• 제목/요약/키워드: Pore diameter

검색결과 496건 처리시간 0.03초

활성탄소섬유의 미세기공 특성화 (Characterization of the Microporosity of Activated Carbon Fiber)

  • 진항교;이정민;유승곤
    • 한국진공학회지
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    • 제2권4호
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    • pp.491-500
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    • 1993
  • The adsorption of nitrogen (77K) and carbon dioxide(273K) was performed on a series of activated carbon fiber. Theadsorption iotherm of nitrogen was typical type 1 and that of carbon dioxide was convex. As the specific surface area increases, there are linear increases in BET constant C mean pore diameter, the width of pore size distribution, wide micropore volume, total micropore volume, total pore volume and external surface area, however, narrow micropore volume was nealy constant . The total micorpore volume fraction in total pore volume is above 97%.

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다공성소결윅구조에 따른 루프 히트파이프에서 압력손실의 이론적 분석 (Theoretical Analysis of the Pressure Drop in Loop Heat Pipe by Sintered Porous Wick Structure)

  • 이기우;이욱현;박기호;이계중;전원표;인현만
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2004년도 춘계학술대회
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    • pp.1225-1230
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    • 2004
  • In this paper, the pressure drops were investigated according to the sintered porous wick structure in loop heat pipe(LHP) by theoretical analysis. LHP has the wick only in evaporator for the circulation of working fluid, so utilizes porous wick structure which pore diameter is very small for large capillary force. This paper investigates the effects of different parameters on the pressure drops of the LHP such as particle diameter of sintered porous wick, wick porosity, vapor line diameter, thickness of wick and heating capacity. Working fluid is water and the material of sintered porous wick is copper. According to the these different parameters, capillary pressure, pressure drop in wick were analized by theoretical design method of LHP.

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양극산화를 이용한 알루미나 나노세공 멤브레인의 제조 (Fabrication of Alumina Membrane Using Anodic Oxidation Process)

  • 임완순;조경철;조유석;최규석;김도진
    • 한국재료학회지
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    • 제13권9호
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    • pp.593-597
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    • 2003
  • Anodic aluminum oxide (AAO) membrane was made of aluminum sheet (99.6%, 0.2 mm thickness). The regular array of hexagonal nano pores or channels were prepared by two step anodization process. A detail description of the AAO fabrication is presented. After the 1st anodization in oxalic acid (0.3 M) at 45 V, The formed AAO was removed by etching in a solution of 6 wt% $H_3$$PO_4$+1.8 wt% $H_2$$CrO_4$. The regular arrangement of the pores was obtained by the 2nd anodization, which was carried out in the same condition as the 1st anodization. Subsequently, the alumina barrier layer at the bottom of the channel layer was removed in phosphoric acid (1M) after removing of aluminum. Pore diameter, density, and thickness could be controlled by the anodization process parameters such as applied voltage, anodizing time, pore widening time, etc. The pore diameter is proportional to the applied voltage and pore widening time. The pore density and thickness can be controlled by anodization temperature and voltage.

Monte Carlo Simulation on Adsorption Properties of Benzene, Toluene, and p-Xylene in MCM-41

  • Moon, Sung-Doo
    • Bulletin of the Korean Chemical Society
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    • 제33권8호
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    • pp.2553-2559
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    • 2012
  • The adsorption properties of benzene, toluene, p-xylene in MCM-41 with heterogeneous and cylindrical pore were studied using grand canonical ensemble Monte Carlo simulation. The simulated isotherms were compared with experimental ones, and the different adsorption behaviors in MCM-41 with pore diameters of 2.2 and 3.2 nm were investigated. The simulated adsorption amounts above the capillary-condensation pressure agreed with the experimental ones. The simulation results showed that most molecular planes were nearly parallel to the pore axis. This orientation was not affected by the molecular position in the pore. The molecular planes were nearly parallel to the pore surface for the adsorbate molecules close to the pore wall, and the molecules in the MCM-41 with the pore diameter of 3.2 nm were ordered along the pore axis.

충격하중시험을 이용한 액상화 후 과잉간극수압 소산속도의 상사비 연구 (Evaluation of Similitude Laws for Dissipation Velocity of Excess Pore Pressure after Liquefaction using Impulse Load Tests)

  • 김동휘;하익수;황재익;김명모
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2004년도 춘계학술발표회
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    • pp.714-721
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    • 2004
  • The purpose of this study is to find out the similitude laws for dissipation velocity of excess pore pressure after liquefaction according to magnitude of input accelerations and height of model soils from the results of impulse load tests. In impulse load tests, model soils were constructed to the height of 25cm, 50cm, and 100cm in acrylic tubes whose inside diameters were 19cm and 38cm respectively, and impulse loads were applied at the bottom of each model soil to liquefy the entire model soil. Excess pore pressure distribution by depth and settlement of soil surface were measured in each test. Dissipation curves of excess pore pressure measured in each tests were simulated by solidification theory, and dissipation velocities of excess pore pressure were determined from the slope of simulated dissipation curves. From the results of impulse load tests, dissipation velocity of excess pore pressure was not affected by magnitude of input acceleration, and from this fact, dissipation process was proved to be different from dynamic phenomenon. However, dissipation velocity of excess pore pressure increased as height of model soil increased and showed little difference as diameter of model soil increased. Therefore, the similitude law for dissipation velocity could be expressed by the similitude law for model height to 0.2 without regard to the diameter of model soil.

