• Korean Journal of Fisheries and Aquatic Sciences
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• v.23 no.3
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• pp.215-224
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• 1990

Finite element model capable of solving coupled deformation-fluid diffusion equations for the fully saturated porous medium was developed using Galerkin's residual method. This model was used to study the mechanical and hydraulic behaviors of unconsolidated sediment near South Harbor, Pusan. The vertical displacement of top surface clay sediment, when subjected to the external load, is significantly affected by the excessive pore pres- sure buildup and its decay due to the pore fluid diffusion. The sand deposit overlain by the much less permeable clay layer serves as a flow channel. Consequently, the fluid diffusion due to pore pressure difference is significantly facilitated, which also affects the diffusion-dependent sediment deformation.

• The Journal of Engineering Geology
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• v.29 no.4
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• pp.367-381
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• 2019

We investigate pore pressure conditions and reservoir compaction associated with oil and gas production using 3 different permeability models, which are all based on one-dimensional radial flow diffusion model, but differ in considering permeability evolution during production. Model 1 assumes the most simplistic constant and invariable permeability regardless of production; Model 2 considers permeability reduction associated with reservoir compaction only due to pore pressure drawdown during production; Model 3 also considers permeability reduction but due to the effects of both pore pressure drawdown and coupled pore pressure-stress process. We first derive a unified stress-permeability relation that can be used for various sandstones. We then apply this equation to calculate pore pressure and permeability changes in the reservoir due to fluid extraction using the three permeability models. All the three models yield pore pressure profiles in the form of pressure funnel with different amounts of drawdown. Model 1, assuming constant permeability, obviously predicts the least amount of drawdown with pore pressure condition highest among the three models investigated. Model 2 estimates the largest amount of drawdown and lowest pore pressure condition. Model 3 shows slightly higher pore pressure condition than Model 2 because stress-pore pressure coupling process reduces the effective stress increase due to pore pressure depletion. We compare field data of production rate with the results of the three models. While models 1 and 2 respectively overestimates and underestimates the production rate, Model 3 estimates the field data fairly well. Our result affirms that coupling process between stress and pore pressure occurs during production, and that it is important to incorporate the coupling process in the permeability modeling, especially for tight reservoir having low permeability.

• Journal of Korean Society of Water and Wastewater
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• v.33 no.3
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• pp.205-213
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• 2019

Batch adsorption tests were performed to evaluate the applicability of adsorption kinetic model by using hydrogel chitosan bead crosslinked with glutaraldehyde (HCB-G) for Cu(II) as cation and/or phosphate as anion. Pseudo first and second order model were applied to determine the sorption kinetic property and intraparticle and Boyd equation were used to predict the diffusion of Cu(II) and phosphate at pore and boundary-layer, respectively. According to the value of theoretical and experimental uptake of Cu(II) and phosphate, pseudo second order is more suitable. On comparison with the value of adsorption rate constant (k), phosphate kinetic was 2-4 times faster than that of Cu(II) at any experimental condition indicating the electrostatic interaction between ${NH_3}^+$ and phosphate is dominated at the presence of single component. However, when Cu(II) and phosphate simultaneously exist, the value of k for phosphate was sharply decreased and then the difference was not significant. Both diffusion models confirmed that the sorption rate was controlled by film mass transfer at the beginning time (t < 3 hr) and pore diffusion at next time section (t > 6 hr).

• Journal of the Korean Institute of Gas
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• v.8 no.3 s.24
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• pp.43-51
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• 2004

In this study, gas permeation and separation characteristics of $CO_2$ and $N_2$ on nano-porous TPABr(Tetrapropylammoniumbromide) templating silica/alumina composite membrane were studied by using GMS (Generalized Maxwell Stefan) model. Since the transport mechanisms of meso-porous alumina support are Knudsen diffusion and viscous diffusion(or poiseulle flow), they can be identified by DGM (dusty gas model). The transport mechanism of TPABr templating silica layer, which would contribute mainly to the separation of $N_2/CO_2$ mixture, showed surface diffusion rather than pore diffusion. Therefore, the oermeationjseparation mechanisms in multi-component suface diffusion were successfully analyzed by the GMS model. In the separation of $N_2/CO_2$ mixture using the composite membrane, $CO_2$, the strongadsorbate, was permeated through the membrane more than Na due to the pore-blocking phenomena of $CO_2$ by adsorption isotherm and solace diffusion.

