductivity using the pore size distribution are proposed for hydraulic analysis of unsaturated soil. Continuous research is needed to select a model suitable to estimate hydraulic properties by applying the developed model formulas to various soils.

Pore Size Distribution and Reflectivity of Light of Paper

  • Won, Jong-Myoung;Park, Bong-Sun;Park, Kyung-Ouk
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2006.06b
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    • pp.479-484
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    • 2006
  • The pore structures of paper were modified by the application of the blending of pulp, refining, and filler particle size and ash content. It was conformed that the reflectivity of paper can be modified by the combination of above parameters. It was also found that the modifications of reflectivity of paper were very close relation with pore structure, such as average pore size, pore size distribution and porosity. The average pore size was decreased with addition of HwBKP, but showed smaller particle size than those made from 100% HwBKP. Refining of pulp decreased both average pore size and the reflectivity of paper. The pore size distribution of filled paper can be varied by the combination of filler particle size and ash content.

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Evaluation of Pore Size Distribution of Berea Sandstone using X-ray Computed Tomography (X-ray CT를 이용한 베레아 사암의 공극크기분포 산정)

  • Kim, Kwang Yeom;Kim, Kyeongmin
    • The Journal of Engineering Geology
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    • v.24 no.3
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    • pp.353-362
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    • 2014
  • Pore structures in porous rock play an important role in hydraulic & mechanical behaviour of rock. Porosity, size distribution and orientation of pores represent the characteristics of pore structures of porous rock. While effective porosity can be measured easily by conventional experiment, pore size distribution is hard to be quantified due to the lack of corresponding experiment. We assessed pore size distribution of Berea sandstone using X-ray CT image based analysis combined with associated images processing, i.e., image filtering, binarization and skeletonization subsequently followed by the assessment of local thickness and star chord length. The aim of this study is to propose a new and effective way to evaluate pore structures of porous rock using X-ray CT based analysis for pore size distribution.

Realistic pore structure of Portland cement paste: experimental study and numerical simulation

  • Ma, Hongyan;Li, Zongjin
    • Computers and Concrete
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    • v.11 no.4
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    • pp.317-336
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    • 2013
  • In this study, the pore structure of Portland cement paste is experimentally characterized by MIP (mercury intrusion porosimetry) and nitrogen adsorption, and simulated by a newly developed status-oriented computer model. Cement pastes with w/c=0.3, 0.4 and 0.5 at ages from 1 day to 120 days are comprehensively investigated. It is found that MIP cannot generate valid pore size distribution curves for cement paste. Nevertheless, nitrogen adsorption can give much more realistic pore size distribution curves of small capillary pores, and these curves follow the same distribution mode. While, large capillary pores can be effectively characterized by the newly developed computer model, and the validity of this model has been proved by BSE imaging plus image analysis. Based on the experimental findings and numerical simulation, a hypothesis is proposed to explain the formation mechanism of the capillary pore system, and the realistic representation of the pore structure of hydrated cement paste is established.

Mapping Particle Size Distributions into Predictions of Properties for Powder Metal Compacts

  • German, Randall M.
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.704-705
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    • 2006
  • Discrete element analysis is used to map various log-normal particle size distributions into measures of the in-sphere pore size distribution. Combinations evaluated range from monosized spheres to include bimodal mixtures and various log-normal distributions. The latter proves most useful in providing a mapping of one distribution into the other (knowing the particle size distribution we want to predict the pore size distribution). Such metrics show predictions where the presence of large pores is anticipated that need to be avoided to ensure high sintered properties.

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Adsorption of Carbon Dioxide onto Tetraethylenepentamine Impregnated PMMA Sorbents with Different Pore Structure

  • Jo, Dong Hyun;Park, Cheonggi;Jung, Hyunchul;Kim, Sung Hyun
    • Korean Chemical Engineering Research
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    • v.53 no.3
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    • pp.382-390
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    • 2015
  • Poly(methyl methacrylate) (PMMA) supports and amine additives were investigated to adsorb $CO_2$. PMMA supports were fabricated by using different ratio of pore forming agents (porogen) to control the BET specific surface area, pore volume and distribution. Toluene and xylene are used for porogens. Supported amine sorbents were prepared by wet impregnation of tetraethylenepentamine (TEPA) on PMMA supports. So we could identify the effect of the pore structure of supports and the quantity of impregnated TEPA on the adsorption capacity. The increased amount of toluene as pore foaming agent resulted in the decreased average pore diameter and the increased BET surface area. Polymer supports with huge different pore distribution could be fabricated by controlling the ratio of porogen. After impregnation, the support with micropore structure is supposed the pore blocking and filling effect so that it has low $CO_2$ capacity and kinetics due to the difficulty of diffusing. Macropore structure indicates fast adsorption capacity and low influence of amine loading. In case of support with mesopore, it has high performance of adsorption capacity and kinetics. So high surface area and meso-/macro- pore structure is suitable for $CO_2$ capture.

Effect of Hydrolytic Temperature on Pore Structure of Alkoxide-derived Aluminas (Alkoxide 법으로 합성한 알루미나의 동공구조에 미치는 가수분해 온도의 영향)

  • 조정미;정필조
    • Journal of the Korean Ceramic Society
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    • v.25 no.3
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    • pp.217-224
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    • 1988
  • Pore structures of Alkoxide-derived aluminas are investigated by BET Nitrogen Sorption method. Aluminas are derived from hydrolysis of aluminum isopropoxide at 3$^{\circ}$and 8$0^{\circ}C$ with stoichiometric quantities of water in use. The resulting hydrolysates are then subjected to thermal treatment for a fixed period of time from 200$^{\circ}$to 50$0^{\circ}C$ in gradual fashions. The hydrolysates obtained at 3$^{\circ}C$ increase their pore volumes with increasing heat treatment, exhibiting their pore-size distributio as twinpeaked. In contrast, the reverse is true to the hydrolysates obtained at 8$0^{\circ}C$, showing their pore size distribution as single-peaked. This suggests that the pore shapes of the former shall be slit-shaped, whilst whose as the latter shall be of a ink-bottle shape. All the evidence indicates that the hydrolytic temperatures play an important role not only in determining the pore shapes of the alumina samples, but in controlling the liberation of structural water in the alumina layers. It is also, surmized that the subsequent heat treatment may at best affect the mode of pore size distribution for the resulting alumina product(s).

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