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활성슬러지조내 부직포 여재 관형필터의 고액분리 특성 평가 (Evaluation of Tubular Type Non-woven Fabric Filter for Solid-liquid Separation in Activated Sludge Reactor)

  • 서규태;이택순;박영미
    • 대한환경공학회지
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    • 제30권2호
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    • pp.234-238
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    • 2008
  • 활성슬러지 공정에 막을 침지한 MBR(Membrane Bioreactor)공정에서 고가의 막을 대체하여 부직포 같은 섬유 여과막을 이용한 연구가 수행되었다. 부직포는 저렴한 가격, 저압에서 높은 투과유속의 확보 등 막을 대체할 수 있는 대안으로서 가치가 높다. 그러나 부직포 여과막 모듈은 막에 비하여 비표면적이 현저하게 작기 때문에 이를 증가시키는 노력이 필요하다. 본 연구에서는 활성슬러지 공정에 부직포 여과 관형 막모듈을 침지하여 설치형태와 관직경에 따라 여과압력에 미치는 영향을 실험적으로 검토하였다. 관형 필터의 직경이 같을 때, 반응조내 필터 모듈의 설치형태가 여과압력 변화에 미치는 영향은 없었다. 그러나 필터의 관 직경이 작을수록 여과압력의 상승이 빠르게 나타났고 이는 관내 수리학적 손실에 기인된 것으로 해석되었다. 따라서 관형 부직포 여과막은 관경 10 mm 이상에서 비표면적을 고려하여 설계하고, 반응조내 수직형으로 설치함이 적정한 것으로 나타났다.

알루미나 멤브레인을 이용한 CdS nanowire 제작에 관한 연구 (A study on the fabrication of CdS nanowires using by Alumina Membrane)

  • 서문수;이수호;유현민;이재형;최원석;김도영
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2011년도 제42회 하계학술대회
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    • pp.1493-1494
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    • 2011
  • CdS nanostructure materials have been fabricated in porous anodic aluminum oxide (AAO) template by using chemical bath deposition (CBD). These nanostructure materials had uniform diameters of about 15e200 nm, which correspond to the pore sizes of the templates used, and the length was up to 40 mm. X-ray diffraction (XRD) investigation demonstrates that CdS nanostructure materials were hexagonal polycrystalline in nature. As the pore diameter of AAO templates was enlarged, the preferential orientation of c-axis was improved. From PL analysis, the sulfur-deficient defects at the surfaces of CdS nanostructure materials were increasedwhen the samplewas synthesized in the template with larger pore diameter.

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A Simulation Method for Modeling the Morphology and Characteristics of Electrospun Polymeric Nanowebs

  • Kim Hyungsup;Kim Dae-Woong;Seo Moon Hwo;Cho Kwang Soo;Haw Jung Rim
    • Macromolecular Research
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    • 제13권2호
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    • pp.107-113
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    • 2005
  • We developed an algorithm to simulate the generation of virtual nanowebs using the Monte Carlo method. To evaluate the pore size of the simulated multi-layered nanoweb, an estimation algorithm was developed using a ghost particle having zero volume and mass. The penetration time of the ghost particle through the virtual nanoweb was dependent on the pore size. By using iterative ghost particle penetrations, we obtained reliable data for the evaluation of the pore size and distribution of the virtual nanowebs. The penetration time increased with increasing number of layers and area ratio, whereas it decreased with increasing fiber diameter. Dimensional analysis showed that the penetration time can be expressed as a function of the fiber diameter, area ratio and number of layers.

양극산화에 의한 다공성 알루미나 막의 기체투과 특성 (Gas Permeation Characteristics of Porous Alumina Membrane Prepared by Anodic Oxidation)

  • 함영민
    • 환경위생공학
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    • 제13권3호
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    • pp.72-78
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    • 1998
  • For investigation into gas permeation characteristics, the porous alumina membrane with asymmetrical structure, having upper layer with 10 nanometer under of pore diameter and lower layer with 36 nanometer of pore diameter, was prepared by anodic oxidation using DC power supply of constant current mode in an aqueous solution of sulfuric acid. The aluminium plate was pre-treated with thermal oxidation, chemical polishing and electrochemical polishing before anodic oxidation. Because the pore size depended upon the electrolyte, electrolyte concentration, temperature, current density, and so on, the the membranes were prepared by controling the current density, as a very low current density for upper layer of membrane and a high current density for lower layer of membrane. By control of current quantity, the thicknesses of upper layer of membranes were about $6{\;}{\mu}m$ and the total thicknesses of membranes were about $80-90{\;}{\mu}m$. We found that the mechanism of gas permeation depended on model of the Knudsen flow for the membrane prepared at each condition.

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계면활성제와 실리카 몰비의 조절에 따른 구형 MCM-48의 합성 (A Synthesis of Spherical MCM-48 with the Molar Ratio of Surfactant and Silica)

  • 이하영;박상원
    • 한국환경과학회지
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    • 제19권6호
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    • pp.681-687
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    • 2010
  • Mesoporous silica was prepared from hydrothermal synthesis using gel mixture of tetraethylorthosilcate (TEOS) as silica source and cetyltrimethylammonium bromide (CTMABr) as a surfactant. In the optimum synthesis cause, molar ratio of template and silica changed. The surface and structure properties of mesoporous silica were determined by XRD, SEM, TEM and BET. Also, surface potential of mesoporous silica was measured using zeta potential. $N_2$ adsorption isotherm characteristics, including the specific surface area ($S_{BET}$), total pore volume $V_T$), and average pore diameter ($D_{BJH}$), were determined by BET. As a result, SBET of $100m^2/g{\sim}1500m^2/g$ was determined from the $N_2$ adsorption isotherm. Also, the average pore diameter was 2 nm∼4 nm. Mesoporous silica's surface potential of minus charge was determined from zeta potential.