• Proceedings of the Korean Geotechical Society Conference
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• 2006.10a
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• pp.481-489
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• 2006

Two dimensional diffusion model test was conducted to investigate the sedimentation properties and consolidation process of reclaimed ground using dredging coarse soil which is composed of passing amount 20 percentage and 45 percentage of #200 sieve size respectively. The passing amount of #200 sieve size affected on sedimentation properties. The coarse soil which is passing amount of 20 percent showed that the sedimentation structure was layered type and passing amount of 45 percentage was wall-partition type according diffusion distance. Furthermore, the water content of surface and section, and distribution of fine soil were changed according to diffusion distance. and the change amount of pore water pressure and strength property when soil is diffused, segregated and accumulated can be applied efficiently in design of dredging and reclamation.

• Environmental Engineering Research
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• v.9 no.1
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• pp.45-50
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• 2004

• Environmental Engineering Research
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• v.9 no.1
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• pp.38-44
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• 2004

• Transactions of the Korean hydrogen and new energy society
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• v.9 no.3
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• pp.119-125
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• 1998

The modified statistical-mechanical theory for dense fluid mixtures of rigid spheres has been applied to rigid sphere fluids in the nonoverlapping pore model. The resulting expressions for the partition coefficient and diffusivity illustrate the influence of steric hindrance on the thermodynamic and transport properties in such systems. The open membrane model without the size-exclusion and shielding effects shows considerable overestimation of the diffusion flux when the effective mean pore radii of the order of $20{\AA}$ or less are involved. Theoretical predictions investigated here were also compared with experimental data for hydrogen gases in inorganic porous membranes and it was observed a qualitative agreement in the low pressure limit.

• Journal of environmental and Sanitary engineering
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• v.11 no.3
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• pp.29-35
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• 1996

Numerical solutions were obtained to the model equations for various parameters characterizing the pore structure, effective internal diffusion and the chemical reaction constant. The conversion was decreased with the cause of pore closure at the surface of reacting particles, reduction of porosity, surface area of reaction and effective diffusion coefficient in the solid with the progress of reaction. Total conversion was strongly depend on the local conversion at surface. According to the decreasing of impregnated concentration of the copper oxide and the increase of the flue gases concentration, total conversion was increased. And the conversion were affected by gas flow rate and pore size distribution of the reacting solid.

• Proceedings of the Korea Concrete Institute Conference
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• 2002.10a
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• pp.385-390
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• 2002

Autogenous shrinkage of concrete has been defined as decrease in volume due to hydration cement, not due to other causes such as evaporation, temperature change and external load and so on. For ordinary concretes, autogenous shrinkage is so little compared to the other deformations that it has been dignored. It has recently been proved, however, that autogenous shrinkage considerably increase with decrease in water to cement ratio. And it has been reported that cracking can be caused by autogenous shrinkage, when high- strength concretes were used. In this study, we propose an analytical system to represent autogenous shrinkage in cement paste in order to control crack due to autogenous shrinkage. The system is composed with the hydration model and pore structure model. Contrary to the usual assumption of uniform properties in the hydration progress, the hydration model to refine Tomosawa's represents the situation that inner and outer products are made in cement paste. The pore structure model is based upon the physical phenomenon of ion diffusion in cement paste and chemical phenomenon of hydration in cement particle. The proposed model can predict the pore volume ratio and the pore structure in cement paste under variable environmental conditions satisfactorily The autogenous shrinkage prdiction system with regard to pore structure development and hydration at early ages for different mix-proportions shows a reasonable agreement with the experimental data.